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Resin adhesives in
  Endodontics


    INDIAN DENTAL ACADEMY
Leader in Continuing Dental Education
    www.indiandentalacademy.com

  www.indiandentalacademy.com
Contents
   Introduction
   Adhesion
   Challenges in bonding to dentin
   Coronal vs radicular dentin
   Resin based root canal sealers
      -factors affecting adhesion
   Post endodontic restoration
   Resin based luting cements
   Rehabilitation of endodontically treated tooth
   Restoration of access cavities
   Material incompatibility
   conclusion



               www.indiandentalacademy.com
Introduction
   Improvement in esthetic materials &
    techniques
   Acid etch technique & composites present
    two major advances
   Stronger bonds to enamel & more
    predictable bonds to dentin
   The tremendous potential of resin based
    materials have been tried in endodontics

          www.indiandentalacademy.com
Adhesion
   Process of solid &/or liquid interaction of
    one material with another at a single
    interface
   Classified as
        *physical bonding
        *mechanical bonding
        *chemical bonding
        *micromechanical bonding
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Factors for achieving adhesive
                  bond
   Wetting

   Interpenetration

   Micromechanical interlocking

   Chemical bonding
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Challenges in bonding to dentin
   Dentin as substrate,

      composition

      tubular structure

      intrinsically hydrated


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   Smear layer




   Moist vs dry dentin
    surfaces




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Coronal vs radicular dentin
   Root dentin is less permeable than coronal
    dentin




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Resin sealers
   Epoxy based resin sealers
          AH 26 , toxicity due to release of
    formaldehyde
          AH Plus, paste-paste system,
    increased radiopacity, shoter setting time ,
    better flow

   Kwang et al ,AH 26 showed greater bond
    strength to dentin & GP
           www.indiandentalacademy.com
Methacrylate based root canal
                sealers
   Application of adhesive dentistry concepts to
    endodontics      create improved apical &
    coronal seal

   Introduction of methacrylate resin based sealers
    & dentin adhesives for endodontic use

   Sealers that bond to dentin & used with gutta-
    percha

            www.indiandentalacademy.com
Fiberfill ( Pentron, Wallingford)
   Designed for use with GP in single cone
    technique
   Consists of,
      primer A & B
      methacrylate based sealer
   Economidies et al 2004, compared sealing
    ability with CaOH based sealer

          www.indiandentalacademy.com
EndoREZ ( Ultradent)
   New dual cure sealer
   The only self-priming, hydrophilic sealer
    available
   UDMA resin-based root canal sealer with
    hydrophilic properties that improve sealing
    ability
   radiopaque as gutta percha
   Kardon et al 2003, EndoRez vs AH plus


           www.indiandentalacademy.com
   EndoREZ Points are
    standard ISO-sized
    gutta percha points
    overlayed with a thin
    resin coating.
   The resin coating allows
    EndoREZ Points to
    bond chemically with
    EndoREZ and other
    resin-based sealers.
           www.indiandentalacademy.com
Newer systems

Each system component is resin based
 resulting in a solid resin monoblock in the
 root that effectively seals to the dentinal
 walls




         www.indiandentalacademy.com
Epiphany (Pentron)
The Epiphany Soft Resin
 Endodontic Obturation System
 consists of,
*self-etching primer

*dual-cure resin sealer


        www.indiandentalacademy.com
RealSeal (sybronEndo)
   System consists of
     primer
     polyester based sealer

                                         Shortcut to real seal.lnk




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Resilon
   It is a thermoplastic synthetic
    polymer-based RC filling material
   Polyester, difunctional
    methacrylate resin, bioactive glass
    & radioopaque fillers
   Available as conv/std cones &
    pellets
   Lat compaction, warm vertical
    condensation or thermoplastic
    injection
             www.indiandentalacademy.com
   Shipper et al 2004, evaluated coronal
    leakage using E. faecalis & S. mutans

   Trope et al 2004, root filled teeth with
    resilon showed greater fracture resistance

   Shipper et al 2005, resilon group showed
    lesser periapical inflamation
          www.indiandentalacademy.com
Factors influencing adhesion in root
               canal
   Smear layer removal with 17% EDTA &
    5.25% NaOCl
   Mitzi D. Morris et al, demonstrated
    significantly larger reduction in dentin
    bond strength
   Completely reversed by application of
    10% ascorbic acid or 10% sodium
    ascorbate

           www.indiandentalacademy.com
   Mitzi et al , reduction in bond strength with
    RC prep
           - H2O2
           - polyethlene glycol
   C – factor in root canal- 20 -100



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Post endodontic restoration




     www.indiandentalacademy.com
Resin based post systems
   Carbon, glass, quarts or silica fibers embedded
    in resin matrix

   Advantage of flexing slightly

   Modulus of elasticity close to dentin

   Bonded to the root surface with resin cements

            www.indiandentalacademy.com
Carbon fiber posts
• Carbopost unidirectional, longitudinal fiber
reinforced composite posts, made of T700
carbon fibers (60% by volume) embedded in an
epoxy resin matrix (40% by volume).


• radiopacity- barium filler in the resin matrix.


• factory silanated, allowing the use of resin
bonding cements and core composite, and
giving a homogeneous all-composite corono-
radicular restoration.


                www.indiandentalacademy.com
Quartz fiber post
   Aestheti-post, white
    quartz fibers
    surrounding carbon
    fibers
   Aesthetic-plus, all
    quartz fibers, used
    with One step + Post
    cement Hi-X


           www.indiandentalacademy.com
Quartz fiber post
   Light Post (Bisco) unidirectional,
    quartz fibres, instead of carbon
    fibres
    The ratio of the quartz
    fibres/epoxy matrix is
    approximately 60/40
    higher flexural strength
   a low modulus of elasticity (close
    to that of dentin) to allow the post
    to flex along with the restored
    tooth.
            www.indiandentalacademy.com
   Lucent anchor post (Dentatus) is a fiber-glass,
    clear resin post used with Luxacore (zenith), an
    auto mixed self cured resin cements
   FibreKor post (Jeneric/Pentron) uses glass
    fibers bundled in resin matrix, Bond 1 + Build-it,
    an automixed dual-cured composite
   ParaPost Fiber White (Coltene/Whaledent)
    mono directional fibers in resin matrix




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www.indiandentalacademy.com
Glass fiber post

   SNOWPOST posts are made of 60% in volume of
    zircon-rich glass fiber embedded in an epoxy resin
    matrix.

   SNOWLIGHT posts are made of 65% in volume of
    zircon-rich glass fiber embedded in a polyester-
    metacrylate resin matrix, thus allowing the transmission
    of light.
    Both are silanated

   unidirectional, longitudinal glass fibers for strength,
    embedded in a resin matrix
     
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Resin luting cements




  www.indiandentalacademy.com
3M RelyX ARC Adhesive Resin Cement

   methacrylate resin-based dual cure luting
    material designed to be used with the 3M Single
    Bond dental adhesive system.

   two-paste system

   The resin is composed of bisphenol-A-
    diglycidylether dimethacrylate (BisGMA) and
    triethylene glycol dimethacrylate (TEGDMA)
    polymer. Zirconia/silica filler is used
            www.indiandentalacademy.com
Step 1 -Etching:
   • Apply 3M Scotchbond Etchant to the canal - wait 15 seconds.
   • Rinse for 10 seconds.
   • Dry for 2 seconds. Remove excess moisture with a
   paper point.

   Step 2 - Adhesive:
   • Apply 3M Single Bond Adhesive to the canal.
   • Dry for 5 seconds.
   • Remove excess (if any) with a dry paper point.

   Step 3 - Light-Cure:
   • Light-cure for 10 seconds.

   Step 4 - Apply Cement:
   • Dispense cement onto a mixing pad and mix for 10 seconds.
   • Apply cement in and around canal using a periodontal probe.
   • Place a thin layer of mixed cement on post.

   Step 5 - Seat the Post and Light-Cure:
   • Seat the post.
   • Remove excess cement while holding post in place.
   • Light-cure for 40 seconds from an occlusal direction. The
   remaining
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Calibra , Dentsply
   Prime & Bond NT Dual Cure is the
    bonding agent component of the system.
   Calibra is both light cure and dual cure.
   low film thickness between 12 and 18
    microns




          www.indiandentalacademy.com
PANAVIA 21
        Self-Curing Adhesive Bond System


   Paste/paste formulation
    ED Primer for effective
    one-step conditioning of
    cut enamel and dentin
    without having to rinse
   Radiopaque and insoluble


          www.indiandentalacademy.com
RelyX Unicem
      Self-Adhesive Universal Resin Cement

   3M ESPE RelyX Unicem Self-Adhesive
    Universal Resin Cement




          www.indiandentalacademy.com
RelyX luting cement 3M
   RelyX Luting cement is the new name for
    Vitremer Luting cement.
   is a hybrid glass ionomer cement
    simple application with no pretreatment or
    adhesives required
   Indicated for metal post


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Rehablitation of weakened roots




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Core material
   Popular core materials
   Bondability to posts & to remaining tooth
    structure – increased retension
   Pilo et al showed that composites have fracture
    resistance comparable to amalgam and cast
    post & core
   High tensile strength & tooth prepation can be
    done immediately
   More favourable failure mode
   Used with transluscent restorations

           www.indiandentalacademy.com
   Disadvantages
       - polymerization shrinkage
       - water sorption
       - adhesion to deep dentin
       - technique sensitive
   Composite is not a good choice with minimal
    remaining tooth structure, particularly if isolation
    is a problem.
   Eg. ParaCore (Coltene), Build-it (Pentron)
            www.indiandentalacademy.com
Restoration of access cavity
    Bonding to metal
     ceramic & all-
     ceramic restorations
1.   Surface treatment
2.   Silanation
3.   Bonding




           www.indiandentalacademy.com
www.indiandentalacademy.com
   Bonding to metal restoration

     * mechanical adhesion- surface treatment
    * chemical adhesion – oxide layer, tin or
    chromium plating platting
    * metal primers
    * silica coating
    * silanation has no effect on bonding to metal

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Material incompatibility
   Eugenol
   Selfetching systems vs self-cure & dual
    cure composites
          - residual acid
          - emulsion polymerization



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Conclusion
   Future directions should focus on materials that
       penetrate patent d.tubules
       bond to both org & inorg phases of dentin
       antimicrobial action
       induce cemental regenarative response
       strength root system
   Within this frame work resin based materials
    hold tremendous potentials and furthur research
    is need
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References
   Post and core systems, refinements to tooth
    preparation and cementation
                    - BDJ, vol .198,9 – 2004
   Post placement and restoration of endodontically
    treated teeth: A literature review
                    - JOE, vol.30,5 – 2004
   Comparative study of apical sealing ability of a
    new resin-based root canal sealer.
                    - JOE, vol.30,6 – 2004
   Colour atlas of endodontics
                    - Debra R. Haselton

            www.indiandentalacademy.com
   Geometric factors affecting dentin bonding in root canals: A
    theoretical modeling approach
                         -JOE, vol.31,8 – 2005

   Adhesive dentistry and endodontics : A review
                         -JOE, vol.31,3 – 2005

   Weakened anterior roots – intraradicular rehabilitation
                        -BDJ, vol.198 – 2005

   Esthetic dentistry
                          -DCNA, vol.34,4 – 1998

   Properties of a new injectable type of root canal filling resin with
    adhesiveness to dentin
                          -JOE,vol.29,1 - 2003

               www.indiandentalacademy.com
   Restorative dentistry
                       -DCNA,vol.46 – 2002
   Adhesion of a new methacrylate resin-based sealer of
    human dentin
                       -JOE, vol.30,4 – 2004
   Phillip’s science of dental materials
                 - Anusavice, 11th ed
   Sturdevant’s Art & science of operative dentistry
                 - Theodore M Roberson, 4th ed
   Pathways of pulp
                 - Stephen Cohen 8th & 9th ed

            www.indiandentalacademy.com

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Resin adhesives in endodontics / /certified fixed orthodontic courses by Indian dental academy

  • 1. Resin adhesives in Endodontics INDIAN DENTAL ACADEMY Leader in Continuing Dental Education www.indiandentalacademy.com www.indiandentalacademy.com
  • 2. Contents  Introduction  Adhesion  Challenges in bonding to dentin  Coronal vs radicular dentin  Resin based root canal sealers -factors affecting adhesion  Post endodontic restoration  Resin based luting cements  Rehabilitation of endodontically treated tooth  Restoration of access cavities  Material incompatibility  conclusion www.indiandentalacademy.com
  • 3. Introduction  Improvement in esthetic materials & techniques  Acid etch technique & composites present two major advances  Stronger bonds to enamel & more predictable bonds to dentin  The tremendous potential of resin based materials have been tried in endodontics www.indiandentalacademy.com
  • 4. Adhesion  Process of solid &/or liquid interaction of one material with another at a single interface  Classified as *physical bonding *mechanical bonding *chemical bonding *micromechanical bonding www.indiandentalacademy.com
  • 5. Factors for achieving adhesive bond  Wetting  Interpenetration  Micromechanical interlocking  Chemical bonding www.indiandentalacademy.com
  • 6. Challenges in bonding to dentin  Dentin as substrate, composition tubular structure intrinsically hydrated www.indiandentalacademy.com
  • 7. Smear layer  Moist vs dry dentin surfaces www.indiandentalacademy.com
  • 8. Coronal vs radicular dentin  Root dentin is less permeable than coronal dentin www.indiandentalacademy.com
  • 9. Resin sealers  Epoxy based resin sealers AH 26 , toxicity due to release of formaldehyde AH Plus, paste-paste system, increased radiopacity, shoter setting time , better flow  Kwang et al ,AH 26 showed greater bond strength to dentin & GP www.indiandentalacademy.com
  • 10. Methacrylate based root canal sealers  Application of adhesive dentistry concepts to endodontics create improved apical & coronal seal  Introduction of methacrylate resin based sealers & dentin adhesives for endodontic use  Sealers that bond to dentin & used with gutta- percha www.indiandentalacademy.com
  • 11. Fiberfill ( Pentron, Wallingford)  Designed for use with GP in single cone technique  Consists of, primer A & B methacrylate based sealer  Economidies et al 2004, compared sealing ability with CaOH based sealer www.indiandentalacademy.com
  • 12. EndoREZ ( Ultradent)  New dual cure sealer  The only self-priming, hydrophilic sealer available  UDMA resin-based root canal sealer with hydrophilic properties that improve sealing ability  radiopaque as gutta percha  Kardon et al 2003, EndoRez vs AH plus www.indiandentalacademy.com
  • 13. EndoREZ Points are standard ISO-sized gutta percha points overlayed with a thin resin coating.  The resin coating allows EndoREZ Points to bond chemically with EndoREZ and other resin-based sealers. www.indiandentalacademy.com
  • 14. Newer systems Each system component is resin based resulting in a solid resin monoblock in the root that effectively seals to the dentinal walls www.indiandentalacademy.com
  • 15. Epiphany (Pentron) The Epiphany Soft Resin Endodontic Obturation System consists of, *self-etching primer *dual-cure resin sealer www.indiandentalacademy.com
  • 16. RealSeal (sybronEndo)  System consists of primer polyester based sealer Shortcut to real seal.lnk www.indiandentalacademy.com
  • 17. Resilon  It is a thermoplastic synthetic polymer-based RC filling material  Polyester, difunctional methacrylate resin, bioactive glass & radioopaque fillers  Available as conv/std cones & pellets  Lat compaction, warm vertical condensation or thermoplastic injection www.indiandentalacademy.com
  • 18. Shipper et al 2004, evaluated coronal leakage using E. faecalis & S. mutans  Trope et al 2004, root filled teeth with resilon showed greater fracture resistance  Shipper et al 2005, resilon group showed lesser periapical inflamation www.indiandentalacademy.com
  • 19. Factors influencing adhesion in root canal  Smear layer removal with 17% EDTA & 5.25% NaOCl  Mitzi D. Morris et al, demonstrated significantly larger reduction in dentin bond strength  Completely reversed by application of 10% ascorbic acid or 10% sodium ascorbate www.indiandentalacademy.com
  • 20. Mitzi et al , reduction in bond strength with RC prep - H2O2 - polyethlene glycol  C – factor in root canal- 20 -100 www.indiandentalacademy.com
  • 21. Post endodontic restoration www.indiandentalacademy.com
  • 22. Resin based post systems  Carbon, glass, quarts or silica fibers embedded in resin matrix  Advantage of flexing slightly  Modulus of elasticity close to dentin  Bonded to the root surface with resin cements www.indiandentalacademy.com
  • 23. Carbon fiber posts • Carbopost unidirectional, longitudinal fiber reinforced composite posts, made of T700 carbon fibers (60% by volume) embedded in an epoxy resin matrix (40% by volume). • radiopacity- barium filler in the resin matrix. • factory silanated, allowing the use of resin bonding cements and core composite, and giving a homogeneous all-composite corono- radicular restoration. www.indiandentalacademy.com
  • 24. Quartz fiber post  Aestheti-post, white quartz fibers surrounding carbon fibers  Aesthetic-plus, all quartz fibers, used with One step + Post cement Hi-X www.indiandentalacademy.com
  • 25. Quartz fiber post  Light Post (Bisco) unidirectional, quartz fibres, instead of carbon fibres  The ratio of the quartz fibres/epoxy matrix is approximately 60/40  higher flexural strength  a low modulus of elasticity (close to that of dentin) to allow the post to flex along with the restored tooth. www.indiandentalacademy.com
  • 26. Lucent anchor post (Dentatus) is a fiber-glass, clear resin post used with Luxacore (zenith), an auto mixed self cured resin cements  FibreKor post (Jeneric/Pentron) uses glass fibers bundled in resin matrix, Bond 1 + Build-it, an automixed dual-cured composite  ParaPost Fiber White (Coltene/Whaledent) mono directional fibers in resin matrix www.indiandentalacademy.com
  • 28. Glass fiber post  SNOWPOST posts are made of 60% in volume of zircon-rich glass fiber embedded in an epoxy resin matrix.  SNOWLIGHT posts are made of 65% in volume of zircon-rich glass fiber embedded in a polyester- metacrylate resin matrix, thus allowing the transmission of light. Both are silanated  unidirectional, longitudinal glass fibers for strength, embedded in a resin matrix   www.indiandentalacademy.com
  • 29. Resin luting cements www.indiandentalacademy.com
  • 30. 3M RelyX ARC Adhesive Resin Cement  methacrylate resin-based dual cure luting material designed to be used with the 3M Single Bond dental adhesive system.  two-paste system  The resin is composed of bisphenol-A- diglycidylether dimethacrylate (BisGMA) and triethylene glycol dimethacrylate (TEGDMA) polymer. Zirconia/silica filler is used www.indiandentalacademy.com
  • 31. Step 1 -Etching: • Apply 3M Scotchbond Etchant to the canal - wait 15 seconds. • Rinse for 10 seconds. • Dry for 2 seconds. Remove excess moisture with a paper point. Step 2 - Adhesive: • Apply 3M Single Bond Adhesive to the canal. • Dry for 5 seconds. • Remove excess (if any) with a dry paper point. Step 3 - Light-Cure: • Light-cure for 10 seconds. Step 4 - Apply Cement: • Dispense cement onto a mixing pad and mix for 10 seconds. • Apply cement in and around canal using a periodontal probe. • Place a thin layer of mixed cement on post. Step 5 - Seat the Post and Light-Cure: • Seat the post. • Remove excess cement while holding post in place. • Light-cure for 40 seconds from an occlusal direction. The remaining www.indiandentalacademy.com
  • 32. Calibra , Dentsply  Prime & Bond NT Dual Cure is the bonding agent component of the system.  Calibra is both light cure and dual cure.  low film thickness between 12 and 18 microns www.indiandentalacademy.com
  • 33. PANAVIA 21 Self-Curing Adhesive Bond System  Paste/paste formulation  ED Primer for effective one-step conditioning of cut enamel and dentin without having to rinse  Radiopaque and insoluble www.indiandentalacademy.com
  • 34. RelyX Unicem Self-Adhesive Universal Resin Cement  3M ESPE RelyX Unicem Self-Adhesive Universal Resin Cement www.indiandentalacademy.com
  • 35. RelyX luting cement 3M  RelyX Luting cement is the new name for Vitremer Luting cement.  is a hybrid glass ionomer cement  simple application with no pretreatment or adhesives required  Indicated for metal post www.indiandentalacademy.com
  • 36. Rehablitation of weakened roots www.indiandentalacademy.com
  • 40. Core material  Popular core materials  Bondability to posts & to remaining tooth structure – increased retension  Pilo et al showed that composites have fracture resistance comparable to amalgam and cast post & core  High tensile strength & tooth prepation can be done immediately  More favourable failure mode  Used with transluscent restorations www.indiandentalacademy.com
  • 41. Disadvantages - polymerization shrinkage - water sorption - adhesion to deep dentin - technique sensitive  Composite is not a good choice with minimal remaining tooth structure, particularly if isolation is a problem.  Eg. ParaCore (Coltene), Build-it (Pentron) www.indiandentalacademy.com
  • 42. Restoration of access cavity  Bonding to metal ceramic & all- ceramic restorations 1. Surface treatment 2. Silanation 3. Bonding www.indiandentalacademy.com
  • 44. Bonding to metal restoration * mechanical adhesion- surface treatment * chemical adhesion – oxide layer, tin or chromium plating platting * metal primers * silica coating * silanation has no effect on bonding to metal www.indiandentalacademy.com
  • 45. Material incompatibility  Eugenol  Selfetching systems vs self-cure & dual cure composites - residual acid - emulsion polymerization www.indiandentalacademy.com
  • 46. Conclusion  Future directions should focus on materials that penetrate patent d.tubules bond to both org & inorg phases of dentin antimicrobial action induce cemental regenarative response strength root system  Within this frame work resin based materials hold tremendous potentials and furthur research is need www.indiandentalacademy.com
  • 47. References  Post and core systems, refinements to tooth preparation and cementation - BDJ, vol .198,9 – 2004  Post placement and restoration of endodontically treated teeth: A literature review - JOE, vol.30,5 – 2004  Comparative study of apical sealing ability of a new resin-based root canal sealer. - JOE, vol.30,6 – 2004  Colour atlas of endodontics - Debra R. Haselton www.indiandentalacademy.com
  • 48. Geometric factors affecting dentin bonding in root canals: A theoretical modeling approach -JOE, vol.31,8 – 2005  Adhesive dentistry and endodontics : A review -JOE, vol.31,3 – 2005  Weakened anterior roots – intraradicular rehabilitation -BDJ, vol.198 – 2005  Esthetic dentistry -DCNA, vol.34,4 – 1998  Properties of a new injectable type of root canal filling resin with adhesiveness to dentin -JOE,vol.29,1 - 2003 www.indiandentalacademy.com
  • 49. Restorative dentistry -DCNA,vol.46 – 2002  Adhesion of a new methacrylate resin-based sealer of human dentin -JOE, vol.30,4 – 2004  Phillip’s science of dental materials - Anusavice, 11th ed  Sturdevant’s Art & science of operative dentistry - Theodore M Roberson, 4th ed  Pathways of pulp - Stephen Cohen 8th & 9th ed www.indiandentalacademy.com