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Copycat!
Nature has Some Amazing Nanoscience Feats
           …or Should We Say ‘Feets’.

         Studying the water strider’s
         nanogroovy setules on its toes has
         inspired scientists to design
         miniature aquatic devices and non-
         wetting materials.



          Water strider leg hairs and grooves on one hair.
Help, my pads
                    Eight-Legged Note Pads
      are stuck!
                    • The strength of the suction in a spider’s foot is due
                      to all of the small van der Waals forces at the
                      nanoscale pulling at the same time.

                    • So, why isn’t it stuck in one place? It lifts its leg so
                      that the setules lift successively, not all at once.

                    • This suggests to scientists that, in the future, super-
                      strong Post-it® notes, modeled after the
                      nanoscience of spider toes, will need to be pulled
                      off very slowly, a little at a time.
                                                                           My pads are
                                                                           stuck, too!

Hairy spider toes                     Setules on hairs
And..
                               Using nanoscience and the van der Waals
                               force, future Post-it® notes won’t just be
                               strong, they’ll even stick if they got wet
                               or greasy.

    Imagine astronauts using the same idea for spacesuits
    that help them stick to the walls
    of a spacecraft,just like a spider
    on the ceiling."
                                                    I hope they
                                                    invent that
                                                     suit soon!

http://www.eurekalert.org/pub_releases/2004-04/iop-smb041504.php
Clean as a…

• Gecko feet can stick to
                                               Gecko?
  seemingly smooth
  surfaces thanks to
  nanoscale setules on
  their feet; and the setules
  are self cleaning.

• This bonding capability is
  inspiring scientists to
  develop a synthetic
  adhesive that is both dry
  and self-cleaning.
                                                 SEM image of the polymer fibrillar adhesive fabricated at the NanoRobotics
http://pubs.acs.org/cen/critter/gecko1.html      Laboratory, CMU
A Material Stronger than Steel
     and More Elastic than Nylon?


For 450 million years, spiders have made silk, protein-
based nanomaterials that self-assemble into fibers and
sheets.

•If we figure out how to copy this nanscience feat,
scientists would like to use the material to create an
elevator to space.

•Does that sound like a good idea to you?
http://www.newscientist.com/article.ns?id=dn3522
Color in Butterfly Wings




Butterfly wing scales in increasing magnitude




    Butterfly wings are layers of nanoparticles seperated by
    layers of air. The thickness of the layers changes the
    colors that we see.


http://www.ntcresearch.org/pdf-rpts/AnRp05/M03-MD14-A5.pdf
http://pubs.acs.org/cen/critter/butterfly.html
http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
How Do We Mimic
             Wing Colors?
The layered nanostructure of the butterfly
wing inspires scientists to develop textiles
by assembling nanoparticles into layers
from the ‘bottom up’.
Living LED’s
      Butterflies figured out how to
      emit light 30 million years ago.




                    Fluorescent patches on the wings of this
                     Fluorescent patches on the wings of this
                    African swallowtail butterflies work in a very
                     African swallowtail butterflies work in a very
                    similar way to high emission light emitting
                     similar way to high emission light emitting
                    diodes (LEDs).
                     diodes (LEDs).




http://news.bbc.co.uk/2/hi/science/nature/4443854.stm
Butterfly Nanostructure Inspiration
Depending on what you need, these nanoparticles might be
made into flourescent proteins, DNA, viruses, or dyes. The
ideas are endless!

       These flourescent nanoscale polymer fibers might be used to
       reflect visible, UV and IR radiation for cooling or transmit certain
       wavelengths of light for warming.



               If made into optical chemical or stress sensing nanofibers, they
               can be added into other materials and structures.




                    They can also used for bar coding or other functions.



    http://www.ntcresearch.org/pdf-rpts/AnRp05/M03-MD14-A5.pdf
Look,
                                   Wings are Colorful
        Mom,
      I’m dry!                     and Hydrophobic!
                                                                       Water droplet




                                                           Notice the butterfly’s wing
                                                          in the picture isn’t getting
                                                          wet?

                                                           The butterfly can thank its
                                                          lucky stars or, better yet, its
                                                          nanoscales.


More information can be found on the web at http://www.exploratorium.edu/ronh/bubbles/bubbles.htm .
Activities can be found at http://www.lessonplanspage.com/ScienceExAddPenniesToFullGlassMO68.htm or
http://www.iit.edu/~smile/ph9205.html



  http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
As the Saying Goes…
 “Like Water Off of a Duck’s Back…

  Or a Butterfly’s Wing!




                                                                     This picture shows water
                                                                     droplets on a wood surface
                                                                     treated with "Lotus Spray“,
     The white bar on this                 The white bar on this     a nanotechnology product
     picture of a butterfly wing           nanoscopic view of a      modeled after the butterfly
     is 1mm long.                          butterfly wing is 1 µm.   wing and lotus leaf, which
                                                                     has made the surface
                                                                     extremely water-repellant
http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
                                                                     (superhydrophobic).
http://nanotechweb.org/articles/news/1/11/5/1/0611102
…and Dirt Off of a Butterfly’s Wing!”


          Besides repelling water
          (hydrophobic), the
          nanoscales make butterfly
          wings self-cleaning.
                                            Water droplet




 http://www.nanotechnic-germany.com/lotuseffect.htm
 http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
How These Surfaces Work
Because of the nanostructures on                                                     This magnified image shows the
a butterfly wing or other                                                            nanostructures on a wing surface. Because of
hydrophobic surface, a waterdrop                                                     the waxiness of the surface, the waterdrop
forms into a ball, rolling from the                                                  rolls – rather than slides – down the surface
                                                                                     with little friction. The drop collects dirt and
surface and taking the dirt with it.
                                                                                     bacteria on its way, and in effect cleans itself.


                                                                                     Nanostructures, (tiny waxy "spikes“), on the
                                                                                     surface prevent a water droplet from reaching
Bu                                                                                   the underlying material. It rolls off the waxy
   t   te
            rfl                                                                      tips which are very small compared to the
                y
                    wi
                       n   g
                               or
                                                                                     water droplet. The force of the rolling water is
                                    su
                                         pe                                          greater than the force of attraction between
                                            r-h
                                                  yd                                 the surface and dirt or bacteria which allows it
                                                     ro
                                                        p   ho                       to be washed away.
                                                              bi
                                                                   c
                                                                       su
                                                                          rfa
                                                                                ce


                                                  = water
                                                  = dirt
Science Copies Self-Cleaning Nanoproperties!
   Scientists are copying this process                                                Since I can’t
                                                                                    take a bath, it’s
   with self cleaning hydrophobic                                                   a good thing I’m
                                                                                     self-cleaning!
   micro-dots.




An excellent video demonstrates how
this works at
http://www.nanogreensciences.com/index.html


  http://www.ntcresearch.org/projectapp/index.cfm?project=C04-CL06&topic=progress
Wouldn’t It Be Nice If…?

…more materials could be


        self-cleaning?




                         water repellant?




     Can you think of some?
Nanoscience Uses for
                                 Bioluminescence
                                             •Biological imaging
Detection of cancers                         •Red is particularly useful
                                             because it can transmit
                                             through skin better than
                                             green light.
                                                                              Measuring rate
                                                                              of cell
                                                                              multiplication
               Pathogen detection




Tracing tumor
growth
                                                               Food testing. Bacteria contain ATP that
                                                               accelerates the firefly’s
                                                               bioluminescence reaction. This makes
                                    Drug screening
                                                               it especially good for quickly detecting
                                                               bacterial contamination in food.
 http://pubs.acs.org/cen/science/84/8414biolum.html
Squid Lights
 Remember those squid
 belly nanoplatelets that
 reflect the light of
 bioluminescent bacteria?




                                                        Those Squid platelets inspire
                                                        nanotechnologists to include
                                                        such protein-based reflectors in
                                                        optical nanodevices.
http://pubs.acs.org/cen/critter/critterchemistry.html
Toucan Beaks
                                 •The nanostructure of
                                 toucan beaks inspires
                                 automotive panels that could
                                 protect passengers in crashes.

                                 • And inspires construction of
                                 ultralight aircraft
                                 components.




http://pubs.acs.org/cen/critter/critterchemistry.html
Thirsty?
                            Living in the desert the thirsty Namib
                            beetle collects dew to drink using
                            nanodots on its back.




 So What can Thirsty People Do?
Thirsty people in Chile and Haiti
go to ridgetops to collect fog on
large sheets on ridgetops.
                                                                  But as we learn about
                                                                  nanoscience in nature…
      http://biomechanics.bio.uci.edu/_html/nh_biomech/namib/beetle.htm
      http://www.treehugger.com/files/2005/04/clean_water_fro.php
We have Nanotechnology Solutions!
                                                                              You’re
                     Scientists are modeling                                  welcome!
                     water harvesting surfaces
                     after the Namib beetle’s
                     nanotechnique.

The Namib Beetle’s design is also a model for other
nanotechnology:
 1. controlled drug release coatings,
 2. open-air microchannel
    devices, and
 3. lab-on-chip devices.
                                                                 Patterned Superhydrophobic Surfaces: Toward a
                                                                 Synthetic Mimic of the Namib Desert Beetle Lei
                                                                 Zhai, Michael C. Berg, Fevzi Ç. Cebeci, Yushan Kim, John M. Milwid,
                                                                 Michael F. Rubner, and Robert E. Cohen Nano Lett.; 2006; 6(6) pp 1213
   http://www.treehugger.com/files/2005/04/clean_water_fro.php   - 1217;
   http://www.treehugger.com/files/2006/06/biomimicry_nami.php   http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/nl060644
`
Don’t You Want to Mimic My Nanopowers?
                               Ok, hippo sweat is
                               -a sunscreen,
                               -hydrophilic
                               -and antibacterial.



 It sounds like promising nanoscience. But, personally, I’m
 having a little trouble getting excited about smearing
      something called hipposudoric acid on my body!




       Can you think of interesting ways to use this
       nanoscience or to make it sound more appealing?
                                   http://pubs.acs.org/cen/news/8222/8222notw9.html
Nanoscience Biomimicry
We’ve looked at ways scientists are attempting to mimic the
wonders of nanoscience in nature:
•sticky “feet”
   •strong spider silk

      •self-cleaning light reflecting butterfly wings

         •optical nanoscience

                 •water collecting beetle backs

                    •tough and light toucan beaks

                         •and the list could go on and on.
Your SuperPower Idea
These ideas have been copied
and modified by science fiction
and cartoonists for decades.


 Now it is your turn to delve into
 the world of superheros and                                                   SuperHipp
 supervillains.                                                                 o to the
                                                                                rescue!




                      Take a nanoscience idea from nature.
                      Create a superbeing or supertool that has a special
                      power based on this nanoscience idea.
                      Develop a visual aid and presentation to share
                      with the class.
  http://www.theforce.net/fanfilms/software/3dstudiomax/romanlasers_tutorial/index.asp
  http://news.bbc.co.uk/2/hi/science/nature/4443854.stm
Superpower or Nanopower Copycats?
  Spiderman uses the
  nanoscience of spider silk. Is
  this the only way that Spidey
  uses nanoscience?



         What other superheros could
         be using some of these
         nanoscience ideas to achieve
         their feats?


                  A database of biomimicry may help you find ideas.
                  The following database includes some examples of
                  mimicry that are NOT nanoscale so be careful to
                  select an idea that is based in nanoscience.
                  http://www.biomimicry.net/case_studies.html

         If you don’t feel you are ready to start on your project yet and
         want more clarification or help. Click here for five more slides.

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Biomimicryppt2

  • 2. Nature has Some Amazing Nanoscience Feats …or Should We Say ‘Feets’. Studying the water strider’s nanogroovy setules on its toes has inspired scientists to design miniature aquatic devices and non- wetting materials. Water strider leg hairs and grooves on one hair.
  • 3. Help, my pads Eight-Legged Note Pads are stuck! • The strength of the suction in a spider’s foot is due to all of the small van der Waals forces at the nanoscale pulling at the same time. • So, why isn’t it stuck in one place? It lifts its leg so that the setules lift successively, not all at once. • This suggests to scientists that, in the future, super- strong Post-it® notes, modeled after the nanoscience of spider toes, will need to be pulled off very slowly, a little at a time. My pads are stuck, too! Hairy spider toes Setules on hairs
  • 4. And.. Using nanoscience and the van der Waals force, future Post-it® notes won’t just be strong, they’ll even stick if they got wet or greasy. Imagine astronauts using the same idea for spacesuits that help them stick to the walls of a spacecraft,just like a spider on the ceiling." I hope they invent that suit soon! http://www.eurekalert.org/pub_releases/2004-04/iop-smb041504.php
  • 5. Clean as a… • Gecko feet can stick to Gecko? seemingly smooth surfaces thanks to nanoscale setules on their feet; and the setules are self cleaning. • This bonding capability is inspiring scientists to develop a synthetic adhesive that is both dry and self-cleaning. SEM image of the polymer fibrillar adhesive fabricated at the NanoRobotics http://pubs.acs.org/cen/critter/gecko1.html Laboratory, CMU
  • 6. A Material Stronger than Steel and More Elastic than Nylon? For 450 million years, spiders have made silk, protein- based nanomaterials that self-assemble into fibers and sheets. •If we figure out how to copy this nanscience feat, scientists would like to use the material to create an elevator to space. •Does that sound like a good idea to you? http://www.newscientist.com/article.ns?id=dn3522
  • 7. Color in Butterfly Wings Butterfly wing scales in increasing magnitude Butterfly wings are layers of nanoparticles seperated by layers of air. The thickness of the layers changes the colors that we see. http://www.ntcresearch.org/pdf-rpts/AnRp05/M03-MD14-A5.pdf http://pubs.acs.org/cen/critter/butterfly.html http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
  • 8. How Do We Mimic Wing Colors? The layered nanostructure of the butterfly wing inspires scientists to develop textiles by assembling nanoparticles into layers from the ‘bottom up’.
  • 9. Living LED’s Butterflies figured out how to emit light 30 million years ago. Fluorescent patches on the wings of this Fluorescent patches on the wings of this African swallowtail butterflies work in a very African swallowtail butterflies work in a very similar way to high emission light emitting similar way to high emission light emitting diodes (LEDs). diodes (LEDs). http://news.bbc.co.uk/2/hi/science/nature/4443854.stm
  • 10. Butterfly Nanostructure Inspiration Depending on what you need, these nanoparticles might be made into flourescent proteins, DNA, viruses, or dyes. The ideas are endless! These flourescent nanoscale polymer fibers might be used to reflect visible, UV and IR radiation for cooling or transmit certain wavelengths of light for warming. If made into optical chemical or stress sensing nanofibers, they can be added into other materials and structures. They can also used for bar coding or other functions. http://www.ntcresearch.org/pdf-rpts/AnRp05/M03-MD14-A5.pdf
  • 11. Look, Wings are Colorful Mom, I’m dry! and Hydrophobic! Water droplet Notice the butterfly’s wing in the picture isn’t getting wet? The butterfly can thank its lucky stars or, better yet, its nanoscales. More information can be found on the web at http://www.exploratorium.edu/ronh/bubbles/bubbles.htm . Activities can be found at http://www.lessonplanspage.com/ScienceExAddPenniesToFullGlassMO68.htm or http://www.iit.edu/~smile/ph9205.html http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
  • 12. As the Saying Goes… “Like Water Off of a Duck’s Back… Or a Butterfly’s Wing! This picture shows water droplets on a wood surface treated with "Lotus Spray“, The white bar on this The white bar on this a nanotechnology product picture of a butterfly wing nanoscopic view of a modeled after the butterfly is 1mm long. butterfly wing is 1 µm. wing and lotus leaf, which has made the surface extremely water-repellant http://jbe.jlu.edu.cn/free/v1/i4/207.pdf (superhydrophobic). http://nanotechweb.org/articles/news/1/11/5/1/0611102
  • 13. …and Dirt Off of a Butterfly’s Wing!” Besides repelling water (hydrophobic), the nanoscales make butterfly wings self-cleaning. Water droplet http://www.nanotechnic-germany.com/lotuseffect.htm http://jbe.jlu.edu.cn/free/v1/i4/207.pdf
  • 14. How These Surfaces Work Because of the nanostructures on This magnified image shows the a butterfly wing or other nanostructures on a wing surface. Because of hydrophobic surface, a waterdrop the waxiness of the surface, the waterdrop forms into a ball, rolling from the rolls – rather than slides – down the surface with little friction. The drop collects dirt and surface and taking the dirt with it. bacteria on its way, and in effect cleans itself. Nanostructures, (tiny waxy "spikes“), on the surface prevent a water droplet from reaching Bu the underlying material. It rolls off the waxy t te rfl tips which are very small compared to the y wi n g or water droplet. The force of the rolling water is su pe greater than the force of attraction between r-h yd the surface and dirt or bacteria which allows it ro p ho to be washed away. bi c su rfa ce = water = dirt
  • 15. Science Copies Self-Cleaning Nanoproperties! Scientists are copying this process Since I can’t take a bath, it’s with self cleaning hydrophobic a good thing I’m self-cleaning! micro-dots. An excellent video demonstrates how this works at http://www.nanogreensciences.com/index.html http://www.ntcresearch.org/projectapp/index.cfm?project=C04-CL06&topic=progress
  • 16. Wouldn’t It Be Nice If…? …more materials could be self-cleaning? water repellant? Can you think of some?
  • 17. Nanoscience Uses for Bioluminescence •Biological imaging Detection of cancers •Red is particularly useful because it can transmit through skin better than green light. Measuring rate of cell multiplication Pathogen detection Tracing tumor growth Food testing. Bacteria contain ATP that accelerates the firefly’s bioluminescence reaction. This makes Drug screening it especially good for quickly detecting bacterial contamination in food. http://pubs.acs.org/cen/science/84/8414biolum.html
  • 18. Squid Lights Remember those squid belly nanoplatelets that reflect the light of bioluminescent bacteria? Those Squid platelets inspire nanotechnologists to include such protein-based reflectors in optical nanodevices. http://pubs.acs.org/cen/critter/critterchemistry.html
  • 19. Toucan Beaks •The nanostructure of toucan beaks inspires automotive panels that could protect passengers in crashes. • And inspires construction of ultralight aircraft components. http://pubs.acs.org/cen/critter/critterchemistry.html
  • 20. Thirsty? Living in the desert the thirsty Namib beetle collects dew to drink using nanodots on its back. So What can Thirsty People Do? Thirsty people in Chile and Haiti go to ridgetops to collect fog on large sheets on ridgetops. But as we learn about nanoscience in nature… http://biomechanics.bio.uci.edu/_html/nh_biomech/namib/beetle.htm http://www.treehugger.com/files/2005/04/clean_water_fro.php
  • 21. We have Nanotechnology Solutions! You’re Scientists are modeling welcome! water harvesting surfaces after the Namib beetle’s nanotechnique. The Namib Beetle’s design is also a model for other nanotechnology: 1. controlled drug release coatings, 2. open-air microchannel devices, and 3. lab-on-chip devices. Patterned Superhydrophobic Surfaces: Toward a Synthetic Mimic of the Namib Desert Beetle Lei Zhai, Michael C. Berg, Fevzi Ç. Cebeci, Yushan Kim, John M. Milwid, Michael F. Rubner, and Robert E. Cohen Nano Lett.; 2006; 6(6) pp 1213 http://www.treehugger.com/files/2005/04/clean_water_fro.php - 1217; http://www.treehugger.com/files/2006/06/biomimicry_nami.php http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/nl060644
  • 22. ` Don’t You Want to Mimic My Nanopowers? Ok, hippo sweat is -a sunscreen, -hydrophilic -and antibacterial. It sounds like promising nanoscience. But, personally, I’m having a little trouble getting excited about smearing something called hipposudoric acid on my body! Can you think of interesting ways to use this nanoscience or to make it sound more appealing? http://pubs.acs.org/cen/news/8222/8222notw9.html
  • 23. Nanoscience Biomimicry We’ve looked at ways scientists are attempting to mimic the wonders of nanoscience in nature: •sticky “feet” •strong spider silk •self-cleaning light reflecting butterfly wings •optical nanoscience •water collecting beetle backs •tough and light toucan beaks •and the list could go on and on.
  • 24. Your SuperPower Idea These ideas have been copied and modified by science fiction and cartoonists for decades. Now it is your turn to delve into the world of superheros and SuperHipp supervillains. o to the rescue! Take a nanoscience idea from nature. Create a superbeing or supertool that has a special power based on this nanoscience idea. Develop a visual aid and presentation to share with the class. http://www.theforce.net/fanfilms/software/3dstudiomax/romanlasers_tutorial/index.asp http://news.bbc.co.uk/2/hi/science/nature/4443854.stm
  • 25. Superpower or Nanopower Copycats? Spiderman uses the nanoscience of spider silk. Is this the only way that Spidey uses nanoscience? What other superheros could be using some of these nanoscience ideas to achieve their feats? A database of biomimicry may help you find ideas. The following database includes some examples of mimicry that are NOT nanoscale so be careful to select an idea that is based in nanoscience. http://www.biomimicry.net/case_studies.html If you don’t feel you are ready to start on your project yet and want more clarification or help. Click here for five more slides.