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Enhanced Functionality on Plastic Using
         Inkjet Technology
                                  Kasper Nossent
                             R&D Sales Manager
                         Xennia Technology Ltd

                               SPE ANTEC 2011
                               Boston, May 2011
Talk Outline

 Introduction to Xennia
 What is inkjet printing?
 Inkjet Drivers & Benefits
 Challenges
 Industrial Solutions
 Application Examples
 Conclusion
Section 1
INTRODUCTION TO XENNIA
Xennia helps customers lower
   operating costs, increase productivity
 and simplify mass customised production
by revolutionising manufacturing processes
BACKGROUND

 Xennia is the world’s leading industrial inkjet solutions provider
 14 year history, over 300 customer development programs
 World class reputation underpinned by a strong IP portfolio
 Unique expertise in inkjet chemistry with strong engineering capability
 Headquartered in UK, offices in US and China
 Received the Queens Award in 2010


 Offering reliable inkjet process solutions:
     Inkjet modules and inks for OEM partners with market access
     Printing systems and inks for end users
FROM INKJET IDEAS ...
TO PRODUCTION REALITY




ink formulation & test   evaluation tools   system design   production solutions
Xennia develops & supplies inkjet systems, modules
         and inks for industrial applications
Section 2
What is Inkjet Printing?
What is Inkjet Printing?

 A mechanism for controlled ejection of discrete drops of fluid
 Examples of actuation mechanisms:
     Deformation of piezoelectric crystals
     Thermal expansion of bubbles
 Effectively analogous to a fountain pen, except much smaller!
     Drop volumes1-80 pL
What is Inkjet Printing?

        Ink channel
                         Nozzle           Ligament     Satellite

Pressure wave                                                                     Substrate

                        Ejecting ink

 Drop formation                        Drop ejection   Drop travel         Drop on substrate



      Drop formation controlled by:                         Determined by a complex
                                                            interplay of:
            Rheology
                                                                   Chemical functionalities
            Surface tension
                                                                   Polymer structure
            Viscoelasticity
                                                                   Particle size and shape
What is Inkjet Printing?

                      Low surface              Medium surface            High surface
                        tension                   tension                  tension
Ink behaviour
on substrate
         Surface tension of ink relative to surface energy of substrate controls
         behaviour of ink drops on substrate
         Printed features are built-up drop by drop
         Ability to fine tune morphology of printed features by adjusting ink
         properties

     UV-cured ink                                                UV-cured ink
      on plastic                                                  on copper
What is Inkjet Printing?


      Liquid carrier       Surfactants


   Binders/                     Adhesion
  bulk matrix                  promoters



   Rheology                       Other
   modifiers                     additives


       Functional          Colorants
       materials
What is Inkjet Printing?

Effect of
particles

                     Same size as               Slightly smaller           Much smaller than
                       nozzles                   than nozzles                  nozzles

      Nozzles typically 20-30 m in diameter
      Particles in inkjet inks typically sub-micron
            Development of inkjet inks has been reliant on the development of
            nanoparticulates
      Key area of experience is producing stable particle dispersions
            High density particles tend to settle and reduce reliability
            Settling prevention - ink formulation and/or recirculating printhead technology
What is inkjet Printing?

     Substrate?                      End-user?                  Processing?
 Porous     Non-porous                 Adhesion                  Line speed
  Paper      Polymer               Scratch resistance            Temperature
 Polymer      Metal                Solvent resistance           UV sensitivity
 Textile      Glass                Tensile properties           Environmental




                         Aqueous                    Oil-based

                                     Ink Types
           Solvent-based                                   Phase change
                                     UV-curable
What is Inkjet Printing?

                       Waveform and drive voltage



                                           Flow through the nozzle




 Droplet formation and jet stability



                        Image quality and durability
What is Inkjet Printing?


   Adhesives                                     Inorganic pigments
   Abrasive materials                            Inorganic phosphors and lanthanides
   Aggressive acids and alkali materials         Magnetic materials (MICR)
   Anti-scratch materials/clear coats            Media coating materials
   Biomedical antibodies, reagents and enzymes   Metal solutions and dispersions
   Bronze, aluminium and molybdenum powders      OLED and LEP materials
   Ceramic pigments                              Organic soluble and dispersed dyes
   Colloidal and emulsion materials              Sintered metals and ceramics
   Conductive graphite                           Textile pigments and dyes
   Conductive metals                             Titanium dioxide
   Conductive polymers                           Ultra high purity materials
   Decorative metallic pigments                  UV cure pigment inks
   Electrochromic materials                      UV cure structural polymers
                                                 UV clear coating
What is Inkjet Printing?
 What inks are available for plastics
      UV, Solvent, Waterbased
           Blends of the above



 Functions available in inks for plastics
      Colour
      Metallic
           Conductive
           RFID
           Aesthetic

      Biofluids
      Tracers
      Security
      Coatings
      Components for solar cells
      Conductive polymers
Section 3
Inkjet Drivers & Benefits
Inkjet Drivers & Benefits

 Key market driver in product decoration
    Need for economic short print runs
    Faster and more frequent product upgrades
    Increased number of niche products
    Increased number of national/regional variations
    Increased demand for personalisation to add value
Inkjet Drivers & Benefits
 Reduced production costs
     Efficient use of consumables
     No requirement to produce new screens/pads
     Short runs are economic
     Cost per print same for 1, 10, 100, 1000, 10,000
     No requirement for inventory
 Increased productivity
     No time for set-up – printer is always printing
 Faster response
     Print on demand
     Just-in-time customisation/personalisation
 Ideal for all types of substrates
Section 4
Challenges
Challenges – Critical areas


Wetting, drying, curing                       Fluid control
                            Ink chemistry




       Substrate                                   Print heads


                          Material handling
     Encoder accuracy                         Drive electronics, software
Challenges

 Challenges can be broken down into
    Ink/substrate


    Image quality


    System
Challenges – Ink
Challenges – Image Quality




                   Original (256 levels)




     Binary Head      7 Level Greyscale
Challenges – Image Quality


 Output from greyscale printhead




  Viewed close –                   Perceived by human eye
  individual dot sizes             from a distance
  visible
Challenges – Image Quality
        Digital                 Variable no. of           Different ink            Directly vary
       halftoning                   drops                  densities               drop volume




Regular screen, dither,       Same ink density, small   Multiple ink densities   Vary waveform according
stochastic                    drops                     Requires multiple        to drop size
Needs very small dot size     Reduces throughput        nozzles - extra cost     Increases head complexity
and high resolution to give   as multiple drops/pixel   Extra ink tanks          No loss of pixel frequency
good results

                          Variable drop volume requires
                              Close printhead manufacturing tolerances
                              Excellent temperature control
                              Well behaved and consistent inks
Challenges – Image Quality
Challenges – System

 Understanding failure modes is key in designing industrial inkjet solutions
    Typical failure modes for inkjet are:
        Nozzle blockages
        Nozzle plate contamination
        Air inclusion
        Drop substrate interaction fails
        Consumable failures (filters, dampers)


    Failure modes to take into account that are non inkjet:
        Mechanical shocks
        Standing waves in piping/beams
        Vibrations (Eigen Frequency)
        Influence of temperature/moisture
        Mechanical deformation/expansion
Challenges - System
Challenges – System

 Typical options to increase reliability of print process
     Spitting nozzles
     Purging
                                                In process
     Wiping nozzle plate
     Capping printheads
     Optimizing ink for the printhead and process and substrate
     Optical systems to detect nozzle failure
     Camera’s to inspect printed product
     Nozzle redundancy                                            Design

     Modular approach
     Redundancy
Section 5
Industrial Solutions
Industrial Solutions

 Balance between
    Quality
    Productivity
    Cost
    Size
    Reliability


 Systems covering a broad range of configurations
    Batch production
    Continuous/web production
    3D printing
    Development/materials deposition
Industrial Solutions

                   600+
                               Desk top thermal and piezo DOD inkjet


                   500                                                    The best compromise
Resolution (dpi)




                                                                          of speed and resolution
                                                                            for most industrial
                                                                               applications
                   400
                                          Industrial piezo DOD inkjet

                   300                                                                          Binary
                                                                                                  continuous
                                                                                                    inkjet
                   200
                                                                        Raster continuous inkjet

                   100
                          50      100       150      200       250       300          350

                                              Speed (m / min)
Industrial Solutions


        Fail and act                              100% Redundant



  Low                       System Cost                         High



  Low                        Efficiency                         High


 The optimal solution should be determined based on the final specification
 of the process
 Understanding the failure modes of the system and the jetting process is a
 key element in the pilot setups
Industrial Solutions




 Print engine

                              Software




          Fluid controllers
Industrial Solutions
Industrial Solutions –
PRODUCT DECORATION PRINTER




Integrated corona pre-treatment
Vacuum platen to secure product(s)
Print width 210mm
Print speed up to 24m/min at 360dpi
Jig can be customised to suit product
Manual load/unload
                                                    210mm
    Can also be integrated into pick & place line
Variable data for barcodes, serial numbers etc.
Re-circulating ink systems ( XenJet Aquarius)
Integrated print software (XenJet Cygnus)
Industrial Solutions
SCANNING XY PRINTER




  Up to 6 colours (2x white)
  Print area 700mm x 1400mm
  Print speed up to 450mm/s at 360dpi
  Throughput up to 100m2/hr
                                                  70mm
  Integrated UV lamps
  Optional vacuum table to secure product(s)
  Optional turntable for easy load/unload
  Re-circulating ink systems ( XenJet Aquarius)
  Integrated print software (XenJet Cygnus)
Industrial Solutions –
FIXED ARRAY NARROW WEB PRINTER




 Roll-to-roll printer
      Compatible with wide variety of flexible substrates
 280mm print width on 300mm web
 Print speed up 24m/min
 Optional corona pre-treat unit              280mm
 Integrated UV cure lamps
 Up to 7 colours/fluids supported
 Re-circulating ink systems ( XenJet Aquarius)
 Integrated print software (XenJet Cygnus)
Industrial Solutions –
3D PRODUCT PRINTER

 5 colours
 Print speed up to 150mm/s at 360 dpi
 35s cycle time for typical object
 Printing onto general 3D surfaces
      CAD data used to generate robot program
 Multi-stage process
 Integrated pre-treatment station
 Integrated vacuum-based maintenance station
 Robot-based product handling system
 Integrated UV pin and full cure
Industrial Solutions –
Xennia Xanadu
Section 6
Application Examples
Application Examples

 Products require decoration for several key reasons:
    Attractive appearance
    Branding
    To provide information
    Colour matching with other parts
    Trademark protection
    Personalisation
Application Examples

   Huge demand for digital decoration of parts on production lines
Key drivers are:
   Reduced costs
       Print on demand means no need for large inventories
   Increased productivity
       Printing system spends the whole time printing
   Faster response to customer demands
       New designs can be introduced rapidly
       Products can be personalised/customised on the fly
Application Examples

3D product Decoration
  Many products have difficult/unusual shapes
     Golfballs, helmets, pens
     Home appliance front covers
     Automotive glass
     Ceramic tableware
  Need to integrate a suitable motion system
     Fast enough for the application
     Accurate/consistent enough to give required print quality
Application Examples


                                                                                         Ceramics
  Textiles                                     Furniture & laminates




                                       Glass
                                                     Product decoration


Wall coverings



                                                               Biotechnology &   Packaging & labelling
                                                               medical
                 Printed electronics
Application Examples


                    Product Decoration &
                         Packaging



   Safety helmets                          Consumer appliance fascias
   Security wristbands                     Promotional gifts
   Identity cards                          Laptops
   Optical fibres                          Mobile phones
   Wires and connectors                    Healthcare products
                                           Toys
                                           etc
Application Examples


      Textiles

                                              Flooring & furniture
 Digital decoration of textiles:                   laminates
     Garment personalisation           Digital decoration of flooring &
     Reel-to-reel textile production   furniture laminates:
     Flags, banners, awnings              Wood-effect flooring
     Soft furnishings                     (Direct printing and laminates)
                                          Furnishings
Application Examples


               Architectural
                  glass


 Digital glass printing applications:   Ceramic tiles & tableware

     Direct print during manufacture
                                        Digital decoration of ceramic tiles
     Print polymer laminate
                                        & tableware:
     Direct print after manufacture
                                            Ceramic wall/floor tiles
                                            Ceramic tableware
                                            Promotional items
Application Examples

                                  Automotive parts




        Wall coverings


 Digital decoration of wall
 coverings:                      Digital decoration of automotive
                                 parts:
     Consumer wall paper
                                    Automotive glass
     Business paper/vinyl wall
     coverings                      Headlamp covers
                                    Motorcycle fairings
                                    Helmets
                                    Spare parts branding
Section 7
Conclusion
Conclusion

 Industrial inkjet is proven
     Systems
     Modular components
     Software is proven


 Ink technology is proven
     Needs to be optimized for the application


 Growing rate of industrial implementation
     Stand alone systems
     Integrated systems
     Replacement of analogue systems
Kasper Nossent
Visit: www.xennia.com
Email: knossent@xennia.com

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Enhanced Functionality On Plastic Using Inkjet Technology

  • 1. Enhanced Functionality on Plastic Using Inkjet Technology Kasper Nossent R&D Sales Manager Xennia Technology Ltd SPE ANTEC 2011 Boston, May 2011
  • 2. Talk Outline Introduction to Xennia What is inkjet printing? Inkjet Drivers & Benefits Challenges Industrial Solutions Application Examples Conclusion
  • 4. Xennia helps customers lower operating costs, increase productivity and simplify mass customised production by revolutionising manufacturing processes
  • 5. BACKGROUND Xennia is the world’s leading industrial inkjet solutions provider 14 year history, over 300 customer development programs World class reputation underpinned by a strong IP portfolio Unique expertise in inkjet chemistry with strong engineering capability Headquartered in UK, offices in US and China Received the Queens Award in 2010 Offering reliable inkjet process solutions: Inkjet modules and inks for OEM partners with market access Printing systems and inks for end users
  • 6. FROM INKJET IDEAS ... TO PRODUCTION REALITY ink formulation & test evaluation tools system design production solutions
  • 7. Xennia develops & supplies inkjet systems, modules and inks for industrial applications
  • 8. Section 2 What is Inkjet Printing?
  • 9. What is Inkjet Printing? A mechanism for controlled ejection of discrete drops of fluid Examples of actuation mechanisms: Deformation of piezoelectric crystals Thermal expansion of bubbles Effectively analogous to a fountain pen, except much smaller! Drop volumes1-80 pL
  • 10. What is Inkjet Printing? Ink channel Nozzle Ligament Satellite Pressure wave Substrate Ejecting ink Drop formation Drop ejection Drop travel Drop on substrate Drop formation controlled by: Determined by a complex interplay of: Rheology Chemical functionalities Surface tension Polymer structure Viscoelasticity Particle size and shape
  • 11. What is Inkjet Printing? Low surface Medium surface High surface tension tension tension Ink behaviour on substrate Surface tension of ink relative to surface energy of substrate controls behaviour of ink drops on substrate Printed features are built-up drop by drop Ability to fine tune morphology of printed features by adjusting ink properties UV-cured ink UV-cured ink on plastic on copper
  • 12. What is Inkjet Printing? Liquid carrier Surfactants Binders/ Adhesion bulk matrix promoters Rheology Other modifiers additives Functional Colorants materials
  • 13. What is Inkjet Printing? Effect of particles Same size as Slightly smaller Much smaller than nozzles than nozzles nozzles Nozzles typically 20-30 m in diameter Particles in inkjet inks typically sub-micron Development of inkjet inks has been reliant on the development of nanoparticulates Key area of experience is producing stable particle dispersions High density particles tend to settle and reduce reliability Settling prevention - ink formulation and/or recirculating printhead technology
  • 14. What is inkjet Printing? Substrate? End-user? Processing? Porous Non-porous Adhesion Line speed Paper Polymer Scratch resistance Temperature Polymer Metal Solvent resistance UV sensitivity Textile Glass Tensile properties Environmental Aqueous Oil-based Ink Types Solvent-based Phase change UV-curable
  • 15. What is Inkjet Printing? Waveform and drive voltage Flow through the nozzle Droplet formation and jet stability Image quality and durability
  • 16. What is Inkjet Printing? Adhesives Inorganic pigments Abrasive materials Inorganic phosphors and lanthanides Aggressive acids and alkali materials Magnetic materials (MICR) Anti-scratch materials/clear coats Media coating materials Biomedical antibodies, reagents and enzymes Metal solutions and dispersions Bronze, aluminium and molybdenum powders OLED and LEP materials Ceramic pigments Organic soluble and dispersed dyes Colloidal and emulsion materials Sintered metals and ceramics Conductive graphite Textile pigments and dyes Conductive metals Titanium dioxide Conductive polymers Ultra high purity materials Decorative metallic pigments UV cure pigment inks Electrochromic materials UV cure structural polymers UV clear coating
  • 17. What is Inkjet Printing? What inks are available for plastics UV, Solvent, Waterbased Blends of the above Functions available in inks for plastics Colour Metallic Conductive RFID Aesthetic Biofluids Tracers Security Coatings Components for solar cells Conductive polymers
  • 19. Inkjet Drivers & Benefits Key market driver in product decoration Need for economic short print runs Faster and more frequent product upgrades Increased number of niche products Increased number of national/regional variations Increased demand for personalisation to add value
  • 20. Inkjet Drivers & Benefits Reduced production costs Efficient use of consumables No requirement to produce new screens/pads Short runs are economic Cost per print same for 1, 10, 100, 1000, 10,000 No requirement for inventory Increased productivity No time for set-up – printer is always printing Faster response Print on demand Just-in-time customisation/personalisation Ideal for all types of substrates
  • 22. Challenges – Critical areas Wetting, drying, curing Fluid control Ink chemistry Substrate Print heads Material handling Encoder accuracy Drive electronics, software
  • 23. Challenges Challenges can be broken down into Ink/substrate Image quality System
  • 25. Challenges – Image Quality Original (256 levels) Binary Head 7 Level Greyscale
  • 26. Challenges – Image Quality Output from greyscale printhead Viewed close – Perceived by human eye individual dot sizes from a distance visible
  • 27. Challenges – Image Quality Digital Variable no. of Different ink Directly vary halftoning drops densities drop volume Regular screen, dither, Same ink density, small Multiple ink densities Vary waveform according stochastic drops Requires multiple to drop size Needs very small dot size Reduces throughput nozzles - extra cost Increases head complexity and high resolution to give as multiple drops/pixel Extra ink tanks No loss of pixel frequency good results Variable drop volume requires Close printhead manufacturing tolerances Excellent temperature control Well behaved and consistent inks
  • 29. Challenges – System Understanding failure modes is key in designing industrial inkjet solutions Typical failure modes for inkjet are: Nozzle blockages Nozzle plate contamination Air inclusion Drop substrate interaction fails Consumable failures (filters, dampers) Failure modes to take into account that are non inkjet: Mechanical shocks Standing waves in piping/beams Vibrations (Eigen Frequency) Influence of temperature/moisture Mechanical deformation/expansion
  • 31. Challenges – System Typical options to increase reliability of print process Spitting nozzles Purging In process Wiping nozzle plate Capping printheads Optimizing ink for the printhead and process and substrate Optical systems to detect nozzle failure Camera’s to inspect printed product Nozzle redundancy Design Modular approach Redundancy
  • 33. Industrial Solutions Balance between Quality Productivity Cost Size Reliability Systems covering a broad range of configurations Batch production Continuous/web production 3D printing Development/materials deposition
  • 34. Industrial Solutions 600+ Desk top thermal and piezo DOD inkjet 500 The best compromise Resolution (dpi) of speed and resolution for most industrial applications 400 Industrial piezo DOD inkjet 300 Binary continuous inkjet 200 Raster continuous inkjet 100 50 100 150 200 250 300 350 Speed (m / min)
  • 35. Industrial Solutions Fail and act 100% Redundant Low System Cost High Low Efficiency High The optimal solution should be determined based on the final specification of the process Understanding the failure modes of the system and the jetting process is a key element in the pilot setups
  • 36. Industrial Solutions Print engine Software Fluid controllers
  • 38. Industrial Solutions – PRODUCT DECORATION PRINTER Integrated corona pre-treatment Vacuum platen to secure product(s) Print width 210mm Print speed up to 24m/min at 360dpi Jig can be customised to suit product Manual load/unload 210mm Can also be integrated into pick & place line Variable data for barcodes, serial numbers etc. Re-circulating ink systems ( XenJet Aquarius) Integrated print software (XenJet Cygnus)
  • 39. Industrial Solutions SCANNING XY PRINTER Up to 6 colours (2x white) Print area 700mm x 1400mm Print speed up to 450mm/s at 360dpi Throughput up to 100m2/hr 70mm Integrated UV lamps Optional vacuum table to secure product(s) Optional turntable for easy load/unload Re-circulating ink systems ( XenJet Aquarius) Integrated print software (XenJet Cygnus)
  • 40. Industrial Solutions – FIXED ARRAY NARROW WEB PRINTER Roll-to-roll printer Compatible with wide variety of flexible substrates 280mm print width on 300mm web Print speed up 24m/min Optional corona pre-treat unit 280mm Integrated UV cure lamps Up to 7 colours/fluids supported Re-circulating ink systems ( XenJet Aquarius) Integrated print software (XenJet Cygnus)
  • 41. Industrial Solutions – 3D PRODUCT PRINTER 5 colours Print speed up to 150mm/s at 360 dpi 35s cycle time for typical object Printing onto general 3D surfaces CAD data used to generate robot program Multi-stage process Integrated pre-treatment station Integrated vacuum-based maintenance station Robot-based product handling system Integrated UV pin and full cure
  • 44. Application Examples Products require decoration for several key reasons: Attractive appearance Branding To provide information Colour matching with other parts Trademark protection Personalisation
  • 45. Application Examples Huge demand for digital decoration of parts on production lines Key drivers are: Reduced costs Print on demand means no need for large inventories Increased productivity Printing system spends the whole time printing Faster response to customer demands New designs can be introduced rapidly Products can be personalised/customised on the fly
  • 46. Application Examples 3D product Decoration Many products have difficult/unusual shapes Golfballs, helmets, pens Home appliance front covers Automotive glass Ceramic tableware Need to integrate a suitable motion system Fast enough for the application Accurate/consistent enough to give required print quality
  • 47. Application Examples Ceramics Textiles Furniture & laminates Glass Product decoration Wall coverings Biotechnology & Packaging & labelling medical Printed electronics
  • 48. Application Examples Product Decoration & Packaging Safety helmets Consumer appliance fascias Security wristbands Promotional gifts Identity cards Laptops Optical fibres Mobile phones Wires and connectors Healthcare products Toys etc
  • 49. Application Examples Textiles Flooring & furniture Digital decoration of textiles: laminates Garment personalisation Digital decoration of flooring & Reel-to-reel textile production furniture laminates: Flags, banners, awnings Wood-effect flooring Soft furnishings (Direct printing and laminates) Furnishings
  • 50. Application Examples Architectural glass Digital glass printing applications: Ceramic tiles & tableware Direct print during manufacture Digital decoration of ceramic tiles Print polymer laminate & tableware: Direct print after manufacture Ceramic wall/floor tiles Ceramic tableware Promotional items
  • 51. Application Examples Automotive parts Wall coverings Digital decoration of wall coverings: Digital decoration of automotive parts: Consumer wall paper Automotive glass Business paper/vinyl wall coverings Headlamp covers Motorcycle fairings Helmets Spare parts branding
  • 53. Conclusion Industrial inkjet is proven Systems Modular components Software is proven Ink technology is proven Needs to be optimized for the application Growing rate of industrial implementation Stand alone systems Integrated systems Replacement of analogue systems