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DENTAL AMALGAM
Terminology

  Silver paste

  an alloy, one of the constituent of
  which is mercury

  an alloy made by mixing Hg with
  Ag-Sn dental amalgam alloy
Components

    1. Silver ( Ag) -increase expansion
              - retards setting time
              - enhances strength
              - decrease flow
              - resist tarnish/corrosion
2. Copper (Cu)- unites with Hg with
 difficulty
2. Copper- unites with Hg with
 difficulty
          - reduces setting time
2. Copper- unites with Hg with
 difficulty
          - reduces setting time
          - increases expansion
2. Copper- unites with Hg with
 difficulty
          - reduces setting time
          - increases expansion
          - increases strength and
           hardness
2. Copper- unites with Hg with
 difficulty
          - reduces setting time
          - increases expansion
          - increases strength and
           hardness
          - reduces flow
2. Copper- unites with Hg with
 difficulty
          - reduces setting time
          - increases expansion
          - increases strength and
           hardness
          - reduces flow
          -tarnishes readily
3. Tin (Sn)
3. Tin - unites readily with Hg
3. Tin - unites readily with Hg
       -retards setting time
3. Tin - unites readily with Hg
       -retards setting time
       -improves plasticity
3. Tin - unites readily with Hg
       -retards setting time
       -improves plasticity
       -reduces expansion
3. Tin - unites readily with Hg
       -retards setting time
       -improves plasticity
       -reduces expansion
       -increases flow
4. Zinc
4. Zinc (Zn)- combines readily with
 Hg
4. Zinc - combines readily with Hg
         -causes expansion
4. Zinc - combines readily with Hg
         -causes expansion
         -increases setting time
4. Zinc - combines readily with Hg
         -causes expansion
         -increases setting time
         -increases flow
4. Zinc - combines readily with Hg
         -causes expansion
         -increases setting time
         -increases flow
         -inhibits oxidation
4. Zinc - combines readily with Hg
         -causes expansion
         -increases setting time
         -increases flow
         -inhibits oxidation
         -decreases porosity
Classification
Classification
1. Amalgam alloy particle geometry
 and size
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut,
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
e.g. Low Copper (conventional
 amalgam),
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
e.g. Low Copper (conventional
 amalgam), High Copper
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
e.g. Low Copper (conventional
 amalgam), High Copper
3. Zinc Content
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
e.g. Low Copper (conventional
 amalgam), High Copper
3. Zinc Content
e.g. Zinc,
Classification
1. Amalgam alloy particle geometry
 and size
e.g. Lathe-cut – regular, fine
 microfine cut, Spherical
2. Copper Content
e.g. Low Copper (conventional
 amalgam), High Copper
3. Zinc Content
e.g. Zinc, Zinc-free
Alloy- Mercury Ratio
Alloy- Mercury Ratio


    irregular particle pack poorly and
    require a large amount of Hg
    (50%-60%)
Alloy- Mercury Ratio


  irregular particle pack poorly and
  require a large amount of Hg
  (50%-60%)

  precapsulated amalgam
  (spherical)has 42%- 45% mercury
Mercury rich mixtures – uses
 squeeze cloth to remove excess
 mercury
Mercury rich mixtures – uses
 squeeze cloth to remove excess
 mercury

1960 -Eames technique or no
 squeeze cloth technique
Trituration
Trituration

    process of manual mixing of alloy
    with Hg
Trituration

  process of manual mixing of alloy
  with Hg

  done by proportioning mercury and
  Hg into a mortar and grinding the
  mixture with a pestle
Trituration

  process of manual mixing of alloy
  with Hg

  done by proportioning mercury and
  Hg into a mortar and grinding the
  mixture with a pestle

  mixing of alloy with mercury
Types of Trituration
Types of Trituration
1. Hand
Types of Trituration
1. Hand
2. Mechanical
Types of Trituration
1. Hand
2. Mechanical –use of Amalgamator
Types of Trituration
1. Hand
2. Mechanical –use of Amalgamator

  reusable capsule
Types of Trituration
1. Hand
2. Mechanical –use of Amalgamator

  reusable capsule – a hallow tube
  with rounded ends constructed as
  two pieces that could be friction fit
  or screwed together

    precapsulated (preproportioned)-

    precapsulated (preproportioned)-
    the components are separated in
    the capsule by a special diaphragm
    that is broken when the capsule is
    placed in an amalgamator.
Reaction
Reaction
Mercury+Silver-Tin
Reaction
Mercury+Silver-Tin   Silver-Tin
 phase+ Silver-mercury phase + Tin-
 mercury phase
Reaction
Mercury+Silver-Tin   Silver-Tin
 phase+ Silver-mercury phase + Tin-
 mercury phase


    Silver-tin phase is called the
    gamma phase, composed of
    unreacted alloy particle

    Silver-mercury phase is called the
    gamma one

  Silver-mercury phase is called the
  gamma one

  Tin-mercury phase is called the
  gamma two

  Silver-mercury phase is called the
  gamma one

  Tin-mercury phase is called the
  gamma two

  amalgam can be thought of as
  particles of gamma surrounded by
  or bonded together by a matrix of
  gamma1 and gamma2
Hardening of amalgam
Hardening of amalgam
2 Phenomena
Hardening of amalgam
2 Phenomena
1. Solution
Hardening of amalgam
   2 Phenomena
1. Solution
2. Crystallization
Hardening of amalgam
   2 Phenomena
1. Solution
2. Crystallization


    when Hg comes in contact with
    amalgam alloy, the particles
    (gamma) are wet by mercury and
    begins to absorb it.

    the solution of mercury into silver-tin
    particles leads to the formation of
    the surface of Ag-Hg and Sn-Hg
    phases

  the solution of mercury into silver-tin
  particles leads to the formation of
  the surface of Ag-Hg and Sn-Hg
  phases

  the crystallization of the gamma1
  and gamma2 phases and their
  subsequent growth leads to
  hardening of amalgam
Mercury Management
Mercury Management
  Sources of Mercury Hazards
Mercury Management
   Sources of Mercury Hazards
1. Mercury vapors released from
 stored materials
Mercury Management
   Sources of Mercury Hazards
1. Mercury vapors released from
 stored materials
2. Amalgamator aerosols
Mercury Management
   Sources of Mercury Hazards
1. Mercury vapors released from
 stored materials
2. Amalgamator aerosols
3. Spillage during restoration
 procedure
Mercury Management
   Sources of Mercury Hazards
1. Mercury vapors released from
 stored materials
2. Amalgamator aerosols
3. Spillage during restoration
 procedure
4. Amalgam removal and
 replacement
5. Amalgam waste on cotton rolls
5. Amalgam waste on cotton rolls
6. Amalgam and mercury in
 plumbing and sewer system
5. Amalgam waste on cotton rolls
6. Amalgam and mercury in
    plumbing and sewer system
7. Amalgam scrap container
5. Amalgam waste on cotton rolls
6. Amalgam and mercury in
 plumbing ans sewer system
7. Amalgam scrap container
8. Mercury trapped in tiles and
 carpeting
THAT'S ALL FOLKS

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Finals lecture amalgam

  • 2. Terminology  Silver paste  an alloy, one of the constituent of which is mercury  an alloy made by mixing Hg with Ag-Sn dental amalgam alloy
  • 3. Components  1. Silver ( Ag) -increase expansion - retards setting time - enhances strength - decrease flow - resist tarnish/corrosion
  • 4. 2. Copper (Cu)- unites with Hg with difficulty
  • 5. 2. Copper- unites with Hg with difficulty - reduces setting time
  • 6. 2. Copper- unites with Hg with difficulty - reduces setting time - increases expansion
  • 7. 2. Copper- unites with Hg with difficulty - reduces setting time - increases expansion - increases strength and hardness
  • 8. 2. Copper- unites with Hg with difficulty - reduces setting time - increases expansion - increases strength and hardness - reduces flow
  • 9. 2. Copper- unites with Hg with difficulty - reduces setting time - increases expansion - increases strength and hardness - reduces flow -tarnishes readily
  • 11. 3. Tin - unites readily with Hg
  • 12. 3. Tin - unites readily with Hg -retards setting time
  • 13. 3. Tin - unites readily with Hg -retards setting time -improves plasticity
  • 14. 3. Tin - unites readily with Hg -retards setting time -improves plasticity -reduces expansion
  • 15. 3. Tin - unites readily with Hg -retards setting time -improves plasticity -reduces expansion -increases flow
  • 17. 4. Zinc (Zn)- combines readily with Hg
  • 18. 4. Zinc - combines readily with Hg -causes expansion
  • 19. 4. Zinc - combines readily with Hg -causes expansion -increases setting time
  • 20. 4. Zinc - combines readily with Hg -causes expansion -increases setting time -increases flow
  • 21. 4. Zinc - combines readily with Hg -causes expansion -increases setting time -increases flow -inhibits oxidation
  • 22. 4. Zinc - combines readily with Hg -causes expansion -increases setting time -increases flow -inhibits oxidation -decreases porosity
  • 24. Classification 1. Amalgam alloy particle geometry and size
  • 25. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut,
  • 26. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical
  • 27. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content
  • 28. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content e.g. Low Copper (conventional amalgam),
  • 29. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content e.g. Low Copper (conventional amalgam), High Copper
  • 30. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content e.g. Low Copper (conventional amalgam), High Copper 3. Zinc Content
  • 31. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content e.g. Low Copper (conventional amalgam), High Copper 3. Zinc Content e.g. Zinc,
  • 32. Classification 1. Amalgam alloy particle geometry and size e.g. Lathe-cut – regular, fine microfine cut, Spherical 2. Copper Content e.g. Low Copper (conventional amalgam), High Copper 3. Zinc Content e.g. Zinc, Zinc-free
  • 34. Alloy- Mercury Ratio  irregular particle pack poorly and require a large amount of Hg (50%-60%)
  • 35. Alloy- Mercury Ratio  irregular particle pack poorly and require a large amount of Hg (50%-60%)  precapsulated amalgam (spherical)has 42%- 45% mercury
  • 36. Mercury rich mixtures – uses squeeze cloth to remove excess mercury
  • 37. Mercury rich mixtures – uses squeeze cloth to remove excess mercury 1960 -Eames technique or no squeeze cloth technique
  • 39. Trituration  process of manual mixing of alloy with Hg
  • 40. Trituration  process of manual mixing of alloy with Hg  done by proportioning mercury and Hg into a mortar and grinding the mixture with a pestle
  • 41. Trituration  process of manual mixing of alloy with Hg  done by proportioning mercury and Hg into a mortar and grinding the mixture with a pestle  mixing of alloy with mercury
  • 44. Types of Trituration 1. Hand 2. Mechanical
  • 45. Types of Trituration 1. Hand 2. Mechanical –use of Amalgamator
  • 46. Types of Trituration 1. Hand 2. Mechanical –use of Amalgamator  reusable capsule
  • 47. Types of Trituration 1. Hand 2. Mechanical –use of Amalgamator  reusable capsule – a hallow tube with rounded ends constructed as two pieces that could be friction fit or screwed together
  • 48. precapsulated (preproportioned)-
  • 49. precapsulated (preproportioned)- the components are separated in the capsule by a special diaphragm that is broken when the capsule is placed in an amalgamator.
  • 52. Reaction Mercury+Silver-Tin Silver-Tin phase+ Silver-mercury phase + Tin- mercury phase
  • 53. Reaction Mercury+Silver-Tin Silver-Tin phase+ Silver-mercury phase + Tin- mercury phase  Silver-tin phase is called the gamma phase, composed of unreacted alloy particle
  • 54. Silver-mercury phase is called the gamma one
  • 55.  Silver-mercury phase is called the gamma one  Tin-mercury phase is called the gamma two
  • 56.  Silver-mercury phase is called the gamma one  Tin-mercury phase is called the gamma two  amalgam can be thought of as particles of gamma surrounded by or bonded together by a matrix of gamma1 and gamma2
  • 59. Hardening of amalgam 2 Phenomena 1. Solution
  • 60. Hardening of amalgam 2 Phenomena 1. Solution 2. Crystallization
  • 61. Hardening of amalgam 2 Phenomena 1. Solution 2. Crystallization  when Hg comes in contact with amalgam alloy, the particles (gamma) are wet by mercury and begins to absorb it.
  • 62. the solution of mercury into silver-tin particles leads to the formation of the surface of Ag-Hg and Sn-Hg phases
  • 63.  the solution of mercury into silver-tin particles leads to the formation of the surface of Ag-Hg and Sn-Hg phases  the crystallization of the gamma1 and gamma2 phases and their subsequent growth leads to hardening of amalgam
  • 65. Mercury Management Sources of Mercury Hazards
  • 66. Mercury Management Sources of Mercury Hazards 1. Mercury vapors released from stored materials
  • 67. Mercury Management Sources of Mercury Hazards 1. Mercury vapors released from stored materials 2. Amalgamator aerosols
  • 68. Mercury Management Sources of Mercury Hazards 1. Mercury vapors released from stored materials 2. Amalgamator aerosols 3. Spillage during restoration procedure
  • 69. Mercury Management Sources of Mercury Hazards 1. Mercury vapors released from stored materials 2. Amalgamator aerosols 3. Spillage during restoration procedure 4. Amalgam removal and replacement
  • 70. 5. Amalgam waste on cotton rolls
  • 71. 5. Amalgam waste on cotton rolls 6. Amalgam and mercury in plumbing and sewer system
  • 72. 5. Amalgam waste on cotton rolls 6. Amalgam and mercury in plumbing and sewer system 7. Amalgam scrap container
  • 73. 5. Amalgam waste on cotton rolls 6. Amalgam and mercury in plumbing ans sewer system 7. Amalgam scrap container 8. Mercury trapped in tiles and carpeting