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Tips on How to Simplify VOC
Monitoring and Set Up a
Successful Network
Since 2002 American Ecotech has been serving industrial and
government customers throughout the USA
• Systems integration & deployment
• Onsite operational training
• Remote maintenance support
Specializing in :
Rack-mountable VOC analyzers designed for PAMS Fenceline monitoring systems
All other types of ambient air monitoring instruments Shelters, trailers, and all
support infrastructure associated with ambient air monitoring turn-key systems
VOC Monitoring
•Methane Non-Methane
•BTEX
•C6 – C12
•PAMS
What will you learn from this Webinar
1. What is PAMS?
2. GC pre-concentrator management, maintenance and
functions
3. Common mistakes when setting up a calibration
system
4. Getting Data from the GC Monitors
Polling Question
What application of VOC monitoring do you most have a need for ?
BTEX
PAMS
C6 – C12
Methane Non-Methane
Total VOC’s
Other
An Overview and Brief History
of PAMS
Photochemical Assessment
Monitoring Stations
VOC Measurement Technologies
Canisters vs Auto-GCs
• Data averaged over sampling period
• Low Capital Cost
• Reoccuring lab costs
• Need for manual labor
• Hourly data
• Higher Capital costs
• Higher skill level required to run the system
About PAMS
new auto-GCs have been developed that
provide near real-time data, designed for
use in ambient air monitoring stations
About PAMS
Photochemical Assessment Monitoring Stations
US Environmental Protection Agency (EPA)
• Revised Ambient AQ Surveillance Regulations
• Effective February 12, 1993
 In 1998 the EPA commissioned a study using PAMS to determined if there was a change in
ambient VOCs as a result of the introduction of Reformulated Gas in 1995. The result were
positive showing a reduction in Benzene related the reduction in the fuel.
 The revisions required states and local monitoring agencies to establish Photochemical
Assessment Monitoring Stations (PAMS) in ozone nonattainment areas classified as
serious, severe, or extreme
 Monitoring agencies are given options to measure VOCs using either an automated Gas
Chromatograph (auto-GC) or collect samples in the field and analyze them in a laboratory.
 When the PAMS program was originally implemented, field rugged auto-GCs were not
available, so many monitoring agencies had to rely upon canister sampling and/or very
complex laboratory GCs equipped with automatic samplers.
• April 1998 - EPA's Office of Mobile Sources commissioned a contractor to look at
PAMS data to investigate if changes in ambient VOC levels were related to the
introduction of reformulated gas in 1995.
• The report concluded that there is a strong case that a reduction in ambient
benzene was related to the reduction of benzene in fuel and that other species,
such as aromatics, may also have been significantly reduced.
• These findings are consistent with observations in EPA's "National Air Quality and
Emissions Trends Reports" for both 1995 and 1996.
Current design calls for up to 5 sites in
each PAMS area
Type 1 Upwind
Type 2 Max emissions
Type 3 Max ozone
Type 4 Extreme Downwind
•PAMS Season June-August
SIP Control Strategy Evaluation: Evaluation of the effectiveness of State
implemented plans control strategies.
Emissions Tracking:
• Corroboration of NOx and VOC inventories Trends of VOC species source profiles
• Analysis of air toxics.
Ambient Trend Appraisals:
• O3
• NOx
• Total and speculated VOC
• Adjustments in meteorological conditions.
Exposure Assessment: Estimation of risk levels and the size of effected populations.
The principal objectives of the PAMS program can be summarized as follows:
NAAQS Attainment and Control Strategy Development:
• Attainment / Nonattainment determinations
• Assessment of the relative contributions of local and upwind sources
• boundary conditions for photochemical modeling
What Does a PAMS
Consist of?
A PAMS Monitoring System
A PAMS Monitoring System
A PAMS Monitoring System
A PAMS Monitoring System
A PAMS Monitoring System
A PAMS Monitoring System
Pre - Concentrator
Operation and
Maintenance
The purpose of the pre concentrator is to sample the ambient and get the most even
and consistent sample. It helps to evens out the air when spikes or other air related
event might arise. An example is that there is a spike of Methane when the more
consistent air is mixing with it and averaging the air for that hour.
The Pre Concentrator works on a three hour sampling cycle
The main purpose of the Pre Concentrator is to:
• Heat the air
• Creating a sample that is an average of the hour of sampling
At the end of hour 1 of sampling tube #1 opens and releases the cumulative sample
To the GC
The ambient air collected in hour 2 begins to flow into tube #2 for heating
Pre Concentrator Operation and Maintenance
The same process that took place in tube#1 in Hour 2 happens in Tube #2
Components of AQM-PAMS-Alert
Pre-Concentrator – diagram 1
Components of AQM-PAMS-Alert
Pre-Concentrator – diagram 2
Components of AQM-PAMS-Alert
Pre-Concentrator – diagram 3
Components of AQM-PAMS-Alert
Pre-Concentrator – diagram 4
Components of AQM-PAMS-Alert
Pre-Concentrator - diagram 5
Components of AQM-PAMS-Alert
Pre-Concentrator - diagram 6
Calibration
Take the time warm up the system ( 30 mins / 1 hour )
Match up the proper gases
Most calibrations can be done with a single point
Pay attention to Column efficiency
FID Chromatogram
FID Analysis
• Ethane
• Ethylene
• Propane
• Propylene
• Isobutane
• N-butane
• Trans-2-butane
• 1-butane
• Cyclopentane
• Cis-2-butene
• Isopentane
• N-pentane
• Tran-2-Pentane
• 1-Pentane
• Cis-2-Pentane
• 2,2-Dimethylbutane
• 2,3-Dimethylbutane
• 2-/3-
Methylpentane
• Isoprene
Peaks listed in elution order
PID Chromatogram
PID Analysis
• N-Hexane
• Methylcyclopentane
• 2,4-Dimethylpentane
• Benzene
• Cyclohexane
• 2-Methylhexane
• 3-Methylhexane
• 2,2,4-Trimethylpentane
• N-Heptane
• Methylcyclohexane
• 2,3,4-Trimethylpentane
• Toluene
• 2-Methylheptane
• 3-Methylheptane
• N-octane
• Ethylbenzene
• M-/P-Xylene
• Styrene
• O-Xylene
• N-Nonane
• Isopropylbenzene
• N-Propylbenzene
• M-Ethyltoluene
• P-Ethyltoluene
• 1,3,5-
Trimethylbenzene
• O-Ethyltoluene
• 1,2,4-
Trimethylbenzene
• N-Decane
• 1,2,3-
Trimethylbenzene
• M-Diethylbenzene
• P-Diethylebenzene
• N-Undecane
• N-Dodecane
Peaks listed in elution order
Getting data from the GC Monitor
Sample takes an hour to gather
The air that is gathered in Hour 1 is available in the second hour
Field Deployment Options
Instrumentation
• Gas Chromatographs for VOC PAMS
• Hydrocarbon Analyzers including NMHC
• Small VOC Sensors
• Fenceline networked sensor systems
• Hand Held VOC Detectors
• Criteria Pollutant Analyzers
• Particulate Samplers (PM2.5, PM10)
• Nephelometers
• Pb Samplers
• Shelters/Trailers/Mobile Vans
• Dataloggers
• Data Validation/Remote Maint software
Thank You
info@AmericanEcotech.com
Tel: 1-877-247-2403

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American Ecotech VOC PAMS Webinar

  • 1. Tips on How to Simplify VOC Monitoring and Set Up a Successful Network
  • 2. Since 2002 American Ecotech has been serving industrial and government customers throughout the USA • Systems integration & deployment • Onsite operational training • Remote maintenance support Specializing in : Rack-mountable VOC analyzers designed for PAMS Fenceline monitoring systems All other types of ambient air monitoring instruments Shelters, trailers, and all support infrastructure associated with ambient air monitoring turn-key systems
  • 4. What will you learn from this Webinar 1. What is PAMS? 2. GC pre-concentrator management, maintenance and functions 3. Common mistakes when setting up a calibration system 4. Getting Data from the GC Monitors
  • 5. Polling Question What application of VOC monitoring do you most have a need for ? BTEX PAMS C6 – C12 Methane Non-Methane Total VOC’s Other
  • 6. An Overview and Brief History of PAMS Photochemical Assessment Monitoring Stations
  • 7. VOC Measurement Technologies Canisters vs Auto-GCs • Data averaged over sampling period • Low Capital Cost • Reoccuring lab costs • Need for manual labor • Hourly data • Higher Capital costs • Higher skill level required to run the system
  • 8. About PAMS new auto-GCs have been developed that provide near real-time data, designed for use in ambient air monitoring stations
  • 9. About PAMS Photochemical Assessment Monitoring Stations US Environmental Protection Agency (EPA) • Revised Ambient AQ Surveillance Regulations • Effective February 12, 1993  In 1998 the EPA commissioned a study using PAMS to determined if there was a change in ambient VOCs as a result of the introduction of Reformulated Gas in 1995. The result were positive showing a reduction in Benzene related the reduction in the fuel.  The revisions required states and local monitoring agencies to establish Photochemical Assessment Monitoring Stations (PAMS) in ozone nonattainment areas classified as serious, severe, or extreme  Monitoring agencies are given options to measure VOCs using either an automated Gas Chromatograph (auto-GC) or collect samples in the field and analyze them in a laboratory.  When the PAMS program was originally implemented, field rugged auto-GCs were not available, so many monitoring agencies had to rely upon canister sampling and/or very complex laboratory GCs equipped with automatic samplers.
  • 10. • April 1998 - EPA's Office of Mobile Sources commissioned a contractor to look at PAMS data to investigate if changes in ambient VOC levels were related to the introduction of reformulated gas in 1995. • The report concluded that there is a strong case that a reduction in ambient benzene was related to the reduction of benzene in fuel and that other species, such as aromatics, may also have been significantly reduced. • These findings are consistent with observations in EPA's "National Air Quality and Emissions Trends Reports" for both 1995 and 1996. Current design calls for up to 5 sites in each PAMS area Type 1 Upwind Type 2 Max emissions Type 3 Max ozone Type 4 Extreme Downwind •PAMS Season June-August
  • 11. SIP Control Strategy Evaluation: Evaluation of the effectiveness of State implemented plans control strategies. Emissions Tracking: • Corroboration of NOx and VOC inventories Trends of VOC species source profiles • Analysis of air toxics. Ambient Trend Appraisals: • O3 • NOx • Total and speculated VOC • Adjustments in meteorological conditions. Exposure Assessment: Estimation of risk levels and the size of effected populations. The principal objectives of the PAMS program can be summarized as follows: NAAQS Attainment and Control Strategy Development: • Attainment / Nonattainment determinations • Assessment of the relative contributions of local and upwind sources • boundary conditions for photochemical modeling
  • 12. What Does a PAMS Consist of?
  • 19. Pre - Concentrator Operation and Maintenance
  • 20. The purpose of the pre concentrator is to sample the ambient and get the most even and consistent sample. It helps to evens out the air when spikes or other air related event might arise. An example is that there is a spike of Methane when the more consistent air is mixing with it and averaging the air for that hour. The Pre Concentrator works on a three hour sampling cycle The main purpose of the Pre Concentrator is to: • Heat the air • Creating a sample that is an average of the hour of sampling
  • 21. At the end of hour 1 of sampling tube #1 opens and releases the cumulative sample To the GC The ambient air collected in hour 2 begins to flow into tube #2 for heating
  • 22. Pre Concentrator Operation and Maintenance The same process that took place in tube#1 in Hour 2 happens in Tube #2
  • 29. Calibration Take the time warm up the system ( 30 mins / 1 hour ) Match up the proper gases Most calibrations can be done with a single point Pay attention to Column efficiency
  • 31. FID Analysis • Ethane • Ethylene • Propane • Propylene • Isobutane • N-butane • Trans-2-butane • 1-butane • Cyclopentane • Cis-2-butene • Isopentane • N-pentane • Tran-2-Pentane • 1-Pentane • Cis-2-Pentane • 2,2-Dimethylbutane • 2,3-Dimethylbutane • 2-/3- Methylpentane • Isoprene Peaks listed in elution order
  • 33. PID Analysis • N-Hexane • Methylcyclopentane • 2,4-Dimethylpentane • Benzene • Cyclohexane • 2-Methylhexane • 3-Methylhexane • 2,2,4-Trimethylpentane • N-Heptane • Methylcyclohexane • 2,3,4-Trimethylpentane • Toluene • 2-Methylheptane • 3-Methylheptane • N-octane • Ethylbenzene • M-/P-Xylene • Styrene • O-Xylene • N-Nonane • Isopropylbenzene • N-Propylbenzene • M-Ethyltoluene • P-Ethyltoluene • 1,3,5- Trimethylbenzene • O-Ethyltoluene • 1,2,4- Trimethylbenzene • N-Decane • 1,2,3- Trimethylbenzene • M-Diethylbenzene • P-Diethylebenzene • N-Undecane • N-Dodecane Peaks listed in elution order
  • 34. Getting data from the GC Monitor Sample takes an hour to gather The air that is gathered in Hour 1 is available in the second hour
  • 36. Instrumentation • Gas Chromatographs for VOC PAMS • Hydrocarbon Analyzers including NMHC • Small VOC Sensors • Fenceline networked sensor systems • Hand Held VOC Detectors • Criteria Pollutant Analyzers • Particulate Samplers (PM2.5, PM10) • Nephelometers • Pb Samplers • Shelters/Trailers/Mobile Vans • Dataloggers • Data Validation/Remote Maint software