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Fungicides China News

                                         Vol.2 Issue 6.2009




 Copyright © CCM International Limited
Fungicides China News                                                                                                                             Vol.2 Issue 6




   Fungicides China News                                                                                        Vol.2 Issue 6, 10 June 2009


                                                                    Content
   ■      Overview ������������������������������������������������������������������������������������������������������������ 1
   China’s fungicides with self-dominated intellectual property right (I)..............................................................1

   ■      Supply and Demand �������������������������������������������������������������������������������������������2
   Large demand boosts difenoconazole market ...................................................................................................2
   Foreign procurement boosts captan & folpet market ........................................................................................3
   Isoprothiolane sales robust ................................................................................................................................4
   Hymexazol prosperity in April ...........................................................................................................................4

   ■      Price updates ����������������������������������������������������������������������������������������������������� 5
   Monthly price of key raw materials in Jun. 2009 .............................................................................................. 5
   Monthly factory price of main fungicides in Jun. 2009 ....................................................................................6
   Monthly Shanghai port price and FOB Shanghai of main fungicides in Jun. 2009 ......................................... 6
   Monthly market price of main crops in Jun. 2009 ............................................................................................ 7

   ■      Pricing ��������������������������������������������������������������������������������������������������������������� 7
   Most fungicide prices continue downtrend in early June ................................................................................. 7
   Jiangsu Chengyang to build 200t/a cyproconazole ..........................................................................................8

   ■      Company Dynamics �������������������������������������������������������������������������������������������8
   Shanghai carried out a new provision in 1 June ................................................................................................8
   Shouguang ShuangXing to build 1,000t/a tebuconazole ..................................................................................9
   Jiangsu Taicang to build another 300t/a benomyl technical ......................................................................... 10
   Jiangsu Lanfeng’s thiophanate-methyl sees robust demand ..........................................................................11

   ■      Raw Material, Intermediates and Additives ����������������������������������������������������� 12
   JZPC building 100,000t/a m-xylene ............................................................................................................... 12

   ■      Disease ������������������������������������������������������������������������������������������������������������ 13
   Potato late blight to prevail in China ............................................................................................................... 13
   Serious wheat stripe rust and powdery mildew in Henan ............................................................................... 14

   ■      Registration ����������������������������������������������������������������������������������������������������� 15
   Fungicide registration in May 2009 .................................................................................................................15
   Metalaxyl mixed formulation registration soars in China............................................................................... 16

   ■      Policy ��������������������������������������������������������������������������������������������������������������� 17
   Shandong to boost 6 fungicide projects ............................................................................................................17

   ■      News in brief ���������������������������������������������������������������������������������������������������� 18
   Guangdong enters peak season of rice diseases .............................................................................................. 18
   Registration situation of flutriafol technical in China ..................................................................................... 18
   Wheat leaf rust outbreak in Henan ................................................................................................................. 18
   Jiangsu Limin’s 100t/a difenoconazole project to launch in July................................................................... 19




CCM International Limited                                                       I                                                        www.cnchemicals.com
Fungicides China News                                                                                              Vol.2 Issue 6




                                                                              Headlines of Fungicides
  Welcome to the June issue of Fungicides China News,                           China News 0906
  published by CCM International, a professional consulting
  company which has been extensively and intently focusing
  on dynamics of China’s fungicides industry. This newsletter 	 China has developed 14 fungicides with self-
  has covered fungicide market overview, supply & demand,          dominated intellectual property right, and
  price update, company dynamics, policies, registrations, etc.    commercially produced most.
                                                                	 Owing to large demand both at home and abroad,
                                                                   difenoconazole technical supply is very tight in May
  China’s fungicide industry has witnessed fast development        2009.
  in recent years, especially in 2008, with output growth of
  43.1%, to 196,000 tonnes from 137,000 tonnes in 2007.         	 Some foreign producers have suspended production
  Meanwhile, the international trade has grown largely.            of captan and folpet technical, which will boost
                                                                   production and export of these two export-oriented
                                                                   fungicides in China.
  This issue covers overview of Chinese fungicides with self- 	 With the coming of peak season for rice blast control,
  dominated intellectual property right, supply & demand           isoprothiolane production and sales have been
  of difenoconazole, captan and folpet, isoprothiolane,            robust.
  hymexazol, dynamics of Jiangsu Chengyang, Shouguang
  Shuangxing, Jiangsu Taicang and Jiangsu Lanfeng,              	 Hymexazol has enjoyed a promising market since
  registration and price situation of popular fungicides,          April 2009, which has boosted stable production in
  disease forecast on potato and wheat, etc.                       domestic market.
                                                                	 Price of most popular fungicides continues to
                                                                   decrease in early June, some even reaching the
  During 2009 and beyond we will cover a wide variety of           lowest level in recent years.
  topics relevant to China’s fungicides market, including
  market/consumption dynamics, related policies/legislations,   	 Jiangsu Chengyang is registering 95%
  disease dynamics, fungicide production situation,                cyproconazole technical and planning to build a 200t/
  international cooperation, new products, etc.                    a cyproconazole technical production line in its new
                                                                   plant located in Nanjing.

  If there are specific topics you would like to see us cover or 	 Shouguang Shuangxing is to launch a 1,000t/a
  would like to investigate any of the subjects covered in more     tebuconazole technical production line in the end of
  detail, please contact us - CCM International.                    2009
                                                                 	 Jiangsu Taicang plans to build another 300t/a
                                                                    benomyl technical production line in its new plant
                                                                    located in Rugao County, thus expanding its total
                                                                    benomyl capacity to 900t/a.
                                                                 	 Jiangsu Lanfeng, the largest thiophanate-methyl
       Key companies covered in this issue                            producer with capacity of 4,500~5,000t/a in China, is
                                                                      embracing robust demand at home and abroad.
                                                                 	 Jiangsu Zhongxin Petrochemical Company now is
                                                                      building a 100,000t/a m-xylene production line.
                                                                 	 Potato late blight has occurred severely in Chongqing
                                                                      and Sichuan by mid May 2009, with stricken area
                                                                      increasing by 87.7% and 37.0% respectively over the
                                                                      same period of last year
                                                                 	 Wheat stripe rust and powdery mildew, which
                                                                      occurred more severely in 2009 with large stricken
                                                                      areas, has promoted a remarkable demand growth
                                                                      for triazole fungicides.
                                                                 	 Chinese fungicide registrations in May 2009 had
                                                                      a great decrease compared with April. Only 12
                                                                      fungicide technical were registered.
                                                                 	 The registration for Metalaxyl mixed formulations has
                                                                      soared in 2008 and 2009, compared with almost no
                                                                      technical or single formulation registration in the past
                                                                      ten years.
                                                                 	 Shandong releases guiding opinions on local
                                                                      pesticide industry and plans to boost 6 fungicide
                                                                      projects.




CCM International Limited                                   II                                             www.cnchemicals.com
Fungicides China News                                                                                                 Vol.2 Issue 6




  ■        Overview
          China’s fungicides with self-dominated intellectual property right (I)

   C    hina has developed 14 fungicides
        with self-dominated intellectual
   property right, all of which were
                                                 FIGURE 2: Structure formula of
                                                          SYP-Z071
                                                                                          resistance when used with other
                                                                                          fungicides. According to field test
                                                                                          result of tomato botrytis cinerea
   registered in the Institute for the                                                    control from SYRICI, control effect
   Control of Agrochemicals, Ministry                                                     of 25% SYP-Z048 EC reaches 89.79%
   of Agriculture (ICAMA), and most                                                       with dosage of 400 g(i.a.)/ha., higher
   of them have been commercially                                                         than that of 40% pyrimethanil SC
   produced by domestic companies.              Source: SYRICI                            and 50% procymidone WP (Pls refer
                                                                                          to Fungicides China News 0905, Page
   In this issue, CCM would like to           SYRICI has completed technological          1).
   introduce 4 of these fungicides,           upgrade of SYP-Z071 by launching
   developed by Shenyang Research             a new production line with                  SYP-1620
   Institute of Chemical Industry             enestroburin technical capacity of
   (SYRICI).                                  10t/a in late 2008. SYRICI can also         SYP-1620, a new strobilurin fungicide
                                              produce SYP-Z071 formulation: 25%           with broad-range of fungicidal
                                              SYP-Z071 EC, with capacity of 40t/a.        activity, developed by SYRICI in
   Flumorph                                                                               1999, is highly effective in controlling
                                              25% SYP-Z071 EC has better control          wheat powder mildew, wheat rust,
   Flumorph, with CAS name of                 effect on cucumber downy mildew             rice blast, rice false smut, banana leaf
   4-[3-(3,4-dimethoxyphenyl)-3-(4-           than some traditional fungicides such       spot, apple alternaria leaf spot, etc.
   fluoro-phenyl)-1-oxo-2-propenyl]           as mancozeb WP, with application
   morpholine, is the first fungicide         dosage of 100~200g(i.a.)/ha.. And             FIGURE 4: Structural formula of
   with self-dominated intellectual           compared with isoprothiolane, 25%                       SYP-1620
   property right in China, developed         SYP-Z071 EC has lower risk for
   by Liu Changling of SYRICI in 1994.        fungicide resistance of rice blast.
      FIGURE 1: Structure formula of
                                              SYP-Z048
                flumorph
                                              SYP-Z048, a new pyridine oxazoline
                                                                                           Source: SYRICI
                                              fungicide with novel structure
                                              (FIGURE 3) and unique action                SYP-1620 was firstly produced in
                                              mechanism, has good control                 2004 in the Pilot Plant of SYRICI, the
                                              effect on crop diseases induced by          only producer in the world. SYRICI
      Source: SYRICI
                                              ascomycetes, basidiomycetes and             developed its first formulation,
                                              deuteromycetes, such as botrytis            5% SYP-1620 EC in 2006, and
   Flumorph has been granted                  cinerea on tomato and cucumber.             started commercial production of
   patents both in China and the U.S.                                                     another formulation, 20% SYP-
   Commercial production of this                FIGURE 3: Structural formula of
                                                                                          1620·tebuconazole SC this year.
   fungicide started in 1999, using                      SYP-Z048
   catechol as starting raw material. It is                                               Up to now, SYRICI has obtained four
   mainly used to control Peronospora                                                     Chinese patents and one American
   and Phytophthora diseases, such                                                        patent for SYP-1620 since 1999,
   as downy mildew on cucumber,                                                           including a Chinese patent for
   cabbage and grape, phytophthora                                                        20% SYP-1620·tebuconazole SC
   blight on pepper and tomato, etc.,                                                     (ZL03134025.3).
   with application dosage of 150g(a.i.)/          Source: SYRICI
   ha.                                                                                    SYP-1620 has been promoted
                                              SYP-Z048, with broad-spectrum and
                                                                                          well in the control of wheat
                                              self-dominated intellectual property
                                                                                          powder mildew and banana leaf
   Enestroburin (SYP-Z071)                    right, is highly effective in controlling
                                                                                          spot, in Shandong province and
                                              various crop diseases, such as
                                                                                          South China respectively, with
   Enestroburin, with test number of          cucumber scab, cotton fusarium wilt,        commercial production of 20% SYP-
   SYP-Z071, is a strobilurin fungicide       wheat scab, grape brown spot and
                                                                                          1620·tebuconazole SC in 2008.
   with broad spectrum and long-              botrytis cinerea.
   lasting preventive and curative                                                        Resemble to the development of
   activity, developed by SYRICI and          SYP-Z048 is especially effective in         SYP-Z071, SYRICI has also completed
   granted Chinese patent.                    botrytis cinerea control, compared          technological upgrade of SYP-1620 by
                                              with such fungicides as pyrimethanil        launching a new production line with
                                              and procymidone. In addition,               technical capacity of 10t/a.
                                              SYP-Z048 won’t lead to cross




CCM International Limited                                         1                                           www.cnchemicals.com
Fungicides China News                                                                                                 Vol.2 Issue 6



  Comments                                    period (1995-2000).                         at the field test stage by SYRICI, with
                                                                                          test numbers of SYP-3375, SYP-3343,
  China is making great efforts in            SYRICI, as the first comprehensive          SYP-3759.
  pesticide independent innovation,           R&D unit for China’s chemical
  with pesticide development listed           industry, has contributed a lot in          CCM will continue to introduce
  in the Guideline of Medium- and             developing China’s pesticide industry.      other fungicides with self-dominated
  Long-Term Program for Science and           Except for the above 4 fungicides           intellectual property right in China in
  Technology (2006-2020). China               with Chinese patents having been            next issue.
  started to build National Pesticide R       commercially produced, there are
  & D Centers in the 9th Five-year plan       other 3 fungicides being developed or



    ■        Supply and Demand

                            Large demand boosts difenoconazole market

   O    wing to large demand both at home and abroad,
        difenoconazole technical supply is very tight in
   Chinese market in May 2009, which has largely boosted
                                                                    kasugamycin · copper oxychloride WP, 10%
                                                                    difenoconazole WG and 20% thiediazole copper SC.
                                                                    Therefore, more peasants would use 10% difenoconazole
   its market.                                                      WDG, thus boosting difenoconazole.

   In China, most large manufacturers have no                       Meanwhile, large demand from overseas is another
   difenoconazole technical storage at present, due to its          important factor boosting tight supply of difenoconazole
   tight supply in recent months.                                   technical. As Table 1 shows, Green Agrosino and
                                                                    Shandong Dongtai export 70% of their difenoconazole
   According to Mr. Yang, sales manager from Beijing Green          to overseas markets, such as Vietnam, while Shouguang
   Agrosino Company (Green Agrosino), the company’s                 ShuangXing exports 50% of its difenoconazole output.
   difenoconazole technical supply is very tight and is not         According to Ms. Liu, difenoconazole technical are well
   able to satisfy new orders until Jun. 2009.                      sold both in domestic and overseas market at present.
   And Shandong Shouguang ShuangXing Pesticide
   Company (Shouguang ShuangXing) isn’t able to satisfy             With difenoconazole technical tight supply in Chinese
   new difenoconazole technical orders until late Jun. 2009,        market, many companies have registered its technical
   according to Ms. Liu, sales manager from the company.            and formulations. Difenoconazole were the most popular
                                                                    fungicide registered in Apr. 2009 (Pls refer to Fungicides
   Tight supply of difenoconazole technical is mainly due to        China News 0905, P15). Besides, some companies like
   the following three reasons:                                     Shouguang ShuangXing are expending their capacity/
                                                                    output. According to Ms. Liu, Shouguang ShuangXing
   With pesticide consumption entering peak season in               will expend its difenoconazole technical output to 20t/
   China at present, especially in South China, domestic            month in H2 2009.
   demand for difenoconazole technical is very large, as most
   difenoconazole formulation producers in China are busy           However, difenoconazole price has reduced to
   producing. According to Shandong Dongtai Agrochemical            USD32,178/t in early May, compared with USD35,103/
   Company, the company sells difenoconazole technical              t in May 2008, as shown in Figure 5, mainly due to the
   very well in economic crop planting regions in the south         global financial crisis. It is predicted that difenoconazole
   of China.                                                        technical supply will continue to be tight in the near
                                                                    future, as fruit disease occurrence will be severe in recent
   Besides,� 10% difenoconazole WDG is among the                    months, which may drive its price up in near future.
   four formulations recommended by National Agro-
   Tech Extension and Service Center (NATESC) in                    Difenoconazole, a systemic fungicide with broad
   Mar. 2009, which include 2% kasugamycin AS, 47%                  spectrum, provides long-lasting preventive and
                         TABLE 1: Current production situation of major difenoconazole technical producers
                                                                     Production
                                                                                       Output
                                                                     Capacity (t/                 Production       Export
                                 Producers                                              (t/
                                                                         a)                         status       proportion
                                                                                       month)
             Beijing Green Agrosino Company                               200
                                                                                         15           Tight          70%
             Shandong Dongtai Agrochemical Company                        300            20           Tight          70%
             Jiangsu Sevencontinent Green Chemical Company                N/A            10          Normal          N/A
             Shandong Shouguang ShuangXing Pesticide Company              300            10
                                                                                                      Tight          50%

           Source: Shanghai metal website




CCM International Limited                                       2                                              www.cnchemicals.com
Fungicides China News                                                                                                         Vol.2 Issue 6



    curative activity against ascomycetes, basidiomycetes                difenoconazole EC and 37% difenoconazole WDG are
    and deuteromycetes, including alternaria, ascochyta,                 most commonly used single formulations in China,
    cercospora, cercosporidium, colletotrichum, guignardia,              while difenoconazole + propiconazole is the major
    mycosphaerella, rhizoctonia, septoria, uncinula, etc.                difenoconazole mixed formulation.

    At present, 10% difenoconazole WDG, 25%
                     TABLE 1: Current production situation of major difenoconazole technical producers

            40,000

            35,000

            30,000

            25,000

            20,000

            15,000

            10,000
                     May-08 Jun-08    Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09
                                                                Difenoconazole


          Source: CCM International



                       Foreign procurement boosts captan & folpet market


   S   ome foreign producers have suspended technical production of captan and folpet, which is to boost production and
       export of these two export-oriented fungicides in China.

   Captan and folpet are broad-spectrum fungicides used to control various vegetable diseases, such as downy mildew,
   powdery mildew and anthracnose, as well as early blight and late blight of tomato and potato.

   The two fungicides have the same capacity in China, as they can be produced by the same production line. Captan and
   folpet are export-oriented fungicides, with most of the output exported to Europe, South America, South Africa, etc.

   Yingde Greatchem Chemicals Company (Yingde Greatchem) is producing technical of captan and folpet tightly at
   present thanks to large demand from overseas. It won’t accept new orders until mid June 2009, according to Mr. Bi,
   sales manager from the company.

   Ningbo Zhenhai Hodak Agrochemicals Company (Ningbo Zhenhai Hodak) and Zhejiang Rayfull Holding Company
   (Zhejiang Rayfull) only produce these two products by orders.

   Technical supply of captan and folpet is tight in China at present, as some foreign producers have suspended production
   due to capital shortage caused by global financial crisis. Besides, with higher production cost in the overseas, many
   formulation processors would like to import technical from China to reduce production cost. Both of these aspects has
   boosted captan and flopet demand.

   It is predicted that captan and folpet are expected to have a promising market in near future. Currently, some
   companies, such as Yingde Greatchem, are expanding technical capacity of captan and folpet in order to satisfy the large
   export. According to Mr. Bi, Yingde Greatchem will double its captan technical capacity in Aug. ~ Sep.2009.



                                     TABLE 2: Technical export situation of captan and folpet

                        Company                            Capacity (t/a)                      Export destination
                                                                                 France, Spain, Turkey, Suriname, Lithuania,
       Changzhou Pangu Chemical Company                       800~900
                                                                                 South Africa
                                                                                 Ecuador, Guatemala, Ukraine, Jordan, Dominican
       Ningbo Zhenhai Hodak Agrochemicals Company             600~700
                                                                                 Rep, Chile, South Africa
       Yingde Greatchem Chemicals Company                     500~600            Spain, South Africa, Europe, South America
       Zhejiang Rayfull Holding Company                       400~500            Europe, South America

        Source: CCM International




CCM International Limited                                            3                                                www.cnchemicals.com
Fungicides China News                                                                                              Vol.2 Issue 6



                                             Isoprothiolane sales robust


   W      ith the coming of peak season
          for rice blast occurrence
   since late Apr. 2009, isoprothiolane
                                             application volume mainly depends
                                             on disease degree, so isoprothiolane
                                             demand mainly depends as well.
                                                                                        Isoprothiolane technical produced by
                                                                                        Zhejiang Linghua Industry Company
   production and sales have been                                                       is not sold in the market. The
   robust in China.                          China has currently 3 major                company uses the product itself to
                                             isoprothiolane technical producers,        produce 30% and 40% isoprothiolane
   Rice blast has occurred seriously         about 40 single formulation                EC.
   in Fujian, Guangdong, Guangxi,            producers and more than 30
   Jiangxi and Hunan at present, due         mixed formulation producers, with          However, Hunan Hengyang
   to favorable temperature and large-       technical capacity of 10,000t/a,           Roymaster Bio-pesticide Company
   scale adoption of non-resistant rice      output of 5, 000t/a and demand of          suspended isoprothiolane production
   varieties this year. China has entered    1,000~2,000t/a at present.                 to focus on glyphosate in H2 2008,
   the peak season for rice blast control                                               according to Ms. Lin from the
   (Pls refer to Fungicides China News       As Table 3 shows, Sichuan Academy          company.
   0905, P13).                               and Sichuan Chuandong are
                                             producing isoprothiolane technical         As for price of isoprothiolane
   In China, three kinds of fungicides,      tightly. According to Ms. Yuan,            technical, it has reduced to
   including tricyclazole, isoprothiolane    director from Guanghan Testing             USD4,270/t in early May from
   and iprobenfos, are commonly              Workshop of Sichuan Academy,               USD 5,400/t in 2008, mainly due
   used to control rice blast, among         isoprothiolane is under short supply       to significant price drop of raw
   which tricyclazole is mainly for rice     both at home and abroad currently.         materials. Isoprothiolane sales
   blast prevention, iprobenfos for                                                     volume is expected to rise this year,
   both prevention and treatment and         Sichuan Chuandong exports 60%              as more growers will be able to offer
   isoprothiolane for treatment.             of its isoprothiolane output to the        lower price and rice blast occurrence
                                             overseas, such as Southeast Asia. Its      situation is severe this year with
   Isoprothiolane is an organic              domestic market has also started up        estimated stricken area of 5.60
   phosphine fungicide with high             thanks to the coming of peak season        million hectares.
   efficacy against rice blast. Occurrence   for isoprothiolane sales, according
   of rice blast mainly depends on           to Mr. Zheng, manager from the
   weather, while isoprothiolane             company.


                         TABLE 3: Current production situation of isoprothiolane technical producers
                                                                                     Output (t/month)         Production
                                      Company
                                                                                                                status
    Sichuan Academy of Chemical Industry Research & Design (Sichuan Academy)
                                                                                          300~400                 Tight
    Sichuan Chuandong Agrochemicals Company(Sichuan Chuandong)
                                                                                             80                   Tight

    Zhejiang Linghua Industry Company (Zhejiang Linghua)
                                                                                           40~50                 Normal

    Hunan Hengyang Roymaster Bio-pesticide Company (Hengyang Roymaster)
                                                                                             0                 Suspended


   Source: CCM International



                                       Hymexazol prosperity in April


   A    fter the slack demand from late 2008 to early 2009,
        hymexazol has enjoyed a promising market since
   this April, as the peak season for rice seedling blight
                                                                   hydrochloride, raw materials for hymexazol technical
                                                                   production, have kept stable in terms of price and supply
                                                                   recently. Accordingly, price of hymexazol technical
   occurrence (June and July) is coming. Despite the gloomy        remained relatively stable in May, going down slightly
   export, robust domestic demand still promotes stable            from 25,000USD/t in Jan. to 23,500USD/t, when a
   production of hymexazol technical.                              majority of pesticides witnessed serious price drop in H1
                                                                   2009.
   Hymexazol has enjoyed a thriving market both at home
   and abroad in 2008 and is expected to enjoy a promising         Currently, 99% hymexazol technical becomes more and
   market in the future years.                                     more popular in China, while 95% and 97% technical still
                                                                   dominate the overseas market. The producers begin to
   Besides, with increasing demand of hymexazol in                 pay more attention to domestic market and promote 99%
   domestic market, methyl acetoacetate and Hydroxylamine          hymexazol technical to foreign users (Table 4).



CCM International Limited                                      4                                           www.cnchemicals.com
Fungicides China News                                                                                                               Vol.2 Issue 6



                                                        Hymexazol, a systemic fungicide                   decompose into compounds with low
          According to Mr. Zhang, sales                 with high efficacy and low toxicity,              toxicity.
          manager from Weifang Tianda                   is usually used as a soil disinfectant
          Plants Protection Co., Ltd, with              by binding with iron and aluminum                 Relevant news link: Hymexazol
          registration in May 2008 and                  ions to inhibit germination of spores.            market promising in China
          technical innovation in late 2008,            Hymexazol can be absorbed by and                  (Fungicides Newsletter 0902, Page 2,
          the company has started to produce            transfer across plant roots, and                  by CCM International)
          99% hymexazol technical in large              generate two glucosides in plants
          scale and achieved good sales in early        to improve physiological activity of              In China, hymexazol had witnessed
          2009. The company has hymexazol               crops, thus promoting crop growth                 a thriving market both at home and
          technical capacity of 200t/a. Its             and root tillering, increasing root               abroad in 2008, and was expected
          export proportion in the total output         hair and improving root activity.                 to have a promising market in the
          reduces to 25% in May from 60% in                                                               future years. To satisfy the future
          Jan. 2009 (Table 4).                          As a broad-spectrum fungicide,                    demand in the peak season from
                                                        hymexazol has good effects                        Apr. to Sep. 2009, most Chinese
          Mr. Li, salesman from Shandong                against various crops diseases                    hymexazol technical producers have
          Qiaochang Chemical Co., Ltd,                  induced by fusarium, pythium spp,                 continued production even in slack
          claimed that the company still mainly         rhizoctonia, etc, especially for the              season, from late 2008 to early 2009.
          produces 95% hymexazol technical,             control of seedling blight on rice
          as 99% technical hasn’t been well             and sugarbeet and fusarium wilt
          promoted yet. ‘We still largely rely on       on watermelon. It has small effect
          export at present, but we’re planning         on bacteria and actinomycetes in
          to produce 99% technical and adjust           soil, thus exerting little impact on
          export proportion in the future,’ says        microbiological ecology. Besides, it
          Mr. Li.                                       is environmentally friendly as it can


                              TABLE 3: Current production situation of isoprothiolane technical producers

                                                                                    Export proportion
                                                                   Capacity
                                   Producer                                                                       Export destination
                                                                     (t/a)         2009.01      2009.05

                  Weifang Tianda Plants Protection Company
                                                                     200           50~60%      20%~30%       Southeast Asia, East Europe
                  Shandong Qiaochang Chemical Company
                                                                     200            60%        45%~55%          Middle East, East Europe


                 Source: CCM International




           ■         Price updates

                                  Monthly price of key raw materials in Jun� 2009
                                                Factory price                                                       Market price
   Raw material/
                           10 Jun. 2009         10 May 2009            Jun. 2008               10Jun. 2009          10 May 2009            Jun. 2008
   intermediates
                         USD/t     RMB/t       USD/t     RMB/t      USD/t         RMB/t      USD/t    RMB/t       USD/t     RMB/t      USD/t    RMB/t
2,6-Dimethyl aniline     12,097    82,700      12,120    82,700     18,747    129,300        12,141   83,000      12,164    83,000     18,798   129,650
Copper oxychloride       4,052     27,700      4,060     27,700      5,314        36,650     4,096    28,000       4,104    28,000      5,365    37,000
Cuprous oxide             6,100    41,700       6,112     41,700     8,939        61,650      6,143   42,000       6,155    42,000     8,989     62,000
M-xylene                  1,682       11,500    1,715     11,700     2,269        15,650      1,726   11,800       1,759    12,000     2,320     16,000
Nitrobenzene               790        5,400      791      5,400      1,254         8,650       834      5,700        835      5,700     1,305     9,000
1,2,4-Triazole            5,734    39,200      5,818     39,700      6,909        47,650      5,778   39,500       5,862    40,000     6,959    48,000
Sulphur                      88       600         91        620        239         1,650         95      650         106       720       290     2,000


          Source: CCM International




    CCM International Limited                                                 5                                                www.cnchemicals.com
Fungicides China News                                                                                                                                          Vol.2 Issue 6




                                   Monthly factory price of main fungicides in Jun� 2009

                                10 Jun. 2009                10 May 2009                      Jun. 2008                                      10 Jun. 2009                  10 May 2009
          Technical                                                                                                 Formulation
                              USD/t     RMB/t             USD/t       RMB/t             USD/t         RMB/t                            USD/t           RMB/t          USD/t          RMB/t
      Dimethomorph            16,339    111,700           16,810          114,700        18,073       124,650       50% WP             10,122          69,200          10,215        69,700
     Chlorothalonil            5,076       34,700          5,305          36,200          5,749        39,650       75% WP             4,198           28,700          4,646          31,700
     Mancozeb                  3,467       23,700          3,547          24,200          4,299        29,650       80% WP             3,320           22,700          3,400         23,200
     Isoprothiolane            4,198       28,700          4,280          29,200          5,604        38,650       -                       -              -              -             -
     Carbendazim               3,759       25,700          4,060          27,700          7,054        48,650       50% SC             2,443           16,700           2,521         17,200
     Sulphur                    351         2,400           366            2,500             1,051       7,250      50% SC                  322           2,200           352           2,400
     Phosethyl Al              2,516       17,200          2,667          18,200          4,081         28,150      -                       -              -              -             -
     Triadimefon               7,855       53,700          8,163          55,700          9,663        66,650       15% WP              1,711           11,700         2,081          14,200
     Tebuconazole             14,262       97,500         14,319          97,700         18,798       129,650       -                       -              -              -             -
     Tricyclazole              7,562       51,700          7,577           51,700         7,924        54,650       -                       -              -              -             -
     Propiconazole            27,748    189,700           30,001      204,700            30,397       209,650       -                       -              -              -             -
     Metalaxyl                19,703    134,700           21,207          144,700        26,047       179,650       -                       -              -              -             -
     Prochloraz                7,416       50,700          7,577           51,700         11,766         81,150     -                       -              -              -             -
     Difenoconazole           32,136    219,700           32,199          219,700        36,196       249,650       -                       -              -              -             -
     Propamocarb              6,538     44,700             7,137          48,700             8,141     56,150       -                       -              -              -             -

                 Source: CCM International



             Monthly Shanghai port price and FOB Shanghai of main fungicides in Jun� 2009

                                               Shanghai port price                                     FOB Shanghai                                            Shanghai port price

                                                                                                     10 Jun.      10 May
   Technical            10 Jun. 2009                10 May 2009                  Jun. 2008                                    Formulation          10 Jun. 2009                 10 May 2009
                                                                                                      2009         2009

                    USD/t       RMB/t         USD/t          RMB/t           USD/t       RMB/t       USD/t        USD/t                         USD/t          RMB/t          USD/t         RMB/t

Dimethomorph        16,383       112,000       16,854        115,000          18,124     125,000      15,753       16,205     50% WP            10,166           69,500       10,259        70,000
Chlorothalonil
                      5,120      35,000         5,349         36,500           5,800     40,000       4,974         5,195     75% WP              4,242         29,000          4,690       32,000
Mancozeb
                      3,511      24,000         3,591         24,500           4,350     30,000       3,435         3,511     80% WP              3,364          23,000         3,444       23,500
Isoprothiolane
                      4,242      29,000         4,323         29,500           5,655      39,000       4,135        4,213     -                    -              -              -            -
Carbendazim
                      3,803      26,000         4,104         28,000           7,104      49,000       3,715       4,002      50% SC              2,487          17,000         2,565       17,500
Sulphur
                       395         2,700            410           2,800        1,102         7,600       453            468   50% SC               366            2,500          396         2,700
Phosethyl Al
                      2,560       17,500         2,711        18,500           4,132      28,500      2,525        2,670      -                    -              -              -            -
Triadimefon
                     7,899       54,000         8,207         56,000           9,714      67,000      7,634        7,930      15% WP              1,755          12,000         2,125       14,500
Tebuconazole        14,306       97,800        14,363         98,000          18,849     130,000     13,765       13,820      -                    -              -              -             -
Tricyclazole
                      7,606      52,000         7,621         52,000           7,974      55,000      7,354         7,369     -                    -              -              -            -
Propiconazole
                    27,792       190,000       30,045        205,000          30,448     210,000     26,672       28,828      -                    -              -              -            -
Metalaxyl
                     19,747      135,000       21,251        145,000          26,098     180,000     18,973        20,412     -                    -              -              -            -
Prochloraz
                      7,460       51,000        7,621         52,000           11,817     81,500       7,214        7,369     -                    -              -              -            -
Difenoconazole
                    32,180      220,000        32,243        220,000          36,247     250,000     30,871       30,932      -                    -              -              -            -
Propamocarb           6,582      45,000         7,181         49,000           8,192      56,500      6,374        6,948      -                    -              -              -            -

            Source: CCM International




       CCM International Limited                                                              6                                                           www.cnchemicals.com
Fungicides China News                                                                                             Vol.2 Issue 6




                           Monthly market price of main crops in Jun� 2009
                                     10 Jun. 2009                 10 May 2009                   Jun. 2008
                Crops
                               USD/t          RMB/t         USD/t         RMB/t         USD/t           RMB/t

           Wheat                     268            1,830          268          1,827           231           1,592
           Yellow maize              227            1,554          227          1,546        238              1,639
           Peanut Kernel             917            6,267         1,011         6,900       1,179             8,130
           Indica rice               404            2,759         404           2,758        393              2,709
           Japonica rice             490            3,350           481         3,280           441          3,040
           Banana                    834            5,700           821         5,600        580             4,000
           Cucumber                  176            1,200         322           2,200           174          1,200
           Apple                     878            6,000         806           5,500           797          5,500

         Source: CCM International




    ■       Pricing

                    Most fungicide prices continue downtrend in early June


   W     ith a sustaining downtrend in May, price of most popular fungicides continues to decrease in early June, some
         even reaching the lowest level in recent years, mainly due to export depression.

   Price of mancozeb technical, a fungicide with largest capacity in China, has decreased to USD3,511/t in early June,
   down 2.23% over the previous month. Mancozeb technical supply still exceeds the demand severely in early June,
   leading to more intense competition and continuous price decrease. It is worthy noting that the downtrend has slowed
   down, with decrease rate reducing from 5.66% in previous month to 2.23% in early June.

   Price of carbendazim technical, the largest domestic benzimidazole fungicide, has declined to USD3,803/t in early
   June, down 7.34% over the previous month, reaching the lowest level in recent years. After the sharp slump from
   USD6,290/t in Mar. to USD4,242/t in Apr., price of carbendazim technical has dropped slightly, following the
   sustaining export depression.

   Chlorothalonil technical price has decreased by 4.29% in June, compared with USD5,349/t in May. The price war was
   still severe, in which most producers have cut down quotation to capture market share since early 2009.

   Similarly, price of some triazole fungicides decreased slightly in early June, after a continuous rebound from February
   to April. Prices of tebuconazole, propiconazole and triadimefon have decreased by 0.41%, 7.50% and 3.75% separately
   over the previous month, due to the shrinking demand from global market.

   However, difenoconazole price has maintained the same level with last month, thanks to its wide use range and
   excellent effect. According to Mr. Zhang from Beijing Green Jixi agrosino Biotech Co., Ltd, the company still busily
   produces difenoconazole technical though some other pesticides had faced continuous price downtrend. Seeing the
   promising market, most Chinese producers plan to expand capacity in the near future.

   The sharp downtrend for prochloraz technical price has stopped in early June, though it still drops slightly compared
   with last month. Prochloraz technical price has reached the lowest level in recent years to USD7,462, down 2.11% over
   the previous month. As an export-oriented with 70% output exported, prochloraz technical has witnessed a price drop
   of 37.8% from USD11,988/t in Dec. 2008,. It is estimated that it will continue to drop in the future.

   Most fungicide prices haven’t dropped sharply in early June, thanks to the recovery of Chinese economy. However,
   with the global financial crisis, fungicide market in China still needs some time to recover in the near future.




CCM International Limited                                     7                                             www.cnchemicals.com
Fungicides China News                                                                                                Vol.2 Issue 6




     ■         Company Dynamics

                        Jiangsu Chengyang to build 200t/a cyproconazole


   J  iangsu Chengyang Crop
      Technological Co., Ltd (Jiangsu
   Chengyang) is applying for
                                              technical includes synthesis
                                              and refining of onium salts and
                                              1-(4-chlorophenyl)-2-cyclopropyl-
                                                                                           abroad. Some producers began to
                                                                                           produce cyproconazole technical with
                                                                                           small scale in early 2007, though
   registration of 95% cyproconazole          propane. The company produces                without registration. With highest
   technical and planning to build a new      onium salts using dimethyl sulfoxide         price of more than USD130,000/
   200t/a cyproconazole production line       and dimethyl sulfate as raw materials,       t, cyproconazole becomes the most
   and locate it in late 2010.                avoiding the stench emitted by               expensive fungicide in China.
                                              dimethyl sulfide, a raw material used
   The production line will be built          to produce onium salts by traditional        History proved that large numbers
   in its new plant located in Nanjing        technology.                                  of people would roll in when a
   Chemical Industrial Park, together                                                      new market shows up. With more
   with a 200t/a difenoconazole               Furthermore, Jiangsu Chengyang               and more companies engaging in
   production line, with total investment     uses 1-(4-chlorophenyl)-2-                   cyproconazole production and large
   of USD15 million.                          cyclopropyl-propane as intermediate,         impact by global financial crisis,
                                              which is much cheaper than                   cyproconazole price dropped greatly
   Mr. Xu from Jiangsu Chengyang              4-chlorophenyl-cyclopropyl-methyl-           since 2008, down to USD88,000/t
   claims that the new plant is currently     ketone adopted in traditional route.         recently.
   under construction, with the 200t/a        Traditional intermediate has so high
   cyproconazole technical production         price mainly because one of its raw          When more and more producers
   line under environmental impact            material is very expensive, with price       eliminated, the survivals began to
   assessment. “China has recently no         of USD44,000/t.                              develop new production technology
   legal registration for cyproconazole                                                    and formally apply for registration.
   technical, though some producers           Developed by Clariant Corporation            These companies, including Jiangsu
   have produced and sold this product        (previous Sandoz Corporation) in             Chengyang, will gradually dominate
   illegally. This fungicide is expensive,    1985, cyproconazole is a low toxic           Chinese cyproconazole technical
   which generates large room for             triazole fungicide with high efficacy        production in the near future.
   profit,’ said Mr. Xu.                      against powdery mildew, cereal rust,
                                              apple scab, etc.
   According to the report for
   environmental impact assessment,           Domestic cyproconazole production
                               TABLE 1: Domestic registered epoxiconazole technical producers, 2009

                                                                                             Registration      Quoted Price
     Fungicides                         Company                        Capacity (t/a)
                                                                                              Situation          (USD/t)

                                                                        200        (when
                      Jiangsu Chengyang Crop Technological Co., Ltd                             Applying            N/A
                                                                              finish)
    Cyproconazole
      technical         Jiangsu Yancheng Limin Chemical Co., Ltd.              150              Applying           95,187
                       Zhejiang Shangyu Yinbang Chemical Co., Ltd              100              Applying           77,614
                          Hunan Xiangda Bide Chemical Co., Ltd         Stop production            N/A              87,865


   Source: CCM International

   production process of cyproconazole        is quite novel, although it is mature

                            Shanghai carried out a new provision in 1 June



   S  hanghai newly carried out a provision named ‘Provisions of Shanghai Municipality on Administration of Operation
      and Application of Pesticide’ on 1 June, 2009, which regulates that distribution of pesticides must be unified and
   those who purchase highly toxic pesticide must show their ID card. Besides, the provision has suggested a series of
   measures strengthening safe management of pesticides.




CCM International Limited                                        8                                            www.cnchemicals.com
Fungicides China News                                                                                                       Vol.2 Issue 6



                     Shouguang ShuangXing to build 1,000t/a tebuconazole

   S  handong Shouguang ShuangXing Pesticide Company
      (Shouguang ShuangXing) is to build a new 1,000t/a
   tebuconazole technical production line in H2 2009, and
                                                                         Tebuconazole formulations have been promoted well in
                                                                         domestic market in recent years for the control of various
                                                                         crop diseases such as rust, powdery mildew and scab. The
   expects to launch it in the end of 2009.                              overseas demand for tebuconazole technical has also kept
                                                                         robust. Therefore, tebuconazole registration has soared
   This tebuconazole technical production line will be                   in China since 2008 (referred to Fungicides China News
   located in Shouguang ShuangXing’s new plant. Mr. Liu,                 0905, Page 16), with large production capacity expansion.
   manager from the company reveals that the new plant
   is currently under construction, located in Shandong                  Owing to bright market prospect, the company has
   Weifang Binhai Economic Development Area.                             given priority to tebuconazole product development.
                                                                         The company has previously planned to launch several
   Shouguang Shuangxing will use chlorobenzaldehyde,                     new production lines for different fungicide technical
   pinacolone and 1,2,4-triazole purchased from domestic                 including tebuconazole, difenoconazole, propiconazole
   producers as major starting raw materials to produce                  and mancozeb in H2 2009 when the new plant is finished
   tebuconazole technical.                                               construction. However, with export depression caused
                                                                         by the global financial crisis, the mancozeb technical
   After the launch of the production line, 60~70% of                    capacity expansion, from 500t/a to 3,000~5,000t/a has
   tebuconazole technical produced will be exported to the               been postponed, and the schedule for difenoconazole and
   overseas, including Europe, America and Southeast Asia,               propiconazole expansion is uncertain yet.
   and the remaining will be consumed by itself to process
   formulations such as 12.5% tebuconazole EW, which will                Shouguang ShuangXing, established in 1997, is a
   be mainly sold in domestic market, according to Mr. Liu.              subsidiary of Shandong A & fine Agrochemicals Group.
                                                                         It has hundreds of registration products such as TC,
   According to a principal from Product Information                     WP, WDG, EC, EW, ME and SL. Its fungicide products
   Department of Shouguang Shuangxing, the company is                    with brand of ‘Shuangxing’, such as propiconazole and
   now applying for registration of tebuconazole technical,              mancozeb, enjoy good reputation among Chinese crop
   and is expected to obtain the certificate in early 2010.              growers.

   Moreover, Liu claims that construction of this production
   line is mainly driven by good market prospect of
   tebuconazole technical and formulations.

                                  TABLE 6: Major tebuconazole technical producers in China


                                        Company                                           Production capacity (t/a)
        Jiangsu Zhangjiagang No. 2 Pesticide Factory                                                             3,000

        Shanghai Shengnong Pesticide Co., Ltd.                                                                   2,000

        Jiangsu Sevencontinent Green Chemical Co., Ltd.                                                          1,000

        Jiangsu Sheyang Huanghai Pesticide Chemical Co., Ltd.                                                         800

        Jiangsu Sword Agrochemicals Co., Ltd.                                                                         600

        Sinochem Ningbo Chemicals Co., Ltd.                                                                           500

        Jiangsu Flag Chemical Industry Co., Ltd.                                                                      300

        Jiangsu Tuoqiu Agrochemicals Co., Ltd.                                                                        300

        Anhui Huaxing Chemical Co., Ltd.                                                                              300

        Jiangsu Fengdeng Pesticide Co., Ltd.                                                                          100

        Jilin Agrochemicals Co., Ltd. Of CNPC Jilin Chemical Group                                                    500

        Shandong Huayang Technology Co., Ltd.                                                                         300

        Jiangsu Bailing Agrochemical Co., Ltd.                                                                        200

        Shanghai Heben-Eastsun Medicaments Co., Ltd.                                                                  150


      Source: CCM International




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Fungicides China News                                                                                              Vol.2 Issue 6




                 Jiangsu Taicang to build another 300t/a benomyl technical


   J  iangsu Taicang Agrochemical Company (Jiangsu Taicang) plans to build another 300t/a benomyl technical
      production line in its new plant located in Rugao County, and expects to launch it by late 2010, thus expanding its
   total benomyl capacity to 900t/a.

   As a systemic fungicide with low toxicity, benomyl has high efficacy against diseases of grain, grape, pip fruits,
   rice and vegetable caused by ascomycetous, deuteromycetous and some basidiomyctous fungi. Benomyl is a
   benzimidazole fungicide flourishing in the 1980s, but is not so popular now, due to serious resistance and large
   dosage.

   Mr. Gao, sales manager from Jiangsu Taicang, claimed that all benomyl technical produced by the company are
   exported. With good reputation and high quality, the company received many orders from the overseas. It has a
   long-term client from Belgium who purchases more than 100 tonnes of benomyl from it every year. With good sales
   channels, the company plans to expand the capacity.

   According to the statistics from Institute for the Control of Agrochemicals, Ministry of Agriculture (ICAMA), China
   has only five registrations for benomyl technical and one is expired at present. Jiangsu Taicang and Jiangsu Lanfeng
   are the only 2 legal benomyl technical producers in China at present. Other 3 registrants have stopped production, as
   they haven’t established long-term relationship with overseas companies and can’t sell their product under the global
   financial crisis.

   Jiangsu Taicang survives with high product quality, while Lanfeng answers the enemy with low price and large
   capacity. Mr. Ma, sales manager from Jiangsu Lanfeng, claimed that his company has much bigger workshop than
   JiangsuTaicang and can reduce production cost by self-producing raw materials, thus being able to offer lower price.
   Price investigation showed that benomyl technical price kept stable in early 2009, quoted USD10,000/t by Jiangsu
   Taicang and USD8,800/t by Jiangsu Lanfeng.

   ‘When the new production line is launched, with larger capacity, we will be able to reduce production cost, thus
   lowing down the quotation. Aided by high quality we kept all along, our benomyl may dominate Chinese export by
   then, ‘ Said Mr. Gao from Jiangsu Taicang.

   Established in 1983, Jiangsu Taicang has technical capacity of 3,000t/a carbendzain, 600t/a benomyl, 3,000t/a
   glyphosate, 500t/a thiophanate-methyl, 100t/a propiconazol and 300t/a dodine in Taicang County. It is currently
   building a new plant with 10,000t/a glyphosate, 2,500t/a carbendzain (introduced in CCM’s Fungicides China News
   0905), 300t/a benomyl, 500t/a thiophanate-methyl, 50t/a propiconazol, 500t/a dodine, etc. in Rugao County of
   Jiangsu.



                               TABLE 7: Registration situation of benomyl technical in China



              A.I.                                                                Capacity     Export
Fungicide               Registration period        Registration Company                                          Survey Remark
            content                                                                (t/a)     Proportion

                          2009.01.06 ---      Jiangsu Taicang Agrochemical Co.,                            Up to 900t/a when the new
              95%                                                                   600        100%
                           2009.12.31               Ltd ( Jiangsu Taicang )                                      line completes

                          2008.10.17 ---       Jiangsu Lanfeng Bio-Chem Co.,
              95%                                                                  1,200        80%                     N/A
                           2009.10.17              Ltd ( Jiangsu Lanfeng)

Benomyl                   2009.01.09 ---       Jiangsu Anpon Electrochemical                               Stop production because of
              90%                                                                  N/A          N/A
Technical                  2009.12.31                     Co., Ltd                                              severe pollution

                          2009.02.20 ---           Jinagsu Jiangyin KAJO                                     Stop production several
              95%                                                                  N/A          N/A
                            2009.12.31             Agrochemical Co., Ltd.                                           years ago

                         2007.03.23 ---       Jiangsu Suzhou Worldbest Agro-                                 Stop production several
              95%                                                                  N/A          N/A
                       2008.12.31 (expired)        Biochemical Co., Ltd.                                            years ago


   Source:ICAMA, CCM International




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Fungicides China News                                                                                           Vol.2 Issue 6




                  Jiangsu Lanfeng’s thiophanate-methyl sees robust demand

   J   iangsu Lanfeng Bio-chem
       Company (Jiangsu Lanfeng), the
   largest thiophanate-methyl producer
                                            protection policy in Suzhou. It
                                            now mainly purchases technical
                                            from other companies to process
                                                                                     fungicide producers, as there are
                                                                                     only two producers, namely Jiangsu
                                                                                     Lanfeng itself and Anhui Guangxin
   with capacity of 4,500~5,000t/           thiophanate-methyl formulations.         producing thiophanate-methyl
   a in China, has witnessed robust                                                  in China at present.. And Anhui
   demand at home and abroad, thanks        As for Jiangxi Haili Guixi Pesticide     Guangxin is the largest carbendazim
   to its competitive advantage and         & Chemicals Company (Jiangxi             producer in China with capacity of
   higher environmental protection          Haili), it produces thiophanate-         15,000t/a who pays more attention
   requirement released by the              methyl technical only by orders and      to carbendazim production.
   government.                              exports 50% of its output. It has also
                                            suspended production now, due to         For another, environmental
   Thiophanate-methyl is a kind of          the coming of thiophanate-methyl         protection policy in Jiangsu,
   benzimidazole and broad spectrum         slack season, relatively large storage   location of Jiangsu Lanfeng is not
   fungicide used to control various        and no purchasing orders, according      as strict as that in other regions
   crop diseases such as wheat scab,        to Mr. Xiong, sales manager of the       such as Suzhou, location of Suzhou
   rice sheath blight, apple ring rot and   company.                                 Worldbest, so Jiangsu Lanfang
   cucurbits powdery mildew.                                                         needs to spend less in environmental
                                            Jiangsu Lanfeng’s thiophanate-           protection, which also becomes an
   China is one of the largest              methyl witnesses robust demand           advantage for its thiophanate-methyl
   thiophanate-methyl production            mainly thanks to the following           production. Suzhou Worldbest
   countries in the world, with total
   capacity of about 16,000t/a. At      FIGURE 6: Distribution of major thiophanate-methyl technical producers in China
   present, the 3 largest thiophanate-
   methyl producers in China
   include Jiangsu Lanfeng Bio-chem
   Company (Jiangsu Lanfeng), Anhui
   Guangxin Agrochemical Group
   Company (Anhui Guangxin) and
   Suzhou Worldbest Agro-Biochemical
   Company (Suzhou Worldbest) (Table
   8), with their total capacity reaching
   about 12,000~13,000t/a, taking up
   around 80% of total market share.

   According to Ms. Cai, sales manager
   from Jiangsu Lanfeng, the company
   produces thiophanate-methyl all
   year around thanks to large demand
   both at home and abroad, except the
   period for equipment maintenance.
   It exports 70% of its thiophanate-
   methyl technical to overseas, such as
                                               Source: CCM International
   America, Europe and Southeast Asia.

   However, according to Mr. Fan, sales     reasons:                                was the third largest thiophanate-
   manager from Shandong Huayang            For one thing, Jiangsu Lanfeng has      methyl producer in China before
   Science and Technology Company           faced less competition from other       Beijing Olympic Games, but it has
   (Shandong Huayang), the company
   has currently suspended production           TABLE 8: Major thiophanate-methyl technical producers in 2009
   to update its equipment, aiming to
   meet the requirement
   for environmental             Production            Production         Output in         Export          Production
                                  companies           capacity (t/a)    2008 (tonne)      proportion           status
   protection. Therefore,
   it has no output in       Jiangsu Lanfeng             4,500~5,000             4,000        70%              Active
   2009 and will resume      Anhui Guangxin              3,500~3,800             3,200      60~70%             Active
   production in 2010.
   Suzhou Worldbest          Suzhou Worldbest                   4,000     2,000~2,500          0              Stopped
   has also suspended        Shandong Huayang             1,200~1,500         300~500          0              Stopped
   thiophanate-methyl
                             Jiangxi Haili                1,200~1,500            1,000         0              Stopped
   technical production
   at present, due to the
   stricter environmental     Source: CCM International




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Fungicides China News                                                                                                         Vol.2 Issue 6


   suspended thiophanate-methyl                 thiophanate-methyl technical                     and sulfur, its price has decreased
   technical production due to the strict       has witnessed robust demand                      slightly during Jan. 2009 to May
   environmental protection policy in           from formulation production,                     2009, mainly due to the global
   Suzhou.                                      such as thiophanate-methyl WP,                   financial crisis, as shown in Figure 6.
                                                thiophanate-methyl SC and mixed
   Though Jiangsu Lanfeng’s                     formulation production with thiram

             FIGURE 7: Price change of thiophanate-methyl and carbendazim, Jan. ~ May 2009 (Unit: USD/t)




         40,000

         35,000

         30,000

         25,000

         20,000

         15,000

         10,000
                  May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09
                                                            Difenoconazole



     Source: CCM International




   ■        Raw Material, Intermediates and Additives

                                    JZPC building 100,000t/a m-xylene


   J   iangsu Zhongxin Petrochemical
       Company (JZPC) now is building
   a 100,000t/a m-xylene production
                                                According to Mr. Sima, principle of
                                                this project, the company will adopt
                                                                                                 Sima expresses that all m-xylene
                                                                                                 produced by JZPC will be supplied
   line, and is expected to launch it in        a new patent technology to produce               to domestic downstream companies.
   late 2010, which will help to relieve        m-xylene, using bottle grade pet,                ‘With high product quality and
   domestic m-xylene short supply in            textiles, disinfection solution and              m-xylene short supply, our company
   the future.                                  perfume as raw materials. Sima                   has signed long-term contract with
                                                reveals that this patent technology              some domestic companies, ‘ Sima
   JZPC’s m-xylene project, with total          is brought from UOP (the United                  says.
   investment of USD99.5 million                States) with USD20 million.
   and coverage area of 163,333m2,                                                               M-xylene, a basic chemical raw
   is located in Lingang Xincheng               Moreover, active ingredient content              material, is widely applied in the

                                   TABLE 9: M-xylene and its downstream pesticides


         Raw material                  Intermediate                                          Pesticide

                                       Isophthalonitrile                             Chlorothalonil (Fungicide)

            M-xylene                 2,4-dimethyl ani ine                    Semiamitraz chloride, amitraz (Insecticide)

                                     2,6-dimethyl aniline                              Metalaxyl (Fungicide)

      Source: CCM International

   Development Zone of Jiangsu. This            of m-xylene produced by JZPC will                production of pesticides, dyes,
   project has initiated construction in        reach 99.95%, highest among all                  medicine, pigments, etc. A series
   Mar. 2009 and is expected to launch          the domestic producers. At present,              of chemical intermediates, such as
   in H2 2010, including matching               active ingredient content of m-xylene            isophthalic acid, isophthalonitrile, 2,4
   facilities of 120,000t/a isophthalic         produced by Yanshan Petrochemical                (2,6)-dimethyl aniline and m-toluic
   acid production line.                        Company is 99.50%.                               acid, can be produced using m-xylene




CCM International Limited                                            12                                                www.cnchemicals.com
Fungicides China News                                                                                                     Vol.2 Issue 6




   as raw material.

   Homemade m-xylene is far from meeting demand from its downstream industries. At present, Yanshan Petrochemical
   Company, with 35,000t/a production capacity, is the only m-xylene producer in China, after Shanghai Petrochemical
   Company, with 8,000t/a capacity, stopped production in 2006. However, compared with annual domestic m-xylene
   demand of 106,000 tonnes in 2007 and 141,500 tonnes in 2009(predicted by JZPC), current capacity is far from
   meeting the demand.

   As for m-xylene used in downstream fungicide production, the demand from chlorothalonil and metalaxyl production
   was about 15,000t/a in 2008, and this demand will increase by 4,000~5,000t/a in 2009, with capacity expansion of
   the two fungicides (Table 10).


               TABLE 10: Production capacity expansion of chlorothalonil and metalaxyl in China (Unit: t/a)


         Fungicide          Capacity ‘08           Capacity ‘09                             Remark

                                                                    Jiangsu Xinyi CAC Chemical Company is to launch
      Chlorothalonil             13,100               18,100        5,000t/a production line in Jun. or Jul. 2009.
                                                                    Jiangsu Baoling Chemical Company and Zhejiang
                                                                    Heben Pesticide & Chemicals Company expanded by
      Metalaxyl                  1,500                 2,500
                                                                    400t/a and 600t/a in early 2009.


     Source: CCM International




    ■          Disease
                                     Potato late blight to prevail in China

   P   otato late blight has hit
       accumulatively 184,600 hectares
   of planting area in Southwest China
                                                   with much larger stricken areas
                                                   compared with the same period of
                                                   2008 (Table 11).
                                                                                              potato growers’ insufficient efforts on
                                                                                              disease control.

   and Central China by mid May                                                           It is predicted that from late May
   2009, and is predicted to occur                 Chongqing is the most severely         to early June, potato late blight will
   severely in East China, North China,            stricken region by potato late blight, further expand in Southwest China,
   Northeast China and Northwest                   with stricken area of 74,867 hectares  Central China and East China. Then
   China during late May to August this            by mid May 2009, accounting for        from June to August, the occurrence
   year, according to National Agro-               36.8% of Chongqing’s total potato      will still be severe, since weather
   Tech Extension and Service Center               planting area. The stricken regions    forecast from National Climate
   (NATESC).                                       mainly distribute in mountainous       Center shows that rainfall in most
                                                                                                            regions of Northwest
             TABLE 11: Occurrence situation of potato late blight in China (Unit: hectare)                  China, North China
                                                                                                            and Northeast China
         Region         Stricken area by mid May 2009               Change over last year                  will be more abundant
                                                                                                           than normal years,
     Chongqing                       74,867                           Up 87.7% year on year
                                                                                                           which is favorable for
     Sichuan                         36,667                           Up 37.0% year on year                occurrence and spread
     Yunnan                           1,533                        A little severe than last year          of potato late blight.
     Guizhou                              16,000                          Down 36.0% year on year
                                                                                                             Owing to forecasted
     Hubei                                40,000                                    N/A
                                                                                                             severe occurrence
     Hunan                                7,400                                     N/A                      of late blight in
     Shaanxi                              8,133                                     N/A                      China’s major potato
                                                                                                             planting regions, some
    Source: NATESC                                                                                           traditional fungicide
                                                                                                             formulations with
   In mid May, potato late blight has              areas with low altitude of Chongqing,      high control effect and low toxicity,
   occurred severely in some major                 and are estimated to expand fast           such as 80% mancozeb WP, 65%
   potato production regions of                    in the future months, due to the           zineb WP and 4% metalaxyl-M +
   Southwest China and Central China,              favorable weather condition, the           64% mancozeb WDG, are expected
   especially in Chongqing and Sichuan,            high seed transmission rate, and           to enjoy market growth in domestic



CCM International Limited                                           13                                            www.cnchemicals.com
Fungicides China News                                                                                                        Vol.2 Issue 6


  market, thanks to their excellent performance in potato                PICTURE 1: Potato and its leaves hit by late blight
  late blight control and relatively low price.
  However, as for the new fungicides against potato late
  blight, like azoxystrobin, cyazofamid and fluazinam, their
  domestic demand will stay at a low level in the future
  years, since their promotion will still be difficult due to the
  high price.

  Aim to control potato late blight and promote treatment
  technology, NATESC held a National Potato Late Blight
  Prevention Conference from 23 April to 24 April 2009 in
  Jinan city, Shandong province.




                   Serious wheat stripe rust and powdery mildew in Henan

  W      heat stripe rust and powdery
         mildew, two key wheat
  diseases, have occurred severely this
                                              rust and powdery mildew,
                                              consumption of related
                                              fungicides has risen largely
                                                                                         PICTURE 2: Wheat powdery mildew

  year in Henan, with stricken areas          this year. Triazole fungicides,
  of 1.01 million hectares and 2.05           including triadimefon,
  million hectares by May 19th, 2009,         tebuconazole, flutriafol,
  accounting for 19.1% and 39.0%              propiconazole, etc, have enjoyed
  respectively of Henan’s total wheat         a remarkable demand growth
  planting area.                              for their good control effect
                                              against these two diseases. In
  Henan is the largest wheat                  particular, domestic demand for
  production region in China, with total      triadimefon, the most popular
  planting area of 5.26 million hectares,     triazole fungicide applied in
  accounting for 22.8% of China’s total.      China, has grown by more than
                                              70% in Henan.
  According to the monitoring data                                                            PICTURE 3: Wheat stripe rust
  from Henan Plant Protection Station,        By May 19th, 2009, accumulative
  the stricken areas by wheat stripe          control areas to wheat stripe rust
  rust and powdery mildew have kept           and powdery mildew have reached
  increasing since late Apr. 2009             1.56 million hectares and 2.45
  (FIGURE 8). From Apr. 21st to May           million hectares in Henan, 1.55
  19th, the wheat areas hit by stripe         times and 1.22 times compared
  rust and powdery mildew have                to the disease-stricken areas
  grown by 3.97 times and 2.05 times          respectively.
  respectively.
                                             In Henan, wheat harvest began in
  Owing to severe drought during Feb.        late May and is estimated to finish in
  and Mar. and large-scale rainfall in       mid-Jun. By Jun. 2nd, the harvested
  recent two months, wheat planting          area has reached 1.69 million
  areas hit by stripe rust and powdery       hectares, accounting for 32.2% of
  mildew have increased remarkably           Henan’s total wheat planting area.
  in Henan. By May       FIGURE 8: Wheat areas hit by stripe rust and powdery mildew, 21 Apr.~19 May (Unit: ‘000 hectares)
  19th, 2009, wheat
  powdery mildew
  has hit accumulatively 2.05         40,000
  million hectares of wheat
                                      35,000
  planting area, up 77.8%
  year on year. Besides,              30,000
  stricken area by wheat
  stripe rust has increased by        25,000
  several times over the same         20,000
  period of 2008, as this
  disease began to spread in          15,000
  Henan in March, about 40
                                      10,000
  days earlier than last year.
                                              May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09
                                                                                       Difenoconazole
  With severe and large-scale
  occurrence of wheat stripe Source: Henan Plant Protection Station



CCM International Limited                                           14                                              www.cnchemicals.com
Fungicide China News Sample - Published by CCM International Ltd
Fungicide China News Sample - Published by CCM International Ltd
Fungicide China News Sample - Published by CCM International Ltd
Fungicide China News Sample - Published by CCM International Ltd
Fungicide China News Sample - Published by CCM International Ltd
Fungicide China News Sample - Published by CCM International Ltd

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Fungicide China News Sample - Published by CCM International Ltd

  • 1. Fungicides China News Vol.2 Issue 6.2009 Copyright © CCM International Limited
  • 2. Fungicides China News Vol.2 Issue 6 Fungicides China News Vol.2 Issue 6, 10 June 2009 Content ■ Overview ������������������������������������������������������������������������������������������������������������ 1 China’s fungicides with self-dominated intellectual property right (I)..............................................................1 ■ Supply and Demand �������������������������������������������������������������������������������������������2 Large demand boosts difenoconazole market ...................................................................................................2 Foreign procurement boosts captan & folpet market ........................................................................................3 Isoprothiolane sales robust ................................................................................................................................4 Hymexazol prosperity in April ...........................................................................................................................4 ■ Price updates ����������������������������������������������������������������������������������������������������� 5 Monthly price of key raw materials in Jun. 2009 .............................................................................................. 5 Monthly factory price of main fungicides in Jun. 2009 ....................................................................................6 Monthly Shanghai port price and FOB Shanghai of main fungicides in Jun. 2009 ......................................... 6 Monthly market price of main crops in Jun. 2009 ............................................................................................ 7 ■ Pricing ��������������������������������������������������������������������������������������������������������������� 7 Most fungicide prices continue downtrend in early June ................................................................................. 7 Jiangsu Chengyang to build 200t/a cyproconazole ..........................................................................................8 ■ Company Dynamics �������������������������������������������������������������������������������������������8 Shanghai carried out a new provision in 1 June ................................................................................................8 Shouguang ShuangXing to build 1,000t/a tebuconazole ..................................................................................9 Jiangsu Taicang to build another 300t/a benomyl technical ......................................................................... 10 Jiangsu Lanfeng’s thiophanate-methyl sees robust demand ..........................................................................11 ■ Raw Material, Intermediates and Additives ����������������������������������������������������� 12 JZPC building 100,000t/a m-xylene ............................................................................................................... 12 ■ Disease ������������������������������������������������������������������������������������������������������������ 13 Potato late blight to prevail in China ............................................................................................................... 13 Serious wheat stripe rust and powdery mildew in Henan ............................................................................... 14 ■ Registration ����������������������������������������������������������������������������������������������������� 15 Fungicide registration in May 2009 .................................................................................................................15 Metalaxyl mixed formulation registration soars in China............................................................................... 16 ■ Policy ��������������������������������������������������������������������������������������������������������������� 17 Shandong to boost 6 fungicide projects ............................................................................................................17 ■ News in brief ���������������������������������������������������������������������������������������������������� 18 Guangdong enters peak season of rice diseases .............................................................................................. 18 Registration situation of flutriafol technical in China ..................................................................................... 18 Wheat leaf rust outbreak in Henan ................................................................................................................. 18 Jiangsu Limin’s 100t/a difenoconazole project to launch in July................................................................... 19 CCM International Limited I www.cnchemicals.com
  • 3. Fungicides China News Vol.2 Issue 6 Headlines of Fungicides Welcome to the June issue of Fungicides China News, China News 0906 published by CCM International, a professional consulting company which has been extensively and intently focusing on dynamics of China’s fungicides industry. This newsletter  China has developed 14 fungicides with self- has covered fungicide market overview, supply & demand, dominated intellectual property right, and price update, company dynamics, policies, registrations, etc. commercially produced most.  Owing to large demand both at home and abroad, difenoconazole technical supply is very tight in May China’s fungicide industry has witnessed fast development 2009. in recent years, especially in 2008, with output growth of 43.1%, to 196,000 tonnes from 137,000 tonnes in 2007.  Some foreign producers have suspended production Meanwhile, the international trade has grown largely. of captan and folpet technical, which will boost production and export of these two export-oriented fungicides in China. This issue covers overview of Chinese fungicides with self-  With the coming of peak season for rice blast control, dominated intellectual property right, supply & demand isoprothiolane production and sales have been of difenoconazole, captan and folpet, isoprothiolane, robust. hymexazol, dynamics of Jiangsu Chengyang, Shouguang Shuangxing, Jiangsu Taicang and Jiangsu Lanfeng,  Hymexazol has enjoyed a promising market since registration and price situation of popular fungicides, April 2009, which has boosted stable production in disease forecast on potato and wheat, etc. domestic market.  Price of most popular fungicides continues to decrease in early June, some even reaching the During 2009 and beyond we will cover a wide variety of lowest level in recent years. topics relevant to China’s fungicides market, including market/consumption dynamics, related policies/legislations,  Jiangsu Chengyang is registering 95% disease dynamics, fungicide production situation, cyproconazole technical and planning to build a 200t/ international cooperation, new products, etc. a cyproconazole technical production line in its new plant located in Nanjing. If there are specific topics you would like to see us cover or  Shouguang Shuangxing is to launch a 1,000t/a would like to investigate any of the subjects covered in more tebuconazole technical production line in the end of detail, please contact us - CCM International. 2009  Jiangsu Taicang plans to build another 300t/a benomyl technical production line in its new plant located in Rugao County, thus expanding its total benomyl capacity to 900t/a.  Jiangsu Lanfeng, the largest thiophanate-methyl Key companies covered in this issue producer with capacity of 4,500~5,000t/a in China, is embracing robust demand at home and abroad.  Jiangsu Zhongxin Petrochemical Company now is building a 100,000t/a m-xylene production line.  Potato late blight has occurred severely in Chongqing and Sichuan by mid May 2009, with stricken area increasing by 87.7% and 37.0% respectively over the same period of last year  Wheat stripe rust and powdery mildew, which occurred more severely in 2009 with large stricken areas, has promoted a remarkable demand growth for triazole fungicides.  Chinese fungicide registrations in May 2009 had a great decrease compared with April. Only 12 fungicide technical were registered.  The registration for Metalaxyl mixed formulations has soared in 2008 and 2009, compared with almost no technical or single formulation registration in the past ten years.  Shandong releases guiding opinions on local pesticide industry and plans to boost 6 fungicide projects. CCM International Limited II www.cnchemicals.com
  • 4. Fungicides China News Vol.2 Issue 6 ■ Overview China’s fungicides with self-dominated intellectual property right (I) C hina has developed 14 fungicides with self-dominated intellectual property right, all of which were FIGURE 2: Structure formula of SYP-Z071 resistance when used with other fungicides. According to field test result of tomato botrytis cinerea registered in the Institute for the control from SYRICI, control effect Control of Agrochemicals, Ministry of 25% SYP-Z048 EC reaches 89.79% of Agriculture (ICAMA), and most with dosage of 400 g(i.a.)/ha., higher of them have been commercially than that of 40% pyrimethanil SC produced by domestic companies. Source: SYRICI and 50% procymidone WP (Pls refer to Fungicides China News 0905, Page In this issue, CCM would like to SYRICI has completed technological 1). introduce 4 of these fungicides, upgrade of SYP-Z071 by launching developed by Shenyang Research a new production line with SYP-1620 Institute of Chemical Industry enestroburin technical capacity of (SYRICI). 10t/a in late 2008. SYRICI can also SYP-1620, a new strobilurin fungicide produce SYP-Z071 formulation: 25% with broad-range of fungicidal SYP-Z071 EC, with capacity of 40t/a. activity, developed by SYRICI in Flumorph 1999, is highly effective in controlling 25% SYP-Z071 EC has better control wheat powder mildew, wheat rust, Flumorph, with CAS name of effect on cucumber downy mildew rice blast, rice false smut, banana leaf 4-[3-(3,4-dimethoxyphenyl)-3-(4- than some traditional fungicides such spot, apple alternaria leaf spot, etc. fluoro-phenyl)-1-oxo-2-propenyl] as mancozeb WP, with application morpholine, is the first fungicide dosage of 100~200g(i.a.)/ha.. And FIGURE 4: Structural formula of with self-dominated intellectual compared with isoprothiolane, 25% SYP-1620 property right in China, developed SYP-Z071 EC has lower risk for by Liu Changling of SYRICI in 1994. fungicide resistance of rice blast. FIGURE 1: Structure formula of SYP-Z048 flumorph SYP-Z048, a new pyridine oxazoline Source: SYRICI fungicide with novel structure (FIGURE 3) and unique action SYP-1620 was firstly produced in mechanism, has good control 2004 in the Pilot Plant of SYRICI, the effect on crop diseases induced by only producer in the world. SYRICI Source: SYRICI ascomycetes, basidiomycetes and developed its first formulation, deuteromycetes, such as botrytis 5% SYP-1620 EC in 2006, and Flumorph has been granted cinerea on tomato and cucumber. started commercial production of patents both in China and the U.S. another formulation, 20% SYP- Commercial production of this FIGURE 3: Structural formula of 1620·tebuconazole SC this year. fungicide started in 1999, using SYP-Z048 catechol as starting raw material. It is Up to now, SYRICI has obtained four mainly used to control Peronospora Chinese patents and one American and Phytophthora diseases, such patent for SYP-1620 since 1999, as downy mildew on cucumber, including a Chinese patent for cabbage and grape, phytophthora 20% SYP-1620·tebuconazole SC blight on pepper and tomato, etc., (ZL03134025.3). with application dosage of 150g(a.i.)/ Source: SYRICI ha. SYP-1620 has been promoted SYP-Z048, with broad-spectrum and well in the control of wheat self-dominated intellectual property powder mildew and banana leaf Enestroburin (SYP-Z071) right, is highly effective in controlling spot, in Shandong province and various crop diseases, such as South China respectively, with Enestroburin, with test number of cucumber scab, cotton fusarium wilt, commercial production of 20% SYP- SYP-Z071, is a strobilurin fungicide wheat scab, grape brown spot and 1620·tebuconazole SC in 2008. with broad spectrum and long- botrytis cinerea. lasting preventive and curative Resemble to the development of activity, developed by SYRICI and SYP-Z048 is especially effective in SYP-Z071, SYRICI has also completed granted Chinese patent. botrytis cinerea control, compared technological upgrade of SYP-1620 by with such fungicides as pyrimethanil launching a new production line with and procymidone. In addition, technical capacity of 10t/a. SYP-Z048 won’t lead to cross CCM International Limited 1 www.cnchemicals.com
  • 5. Fungicides China News Vol.2 Issue 6 Comments period (1995-2000). at the field test stage by SYRICI, with test numbers of SYP-3375, SYP-3343, China is making great efforts in SYRICI, as the first comprehensive SYP-3759. pesticide independent innovation, R&D unit for China’s chemical with pesticide development listed industry, has contributed a lot in CCM will continue to introduce in the Guideline of Medium- and developing China’s pesticide industry. other fungicides with self-dominated Long-Term Program for Science and Except for the above 4 fungicides intellectual property right in China in Technology (2006-2020). China with Chinese patents having been next issue. started to build National Pesticide R commercially produced, there are & D Centers in the 9th Five-year plan other 3 fungicides being developed or ■ Supply and Demand Large demand boosts difenoconazole market O wing to large demand both at home and abroad, difenoconazole technical supply is very tight in Chinese market in May 2009, which has largely boosted kasugamycin · copper oxychloride WP, 10% difenoconazole WG and 20% thiediazole copper SC. Therefore, more peasants would use 10% difenoconazole its market. WDG, thus boosting difenoconazole. In China, most large manufacturers have no Meanwhile, large demand from overseas is another difenoconazole technical storage at present, due to its important factor boosting tight supply of difenoconazole tight supply in recent months. technical. As Table 1 shows, Green Agrosino and Shandong Dongtai export 70% of their difenoconazole According to Mr. Yang, sales manager from Beijing Green to overseas markets, such as Vietnam, while Shouguang Agrosino Company (Green Agrosino), the company’s ShuangXing exports 50% of its difenoconazole output. difenoconazole technical supply is very tight and is not According to Ms. Liu, difenoconazole technical are well able to satisfy new orders until Jun. 2009. sold both in domestic and overseas market at present. And Shandong Shouguang ShuangXing Pesticide Company (Shouguang ShuangXing) isn’t able to satisfy With difenoconazole technical tight supply in Chinese new difenoconazole technical orders until late Jun. 2009, market, many companies have registered its technical according to Ms. Liu, sales manager from the company. and formulations. Difenoconazole were the most popular fungicide registered in Apr. 2009 (Pls refer to Fungicides Tight supply of difenoconazole technical is mainly due to China News 0905, P15). Besides, some companies like the following three reasons: Shouguang ShuangXing are expending their capacity/ output. According to Ms. Liu, Shouguang ShuangXing With pesticide consumption entering peak season in will expend its difenoconazole technical output to 20t/ China at present, especially in South China, domestic month in H2 2009. demand for difenoconazole technical is very large, as most difenoconazole formulation producers in China are busy However, difenoconazole price has reduced to producing. According to Shandong Dongtai Agrochemical USD32,178/t in early May, compared with USD35,103/ Company, the company sells difenoconazole technical t in May 2008, as shown in Figure 5, mainly due to the very well in economic crop planting regions in the south global financial crisis. It is predicted that difenoconazole of China. technical supply will continue to be tight in the near future, as fruit disease occurrence will be severe in recent Besides,� 10% difenoconazole WDG is among the months, which may drive its price up in near future. four formulations recommended by National Agro- Tech Extension and Service Center (NATESC) in Difenoconazole, a systemic fungicide with broad Mar. 2009, which include 2% kasugamycin AS, 47% spectrum, provides long-lasting preventive and TABLE 1: Current production situation of major difenoconazole technical producers Production Output Capacity (t/ Production Export Producers (t/ a) status proportion month) Beijing Green Agrosino Company 200 15 Tight 70% Shandong Dongtai Agrochemical Company 300 20 Tight 70% Jiangsu Sevencontinent Green Chemical Company N/A 10 Normal N/A Shandong Shouguang ShuangXing Pesticide Company 300 10 Tight 50% Source: Shanghai metal website CCM International Limited 2 www.cnchemicals.com
  • 6. Fungicides China News Vol.2 Issue 6 curative activity against ascomycetes, basidiomycetes difenoconazole EC and 37% difenoconazole WDG are and deuteromycetes, including alternaria, ascochyta, most commonly used single formulations in China, cercospora, cercosporidium, colletotrichum, guignardia, while difenoconazole + propiconazole is the major mycosphaerella, rhizoctonia, septoria, uncinula, etc. difenoconazole mixed formulation. At present, 10% difenoconazole WDG, 25% TABLE 1: Current production situation of major difenoconazole technical producers 40,000 35,000 30,000 25,000 20,000 15,000 10,000 May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09 Difenoconazole Source: CCM International Foreign procurement boosts captan & folpet market S ome foreign producers have suspended technical production of captan and folpet, which is to boost production and export of these two export-oriented fungicides in China. Captan and folpet are broad-spectrum fungicides used to control various vegetable diseases, such as downy mildew, powdery mildew and anthracnose, as well as early blight and late blight of tomato and potato. The two fungicides have the same capacity in China, as they can be produced by the same production line. Captan and folpet are export-oriented fungicides, with most of the output exported to Europe, South America, South Africa, etc. Yingde Greatchem Chemicals Company (Yingde Greatchem) is producing technical of captan and folpet tightly at present thanks to large demand from overseas. It won’t accept new orders until mid June 2009, according to Mr. Bi, sales manager from the company. Ningbo Zhenhai Hodak Agrochemicals Company (Ningbo Zhenhai Hodak) and Zhejiang Rayfull Holding Company (Zhejiang Rayfull) only produce these two products by orders. Technical supply of captan and folpet is tight in China at present, as some foreign producers have suspended production due to capital shortage caused by global financial crisis. Besides, with higher production cost in the overseas, many formulation processors would like to import technical from China to reduce production cost. Both of these aspects has boosted captan and flopet demand. It is predicted that captan and folpet are expected to have a promising market in near future. Currently, some companies, such as Yingde Greatchem, are expanding technical capacity of captan and folpet in order to satisfy the large export. According to Mr. Bi, Yingde Greatchem will double its captan technical capacity in Aug. ~ Sep.2009. TABLE 2: Technical export situation of captan and folpet Company Capacity (t/a) Export destination France, Spain, Turkey, Suriname, Lithuania, Changzhou Pangu Chemical Company 800~900 South Africa Ecuador, Guatemala, Ukraine, Jordan, Dominican Ningbo Zhenhai Hodak Agrochemicals Company 600~700 Rep, Chile, South Africa Yingde Greatchem Chemicals Company 500~600 Spain, South Africa, Europe, South America Zhejiang Rayfull Holding Company 400~500 Europe, South America Source: CCM International CCM International Limited 3 www.cnchemicals.com
  • 7. Fungicides China News Vol.2 Issue 6 Isoprothiolane sales robust W ith the coming of peak season for rice blast occurrence since late Apr. 2009, isoprothiolane application volume mainly depends on disease degree, so isoprothiolane demand mainly depends as well. Isoprothiolane technical produced by Zhejiang Linghua Industry Company production and sales have been is not sold in the market. The robust in China. China has currently 3 major company uses the product itself to isoprothiolane technical producers, produce 30% and 40% isoprothiolane Rice blast has occurred seriously about 40 single formulation EC. in Fujian, Guangdong, Guangxi, producers and more than 30 Jiangxi and Hunan at present, due mixed formulation producers, with However, Hunan Hengyang to favorable temperature and large- technical capacity of 10,000t/a, Roymaster Bio-pesticide Company scale adoption of non-resistant rice output of 5, 000t/a and demand of suspended isoprothiolane production varieties this year. China has entered 1,000~2,000t/a at present. to focus on glyphosate in H2 2008, the peak season for rice blast control according to Ms. Lin from the (Pls refer to Fungicides China News As Table 3 shows, Sichuan Academy company. 0905, P13). and Sichuan Chuandong are producing isoprothiolane technical As for price of isoprothiolane In China, three kinds of fungicides, tightly. According to Ms. Yuan, technical, it has reduced to including tricyclazole, isoprothiolane director from Guanghan Testing USD4,270/t in early May from and iprobenfos, are commonly Workshop of Sichuan Academy, USD 5,400/t in 2008, mainly due used to control rice blast, among isoprothiolane is under short supply to significant price drop of raw which tricyclazole is mainly for rice both at home and abroad currently. materials. Isoprothiolane sales blast prevention, iprobenfos for volume is expected to rise this year, both prevention and treatment and Sichuan Chuandong exports 60% as more growers will be able to offer isoprothiolane for treatment. of its isoprothiolane output to the lower price and rice blast occurrence overseas, such as Southeast Asia. Its situation is severe this year with Isoprothiolane is an organic domestic market has also started up estimated stricken area of 5.60 phosphine fungicide with high thanks to the coming of peak season million hectares. efficacy against rice blast. Occurrence for isoprothiolane sales, according of rice blast mainly depends on to Mr. Zheng, manager from the weather, while isoprothiolane company. TABLE 3: Current production situation of isoprothiolane technical producers Output (t/month) Production Company status Sichuan Academy of Chemical Industry Research & Design (Sichuan Academy) 300~400 Tight Sichuan Chuandong Agrochemicals Company(Sichuan Chuandong) 80 Tight Zhejiang Linghua Industry Company (Zhejiang Linghua) 40~50 Normal Hunan Hengyang Roymaster Bio-pesticide Company (Hengyang Roymaster) 0 Suspended Source: CCM International Hymexazol prosperity in April A fter the slack demand from late 2008 to early 2009, hymexazol has enjoyed a promising market since this April, as the peak season for rice seedling blight hydrochloride, raw materials for hymexazol technical production, have kept stable in terms of price and supply recently. Accordingly, price of hymexazol technical occurrence (June and July) is coming. Despite the gloomy remained relatively stable in May, going down slightly export, robust domestic demand still promotes stable from 25,000USD/t in Jan. to 23,500USD/t, when a production of hymexazol technical. majority of pesticides witnessed serious price drop in H1 2009. Hymexazol has enjoyed a thriving market both at home and abroad in 2008 and is expected to enjoy a promising Currently, 99% hymexazol technical becomes more and market in the future years. more popular in China, while 95% and 97% technical still dominate the overseas market. The producers begin to Besides, with increasing demand of hymexazol in pay more attention to domestic market and promote 99% domestic market, methyl acetoacetate and Hydroxylamine hymexazol technical to foreign users (Table 4). CCM International Limited 4 www.cnchemicals.com
  • 8. Fungicides China News Vol.2 Issue 6 Hymexazol, a systemic fungicide decompose into compounds with low According to Mr. Zhang, sales with high efficacy and low toxicity, toxicity. manager from Weifang Tianda is usually used as a soil disinfectant Plants Protection Co., Ltd, with by binding with iron and aluminum Relevant news link: Hymexazol registration in May 2008 and ions to inhibit germination of spores. market promising in China technical innovation in late 2008, Hymexazol can be absorbed by and (Fungicides Newsletter 0902, Page 2, the company has started to produce transfer across plant roots, and by CCM International) 99% hymexazol technical in large generate two glucosides in plants scale and achieved good sales in early to improve physiological activity of In China, hymexazol had witnessed 2009. The company has hymexazol crops, thus promoting crop growth a thriving market both at home and technical capacity of 200t/a. Its and root tillering, increasing root abroad in 2008, and was expected export proportion in the total output hair and improving root activity. to have a promising market in the reduces to 25% in May from 60% in future years. To satisfy the future Jan. 2009 (Table 4). As a broad-spectrum fungicide, demand in the peak season from hymexazol has good effects Apr. to Sep. 2009, most Chinese Mr. Li, salesman from Shandong against various crops diseases hymexazol technical producers have Qiaochang Chemical Co., Ltd, induced by fusarium, pythium spp, continued production even in slack claimed that the company still mainly rhizoctonia, etc, especially for the season, from late 2008 to early 2009. produces 95% hymexazol technical, control of seedling blight on rice as 99% technical hasn’t been well and sugarbeet and fusarium wilt promoted yet. ‘We still largely rely on on watermelon. It has small effect export at present, but we’re planning on bacteria and actinomycetes in to produce 99% technical and adjust soil, thus exerting little impact on export proportion in the future,’ says microbiological ecology. Besides, it Mr. Li. is environmentally friendly as it can TABLE 3: Current production situation of isoprothiolane technical producers Export proportion Capacity Producer Export destination (t/a) 2009.01 2009.05 Weifang Tianda Plants Protection Company 200 50~60% 20%~30% Southeast Asia, East Europe Shandong Qiaochang Chemical Company 200 60% 45%~55% Middle East, East Europe Source: CCM International ■ Price updates Monthly price of key raw materials in Jun� 2009 Factory price Market price Raw material/ 10 Jun. 2009 10 May 2009 Jun. 2008 10Jun. 2009 10 May 2009 Jun. 2008 intermediates USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t RMB/t 2,6-Dimethyl aniline 12,097 82,700 12,120 82,700 18,747 129,300 12,141 83,000 12,164 83,000 18,798 129,650 Copper oxychloride 4,052 27,700 4,060 27,700 5,314 36,650 4,096 28,000 4,104 28,000 5,365 37,000 Cuprous oxide 6,100 41,700 6,112 41,700 8,939 61,650 6,143 42,000 6,155 42,000 8,989 62,000 M-xylene 1,682 11,500 1,715 11,700 2,269 15,650 1,726 11,800 1,759 12,000 2,320 16,000 Nitrobenzene 790 5,400 791 5,400 1,254 8,650 834 5,700 835 5,700 1,305 9,000 1,2,4-Triazole 5,734 39,200 5,818 39,700 6,909 47,650 5,778 39,500 5,862 40,000 6,959 48,000 Sulphur 88 600 91 620 239 1,650 95 650 106 720 290 2,000 Source: CCM International CCM International Limited 5 www.cnchemicals.com
  • 9. Fungicides China News Vol.2 Issue 6 Monthly factory price of main fungicides in Jun� 2009 10 Jun. 2009 10 May 2009 Jun. 2008 10 Jun. 2009 10 May 2009 Technical Formulation USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t RMB/t Dimethomorph 16,339 111,700 16,810 114,700 18,073 124,650 50% WP 10,122 69,200 10,215 69,700 Chlorothalonil 5,076 34,700 5,305 36,200 5,749 39,650 75% WP 4,198 28,700 4,646 31,700 Mancozeb 3,467 23,700 3,547 24,200 4,299 29,650 80% WP 3,320 22,700 3,400 23,200 Isoprothiolane 4,198 28,700 4,280 29,200 5,604 38,650 - - - - - Carbendazim 3,759 25,700 4,060 27,700 7,054 48,650 50% SC 2,443 16,700 2,521 17,200 Sulphur 351 2,400 366 2,500 1,051 7,250 50% SC 322 2,200 352 2,400 Phosethyl Al 2,516 17,200 2,667 18,200 4,081 28,150 - - - - - Triadimefon 7,855 53,700 8,163 55,700 9,663 66,650 15% WP 1,711 11,700 2,081 14,200 Tebuconazole 14,262 97,500 14,319 97,700 18,798 129,650 - - - - - Tricyclazole 7,562 51,700 7,577 51,700 7,924 54,650 - - - - - Propiconazole 27,748 189,700 30,001 204,700 30,397 209,650 - - - - - Metalaxyl 19,703 134,700 21,207 144,700 26,047 179,650 - - - - - Prochloraz 7,416 50,700 7,577 51,700 11,766 81,150 - - - - - Difenoconazole 32,136 219,700 32,199 219,700 36,196 249,650 - - - - - Propamocarb 6,538 44,700 7,137 48,700 8,141 56,150 - - - - - Source: CCM International Monthly Shanghai port price and FOB Shanghai of main fungicides in Jun� 2009 Shanghai port price FOB Shanghai Shanghai port price 10 Jun. 10 May Technical 10 Jun. 2009 10 May 2009 Jun. 2008 Formulation 10 Jun. 2009 10 May 2009 2009 2009 USD/t RMB/t USD/t RMB/t USD/t RMB/t USD/t USD/t USD/t RMB/t USD/t RMB/t Dimethomorph 16,383 112,000 16,854 115,000 18,124 125,000 15,753 16,205 50% WP 10,166 69,500 10,259 70,000 Chlorothalonil 5,120 35,000 5,349 36,500 5,800 40,000 4,974 5,195 75% WP 4,242 29,000 4,690 32,000 Mancozeb 3,511 24,000 3,591 24,500 4,350 30,000 3,435 3,511 80% WP 3,364 23,000 3,444 23,500 Isoprothiolane 4,242 29,000 4,323 29,500 5,655 39,000 4,135 4,213 - - - - - Carbendazim 3,803 26,000 4,104 28,000 7,104 49,000 3,715 4,002 50% SC 2,487 17,000 2,565 17,500 Sulphur 395 2,700 410 2,800 1,102 7,600 453 468 50% SC 366 2,500 396 2,700 Phosethyl Al 2,560 17,500 2,711 18,500 4,132 28,500 2,525 2,670 - - - - - Triadimefon 7,899 54,000 8,207 56,000 9,714 67,000 7,634 7,930 15% WP 1,755 12,000 2,125 14,500 Tebuconazole 14,306 97,800 14,363 98,000 18,849 130,000 13,765 13,820 - - - - - Tricyclazole 7,606 52,000 7,621 52,000 7,974 55,000 7,354 7,369 - - - - - Propiconazole 27,792 190,000 30,045 205,000 30,448 210,000 26,672 28,828 - - - - - Metalaxyl 19,747 135,000 21,251 145,000 26,098 180,000 18,973 20,412 - - - - - Prochloraz 7,460 51,000 7,621 52,000 11,817 81,500 7,214 7,369 - - - - - Difenoconazole 32,180 220,000 32,243 220,000 36,247 250,000 30,871 30,932 - - - - - Propamocarb 6,582 45,000 7,181 49,000 8,192 56,500 6,374 6,948 - - - - - Source: CCM International CCM International Limited 6 www.cnchemicals.com
  • 10. Fungicides China News Vol.2 Issue 6 Monthly market price of main crops in Jun� 2009 10 Jun. 2009 10 May 2009 Jun. 2008 Crops USD/t RMB/t USD/t RMB/t USD/t RMB/t Wheat 268 1,830 268 1,827 231 1,592 Yellow maize 227 1,554 227 1,546 238 1,639 Peanut Kernel 917 6,267 1,011 6,900 1,179 8,130 Indica rice 404 2,759 404 2,758 393 2,709 Japonica rice 490 3,350 481 3,280 441 3,040 Banana 834 5,700 821 5,600 580 4,000 Cucumber 176 1,200 322 2,200 174 1,200 Apple 878 6,000 806 5,500 797 5,500 Source: CCM International ■ Pricing Most fungicide prices continue downtrend in early June W ith a sustaining downtrend in May, price of most popular fungicides continues to decrease in early June, some even reaching the lowest level in recent years, mainly due to export depression. Price of mancozeb technical, a fungicide with largest capacity in China, has decreased to USD3,511/t in early June, down 2.23% over the previous month. Mancozeb technical supply still exceeds the demand severely in early June, leading to more intense competition and continuous price decrease. It is worthy noting that the downtrend has slowed down, with decrease rate reducing from 5.66% in previous month to 2.23% in early June. Price of carbendazim technical, the largest domestic benzimidazole fungicide, has declined to USD3,803/t in early June, down 7.34% over the previous month, reaching the lowest level in recent years. After the sharp slump from USD6,290/t in Mar. to USD4,242/t in Apr., price of carbendazim technical has dropped slightly, following the sustaining export depression. Chlorothalonil technical price has decreased by 4.29% in June, compared with USD5,349/t in May. The price war was still severe, in which most producers have cut down quotation to capture market share since early 2009. Similarly, price of some triazole fungicides decreased slightly in early June, after a continuous rebound from February to April. Prices of tebuconazole, propiconazole and triadimefon have decreased by 0.41%, 7.50% and 3.75% separately over the previous month, due to the shrinking demand from global market. However, difenoconazole price has maintained the same level with last month, thanks to its wide use range and excellent effect. According to Mr. Zhang from Beijing Green Jixi agrosino Biotech Co., Ltd, the company still busily produces difenoconazole technical though some other pesticides had faced continuous price downtrend. Seeing the promising market, most Chinese producers plan to expand capacity in the near future. The sharp downtrend for prochloraz technical price has stopped in early June, though it still drops slightly compared with last month. Prochloraz technical price has reached the lowest level in recent years to USD7,462, down 2.11% over the previous month. As an export-oriented with 70% output exported, prochloraz technical has witnessed a price drop of 37.8% from USD11,988/t in Dec. 2008,. It is estimated that it will continue to drop in the future. Most fungicide prices haven’t dropped sharply in early June, thanks to the recovery of Chinese economy. However, with the global financial crisis, fungicide market in China still needs some time to recover in the near future. CCM International Limited 7 www.cnchemicals.com
  • 11. Fungicides China News Vol.2 Issue 6 ■ Company Dynamics Jiangsu Chengyang to build 200t/a cyproconazole J iangsu Chengyang Crop Technological Co., Ltd (Jiangsu Chengyang) is applying for technical includes synthesis and refining of onium salts and 1-(4-chlorophenyl)-2-cyclopropyl- abroad. Some producers began to produce cyproconazole technical with small scale in early 2007, though registration of 95% cyproconazole propane. The company produces without registration. With highest technical and planning to build a new onium salts using dimethyl sulfoxide price of more than USD130,000/ 200t/a cyproconazole production line and dimethyl sulfate as raw materials, t, cyproconazole becomes the most and locate it in late 2010. avoiding the stench emitted by expensive fungicide in China. dimethyl sulfide, a raw material used The production line will be built to produce onium salts by traditional History proved that large numbers in its new plant located in Nanjing technology. of people would roll in when a Chemical Industrial Park, together new market shows up. With more with a 200t/a difenoconazole Furthermore, Jiangsu Chengyang and more companies engaging in production line, with total investment uses 1-(4-chlorophenyl)-2- cyproconazole production and large of USD15 million. cyclopropyl-propane as intermediate, impact by global financial crisis, which is much cheaper than cyproconazole price dropped greatly Mr. Xu from Jiangsu Chengyang 4-chlorophenyl-cyclopropyl-methyl- since 2008, down to USD88,000/t claims that the new plant is currently ketone adopted in traditional route. recently. under construction, with the 200t/a Traditional intermediate has so high cyproconazole technical production price mainly because one of its raw When more and more producers line under environmental impact material is very expensive, with price eliminated, the survivals began to assessment. “China has recently no of USD44,000/t. develop new production technology legal registration for cyproconazole and formally apply for registration. technical, though some producers Developed by Clariant Corporation These companies, including Jiangsu have produced and sold this product (previous Sandoz Corporation) in Chengyang, will gradually dominate illegally. This fungicide is expensive, 1985, cyproconazole is a low toxic Chinese cyproconazole technical which generates large room for triazole fungicide with high efficacy production in the near future. profit,’ said Mr. Xu. against powdery mildew, cereal rust, apple scab, etc. According to the report for environmental impact assessment, Domestic cyproconazole production TABLE 1: Domestic registered epoxiconazole technical producers, 2009 Registration Quoted Price Fungicides Company Capacity (t/a) Situation (USD/t) 200 (when Jiangsu Chengyang Crop Technological Co., Ltd Applying N/A finish) Cyproconazole technical Jiangsu Yancheng Limin Chemical Co., Ltd. 150 Applying 95,187 Zhejiang Shangyu Yinbang Chemical Co., Ltd 100 Applying 77,614 Hunan Xiangda Bide Chemical Co., Ltd Stop production N/A 87,865 Source: CCM International production process of cyproconazole is quite novel, although it is mature Shanghai carried out a new provision in 1 June S hanghai newly carried out a provision named ‘Provisions of Shanghai Municipality on Administration of Operation and Application of Pesticide’ on 1 June, 2009, which regulates that distribution of pesticides must be unified and those who purchase highly toxic pesticide must show their ID card. Besides, the provision has suggested a series of measures strengthening safe management of pesticides. CCM International Limited 8 www.cnchemicals.com
  • 12. Fungicides China News Vol.2 Issue 6 Shouguang ShuangXing to build 1,000t/a tebuconazole S handong Shouguang ShuangXing Pesticide Company (Shouguang ShuangXing) is to build a new 1,000t/a tebuconazole technical production line in H2 2009, and Tebuconazole formulations have been promoted well in domestic market in recent years for the control of various crop diseases such as rust, powdery mildew and scab. The expects to launch it in the end of 2009. overseas demand for tebuconazole technical has also kept robust. Therefore, tebuconazole registration has soared This tebuconazole technical production line will be in China since 2008 (referred to Fungicides China News located in Shouguang ShuangXing’s new plant. Mr. Liu, 0905, Page 16), with large production capacity expansion. manager from the company reveals that the new plant is currently under construction, located in Shandong Owing to bright market prospect, the company has Weifang Binhai Economic Development Area. given priority to tebuconazole product development. The company has previously planned to launch several Shouguang Shuangxing will use chlorobenzaldehyde, new production lines for different fungicide technical pinacolone and 1,2,4-triazole purchased from domestic including tebuconazole, difenoconazole, propiconazole producers as major starting raw materials to produce and mancozeb in H2 2009 when the new plant is finished tebuconazole technical. construction. However, with export depression caused by the global financial crisis, the mancozeb technical After the launch of the production line, 60~70% of capacity expansion, from 500t/a to 3,000~5,000t/a has tebuconazole technical produced will be exported to the been postponed, and the schedule for difenoconazole and overseas, including Europe, America and Southeast Asia, propiconazole expansion is uncertain yet. and the remaining will be consumed by itself to process formulations such as 12.5% tebuconazole EW, which will Shouguang ShuangXing, established in 1997, is a be mainly sold in domestic market, according to Mr. Liu. subsidiary of Shandong A & fine Agrochemicals Group. It has hundreds of registration products such as TC, According to a principal from Product Information WP, WDG, EC, EW, ME and SL. Its fungicide products Department of Shouguang Shuangxing, the company is with brand of ‘Shuangxing’, such as propiconazole and now applying for registration of tebuconazole technical, mancozeb, enjoy good reputation among Chinese crop and is expected to obtain the certificate in early 2010. growers. Moreover, Liu claims that construction of this production line is mainly driven by good market prospect of tebuconazole technical and formulations. TABLE 6: Major tebuconazole technical producers in China Company Production capacity (t/a) Jiangsu Zhangjiagang No. 2 Pesticide Factory 3,000 Shanghai Shengnong Pesticide Co., Ltd. 2,000 Jiangsu Sevencontinent Green Chemical Co., Ltd. 1,000 Jiangsu Sheyang Huanghai Pesticide Chemical Co., Ltd. 800 Jiangsu Sword Agrochemicals Co., Ltd. 600 Sinochem Ningbo Chemicals Co., Ltd. 500 Jiangsu Flag Chemical Industry Co., Ltd. 300 Jiangsu Tuoqiu Agrochemicals Co., Ltd. 300 Anhui Huaxing Chemical Co., Ltd. 300 Jiangsu Fengdeng Pesticide Co., Ltd. 100 Jilin Agrochemicals Co., Ltd. Of CNPC Jilin Chemical Group 500 Shandong Huayang Technology Co., Ltd. 300 Jiangsu Bailing Agrochemical Co., Ltd. 200 Shanghai Heben-Eastsun Medicaments Co., Ltd. 150 Source: CCM International CCM International Limited 9 www.cnchemicals.com
  • 13. Fungicides China News Vol.2 Issue 6 Jiangsu Taicang to build another 300t/a benomyl technical J iangsu Taicang Agrochemical Company (Jiangsu Taicang) plans to build another 300t/a benomyl technical production line in its new plant located in Rugao County, and expects to launch it by late 2010, thus expanding its total benomyl capacity to 900t/a. As a systemic fungicide with low toxicity, benomyl has high efficacy against diseases of grain, grape, pip fruits, rice and vegetable caused by ascomycetous, deuteromycetous and some basidiomyctous fungi. Benomyl is a benzimidazole fungicide flourishing in the 1980s, but is not so popular now, due to serious resistance and large dosage. Mr. Gao, sales manager from Jiangsu Taicang, claimed that all benomyl technical produced by the company are exported. With good reputation and high quality, the company received many orders from the overseas. It has a long-term client from Belgium who purchases more than 100 tonnes of benomyl from it every year. With good sales channels, the company plans to expand the capacity. According to the statistics from Institute for the Control of Agrochemicals, Ministry of Agriculture (ICAMA), China has only five registrations for benomyl technical and one is expired at present. Jiangsu Taicang and Jiangsu Lanfeng are the only 2 legal benomyl technical producers in China at present. Other 3 registrants have stopped production, as they haven’t established long-term relationship with overseas companies and can’t sell their product under the global financial crisis. Jiangsu Taicang survives with high product quality, while Lanfeng answers the enemy with low price and large capacity. Mr. Ma, sales manager from Jiangsu Lanfeng, claimed that his company has much bigger workshop than JiangsuTaicang and can reduce production cost by self-producing raw materials, thus being able to offer lower price. Price investigation showed that benomyl technical price kept stable in early 2009, quoted USD10,000/t by Jiangsu Taicang and USD8,800/t by Jiangsu Lanfeng. ‘When the new production line is launched, with larger capacity, we will be able to reduce production cost, thus lowing down the quotation. Aided by high quality we kept all along, our benomyl may dominate Chinese export by then, ‘ Said Mr. Gao from Jiangsu Taicang. Established in 1983, Jiangsu Taicang has technical capacity of 3,000t/a carbendzain, 600t/a benomyl, 3,000t/a glyphosate, 500t/a thiophanate-methyl, 100t/a propiconazol and 300t/a dodine in Taicang County. It is currently building a new plant with 10,000t/a glyphosate, 2,500t/a carbendzain (introduced in CCM’s Fungicides China News 0905), 300t/a benomyl, 500t/a thiophanate-methyl, 50t/a propiconazol, 500t/a dodine, etc. in Rugao County of Jiangsu. TABLE 7: Registration situation of benomyl technical in China A.I. Capacity Export Fungicide Registration period Registration Company Survey Remark content (t/a) Proportion 2009.01.06 --- Jiangsu Taicang Agrochemical Co., Up to 900t/a when the new 95% 600 100% 2009.12.31 Ltd ( Jiangsu Taicang ) line completes 2008.10.17 --- Jiangsu Lanfeng Bio-Chem Co., 95% 1,200 80% N/A 2009.10.17 Ltd ( Jiangsu Lanfeng) Benomyl 2009.01.09 --- Jiangsu Anpon Electrochemical Stop production because of 90% N/A N/A Technical 2009.12.31 Co., Ltd severe pollution 2009.02.20 --- Jinagsu Jiangyin KAJO Stop production several 95% N/A N/A 2009.12.31 Agrochemical Co., Ltd. years ago 2007.03.23 --- Jiangsu Suzhou Worldbest Agro- Stop production several 95% N/A N/A 2008.12.31 (expired) Biochemical Co., Ltd. years ago Source:ICAMA, CCM International CCM International Limited 10 www.cnchemicals.com
  • 14. Fungicides China News Vol.2 Issue 6 Jiangsu Lanfeng’s thiophanate-methyl sees robust demand J iangsu Lanfeng Bio-chem Company (Jiangsu Lanfeng), the largest thiophanate-methyl producer protection policy in Suzhou. It now mainly purchases technical from other companies to process fungicide producers, as there are only two producers, namely Jiangsu Lanfeng itself and Anhui Guangxin with capacity of 4,500~5,000t/ thiophanate-methyl formulations. producing thiophanate-methyl a in China, has witnessed robust in China at present.. And Anhui demand at home and abroad, thanks As for Jiangxi Haili Guixi Pesticide Guangxin is the largest carbendazim to its competitive advantage and & Chemicals Company (Jiangxi producer in China with capacity of higher environmental protection Haili), it produces thiophanate- 15,000t/a who pays more attention requirement released by the methyl technical only by orders and to carbendazim production. government. exports 50% of its output. It has also suspended production now, due to For another, environmental Thiophanate-methyl is a kind of the coming of thiophanate-methyl protection policy in Jiangsu, benzimidazole and broad spectrum slack season, relatively large storage location of Jiangsu Lanfeng is not fungicide used to control various and no purchasing orders, according as strict as that in other regions crop diseases such as wheat scab, to Mr. Xiong, sales manager of the such as Suzhou, location of Suzhou rice sheath blight, apple ring rot and company. Worldbest, so Jiangsu Lanfang cucurbits powdery mildew. needs to spend less in environmental Jiangsu Lanfeng’s thiophanate- protection, which also becomes an China is one of the largest methyl witnesses robust demand advantage for its thiophanate-methyl thiophanate-methyl production mainly thanks to the following production. Suzhou Worldbest countries in the world, with total capacity of about 16,000t/a. At FIGURE 6: Distribution of major thiophanate-methyl technical producers in China present, the 3 largest thiophanate- methyl producers in China include Jiangsu Lanfeng Bio-chem Company (Jiangsu Lanfeng), Anhui Guangxin Agrochemical Group Company (Anhui Guangxin) and Suzhou Worldbest Agro-Biochemical Company (Suzhou Worldbest) (Table 8), with their total capacity reaching about 12,000~13,000t/a, taking up around 80% of total market share. According to Ms. Cai, sales manager from Jiangsu Lanfeng, the company produces thiophanate-methyl all year around thanks to large demand both at home and abroad, except the period for equipment maintenance. It exports 70% of its thiophanate- methyl technical to overseas, such as Source: CCM International America, Europe and Southeast Asia. However, according to Mr. Fan, sales reasons: was the third largest thiophanate- manager from Shandong Huayang For one thing, Jiangsu Lanfeng has methyl producer in China before Science and Technology Company faced less competition from other Beijing Olympic Games, but it has (Shandong Huayang), the company has currently suspended production TABLE 8: Major thiophanate-methyl technical producers in 2009 to update its equipment, aiming to meet the requirement for environmental Production Production Output in Export Production companies capacity (t/a) 2008 (tonne) proportion status protection. Therefore, it has no output in Jiangsu Lanfeng 4,500~5,000 4,000 70% Active 2009 and will resume Anhui Guangxin 3,500~3,800 3,200 60~70% Active production in 2010. Suzhou Worldbest Suzhou Worldbest 4,000 2,000~2,500 0 Stopped has also suspended Shandong Huayang 1,200~1,500 300~500 0 Stopped thiophanate-methyl Jiangxi Haili 1,200~1,500 1,000 0 Stopped technical production at present, due to the stricter environmental Source: CCM International CCM International Limited 11 www.cnchemicals.com
  • 15. Fungicides China News Vol.2 Issue 6 suspended thiophanate-methyl thiophanate-methyl technical and sulfur, its price has decreased technical production due to the strict has witnessed robust demand slightly during Jan. 2009 to May environmental protection policy in from formulation production, 2009, mainly due to the global Suzhou. such as thiophanate-methyl WP, financial crisis, as shown in Figure 6. thiophanate-methyl SC and mixed Though Jiangsu Lanfeng’s formulation production with thiram FIGURE 7: Price change of thiophanate-methyl and carbendazim, Jan. ~ May 2009 (Unit: USD/t) 40,000 35,000 30,000 25,000 20,000 15,000 10,000 May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09 Difenoconazole Source: CCM International ■ Raw Material, Intermediates and Additives JZPC building 100,000t/a m-xylene J iangsu Zhongxin Petrochemical Company (JZPC) now is building a 100,000t/a m-xylene production According to Mr. Sima, principle of this project, the company will adopt Sima expresses that all m-xylene produced by JZPC will be supplied line, and is expected to launch it in a new patent technology to produce to domestic downstream companies. late 2010, which will help to relieve m-xylene, using bottle grade pet, ‘With high product quality and domestic m-xylene short supply in textiles, disinfection solution and m-xylene short supply, our company the future. perfume as raw materials. Sima has signed long-term contract with reveals that this patent technology some domestic companies, ‘ Sima JZPC’s m-xylene project, with total is brought from UOP (the United says. investment of USD99.5 million States) with USD20 million. and coverage area of 163,333m2, M-xylene, a basic chemical raw is located in Lingang Xincheng Moreover, active ingredient content material, is widely applied in the TABLE 9: M-xylene and its downstream pesticides Raw material Intermediate Pesticide Isophthalonitrile Chlorothalonil (Fungicide) M-xylene 2,4-dimethyl ani ine Semiamitraz chloride, amitraz (Insecticide) 2,6-dimethyl aniline Metalaxyl (Fungicide) Source: CCM International Development Zone of Jiangsu. This of m-xylene produced by JZPC will production of pesticides, dyes, project has initiated construction in reach 99.95%, highest among all medicine, pigments, etc. A series Mar. 2009 and is expected to launch the domestic producers. At present, of chemical intermediates, such as in H2 2010, including matching active ingredient content of m-xylene isophthalic acid, isophthalonitrile, 2,4 facilities of 120,000t/a isophthalic produced by Yanshan Petrochemical (2,6)-dimethyl aniline and m-toluic acid production line. Company is 99.50%. acid, can be produced using m-xylene CCM International Limited 12 www.cnchemicals.com
  • 16. Fungicides China News Vol.2 Issue 6 as raw material. Homemade m-xylene is far from meeting demand from its downstream industries. At present, Yanshan Petrochemical Company, with 35,000t/a production capacity, is the only m-xylene producer in China, after Shanghai Petrochemical Company, with 8,000t/a capacity, stopped production in 2006. However, compared with annual domestic m-xylene demand of 106,000 tonnes in 2007 and 141,500 tonnes in 2009(predicted by JZPC), current capacity is far from meeting the demand. As for m-xylene used in downstream fungicide production, the demand from chlorothalonil and metalaxyl production was about 15,000t/a in 2008, and this demand will increase by 4,000~5,000t/a in 2009, with capacity expansion of the two fungicides (Table 10). TABLE 10: Production capacity expansion of chlorothalonil and metalaxyl in China (Unit: t/a) Fungicide Capacity ‘08 Capacity ‘09 Remark Jiangsu Xinyi CAC Chemical Company is to launch Chlorothalonil 13,100 18,100 5,000t/a production line in Jun. or Jul. 2009. Jiangsu Baoling Chemical Company and Zhejiang Heben Pesticide & Chemicals Company expanded by Metalaxyl 1,500 2,500 400t/a and 600t/a in early 2009. Source: CCM International ■ Disease Potato late blight to prevail in China P otato late blight has hit accumulatively 184,600 hectares of planting area in Southwest China with much larger stricken areas compared with the same period of 2008 (Table 11). potato growers’ insufficient efforts on disease control. and Central China by mid May It is predicted that from late May 2009, and is predicted to occur Chongqing is the most severely to early June, potato late blight will severely in East China, North China, stricken region by potato late blight, further expand in Southwest China, Northeast China and Northwest with stricken area of 74,867 hectares Central China and East China. Then China during late May to August this by mid May 2009, accounting for from June to August, the occurrence year, according to National Agro- 36.8% of Chongqing’s total potato will still be severe, since weather Tech Extension and Service Center planting area. The stricken regions forecast from National Climate (NATESC). mainly distribute in mountainous Center shows that rainfall in most regions of Northwest TABLE 11: Occurrence situation of potato late blight in China (Unit: hectare) China, North China and Northeast China Region Stricken area by mid May 2009 Change over last year will be more abundant than normal years, Chongqing 74,867 Up 87.7% year on year which is favorable for Sichuan 36,667 Up 37.0% year on year occurrence and spread Yunnan 1,533 A little severe than last year of potato late blight. Guizhou 16,000 Down 36.0% year on year Owing to forecasted Hubei 40,000 N/A severe occurrence Hunan 7,400 N/A of late blight in Shaanxi 8,133 N/A China’s major potato planting regions, some Source: NATESC traditional fungicide formulations with In mid May, potato late blight has areas with low altitude of Chongqing, high control effect and low toxicity, occurred severely in some major and are estimated to expand fast such as 80% mancozeb WP, 65% potato production regions of in the future months, due to the zineb WP and 4% metalaxyl-M + Southwest China and Central China, favorable weather condition, the 64% mancozeb WDG, are expected especially in Chongqing and Sichuan, high seed transmission rate, and to enjoy market growth in domestic CCM International Limited 13 www.cnchemicals.com
  • 17. Fungicides China News Vol.2 Issue 6 market, thanks to their excellent performance in potato PICTURE 1: Potato and its leaves hit by late blight late blight control and relatively low price. However, as for the new fungicides against potato late blight, like azoxystrobin, cyazofamid and fluazinam, their domestic demand will stay at a low level in the future years, since their promotion will still be difficult due to the high price. Aim to control potato late blight and promote treatment technology, NATESC held a National Potato Late Blight Prevention Conference from 23 April to 24 April 2009 in Jinan city, Shandong province. Serious wheat stripe rust and powdery mildew in Henan W heat stripe rust and powdery mildew, two key wheat diseases, have occurred severely this rust and powdery mildew, consumption of related fungicides has risen largely PICTURE 2: Wheat powdery mildew year in Henan, with stricken areas this year. Triazole fungicides, of 1.01 million hectares and 2.05 including triadimefon, million hectares by May 19th, 2009, tebuconazole, flutriafol, accounting for 19.1% and 39.0% propiconazole, etc, have enjoyed respectively of Henan’s total wheat a remarkable demand growth planting area. for their good control effect against these two diseases. In Henan is the largest wheat particular, domestic demand for production region in China, with total triadimefon, the most popular planting area of 5.26 million hectares, triazole fungicide applied in accounting for 22.8% of China’s total. China, has grown by more than 70% in Henan. According to the monitoring data PICTURE 3: Wheat stripe rust from Henan Plant Protection Station, By May 19th, 2009, accumulative the stricken areas by wheat stripe control areas to wheat stripe rust rust and powdery mildew have kept and powdery mildew have reached increasing since late Apr. 2009 1.56 million hectares and 2.45 (FIGURE 8). From Apr. 21st to May million hectares in Henan, 1.55 19th, the wheat areas hit by stripe times and 1.22 times compared rust and powdery mildew have to the disease-stricken areas grown by 3.97 times and 2.05 times respectively. respectively. In Henan, wheat harvest began in Owing to severe drought during Feb. late May and is estimated to finish in and Mar. and large-scale rainfall in mid-Jun. By Jun. 2nd, the harvested recent two months, wheat planting area has reached 1.69 million areas hit by stripe rust and powdery hectares, accounting for 32.2% of mildew have increased remarkably Henan’s total wheat planting area. in Henan. By May FIGURE 8: Wheat areas hit by stripe rust and powdery mildew, 21 Apr.~19 May (Unit: ‘000 hectares) 19th, 2009, wheat powdery mildew has hit accumulatively 2.05 40,000 million hectares of wheat 35,000 planting area, up 77.8% year on year. Besides, 30,000 stricken area by wheat stripe rust has increased by 25,000 several times over the same 20,000 period of 2008, as this disease began to spread in 15,000 Henan in March, about 40 10,000 days earlier than last year. May-08 Jun-08 Jul-08 Aug-08 Sep-08 Oct-08 Nov-08 Dec-08 Jan-09 Feb-09 Mar-09 Apr-09 May-09 Difenoconazole With severe and large-scale occurrence of wheat stripe Source: Henan Plant Protection Station CCM International Limited 14 www.cnchemicals.com