Ponencia TRIZ XXI: EAEC -13 European Automotive Congress – Valencia - Jun 2011

13 º E
European A t
Automotive C
ti Congress – EAEC 2011

THE ROLE OF COMPUTER AIDED KNOWLEDGE TO DISCLOSE
THE RIGHT POWER TECHNOLOGY

Vicente-Gomila, JM y Palop, F “”. EAEC Conference paper 2011

©2011, triz XXI todos los derechos reservados
<informa@triz.es>, www.triz.es

Objectives

1. To show the combination of semantic TRIZ and
TechMining. Its complementarities and results of their
combination.

2. The increasing importance of computer aided knowledge
to understand the cluttered science and technology map.


Index

1.
1 How TRIZ helps to understand next research results
2. Tech-Mining application to lithium batteries elements
3. Combination of semantic TRIZ and TechMining to extract
key research topics
4. Some partial conclusions


1. TRIZ, concepts

A technical system: simplified functional model of lithium battery in the generation state

Powered by GoldfireTM – Invention Machine Corp.


1. TRIZ, concepts

Some Laws of the classic TRIZ for the development of Systems

Statics Cinematics Dynamics
Law of consolidation Law of increasing Dynamization
y
ideality
Law of conductivity Law of rithms
of the system Law of uneven coordination
gy
energy development of
p
Law of i
L f increasing
i
system parts
controlability
Law of transition
to the
supersystem
Law of transition
from macro to
micro


1. TRIZ, concepts

Trend towards control and governance by fields

Prototipo de dirección
eléctrica, de ZF y Robert Bosch.


1. TRIZ, concepts

Hybridization as a TRIZ 'concept' and the hybrid battery-supercapacitor

“This system that we have gives you capacitor-like power with battery-like energy," said U Illinois' Paul
Braun, a professor of materials science and engineering. "Most capacitors store very little energy. They can
release it very fast, but they can't hold much. Most batteries store a reasonably large amount of energy, but
they can't provide or receive energy rapidly. This does both."
Source: Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes; Nature Nanotechnology Year
published: (2011) DOI: doi:10.1038/nnano.2011.38 Received 21 October 2010 Accepted 24 February 2011 Published online 20 March
2011


1. TRIZ, concepts

The braking of a car: a contradiction

Brake At short
I brake strong
g distance

loose
Control, guidance
etc.

Doesn’t brake
Large
distance
I brake slow
Control, id
C t l guidance
etc.
maintains


1. TRIZ, concepts

The braking of a car: a contradiction

y p


Inventive Principles extracted from patents.

Oxygen diffusion in Li-Air batteries

reprinted from Elsevier ScienceDirect database R. Padbury, X. Zhang / Journal of Power Sources 196 (2011) 4436–4444

Solving a physical contradiction: Separation in space


1. TRIZ, concepts

Fast charge & recharge of EV batteries

reprinted from Gizmag: www.gizmag.com

Solving a physical contradiction: Separation in space,
separating discharging from storage; MIT materials science professors W. Craig Carter and Yet-Ming Chiang
p g g g g ; p g g g


2. Some Tech-Mining results and trends

Research evolution (articles) on Li-ion cathodes. Main research lines.

LiFePO4
disruptive
trend



Selected terms by year in Li-Air: discharge, polymer electrolite, air cathode, non-aqueous
electrolite, hydrophobic eletrolite.
60

50

Discharge

40 Nano
Polymer electrolyte
Aqueous electrolyte
30 Air cathode
Non‐aqueous electrolyte
Hydrophobic
20
Graphene

10 Discharge
Nano
Polymer electrolyte
A l t l t
Aqueous electrolyte
0
Air cathode
2000
2001 Non‐aqueous electrolyte
2002
2003 Hydrophobic
2004
2005
2006 Graphene
2007
2008
Powered by VantagePointTM – Search Technology Inc. 2009
2010


Doping: are we already at 'improving' or still at 'designing'

Li‐ion
Li‐ion 233/6324 Li‐Air 24 /1021
/



Leading
Leading
Cooperation
Cooperation
networks map:
networks map:
Leading
Leading
Research
Research
Institutions in
I I tit titi
Institutionsi in
tit i
Li-S
Li-Air
technology
technology

Powered by VantagePointTM –
Search Technology Inc.



Research Institutions by
Country in Li-air.
y

Powered by VantagePointTM –
Search Technology Inc.


3. Combination of semantic TRIZ and Tech Mining.

Leading companies in patent portfolio and trends in Li-Air

Powered b G ldfi TM – I
P d by Goldfire Invention M hi C
ti Machine Corp.



Example of key activities through the efforts of a leading company in lithiumair, to protect their R & D.

Powered by GoldfireTM –
Invention Machine Corp. ©2011, triz XXI todos los derechos reservados


Problem identification as very early warning signals



Solutions of different industries to the specific problem of oxygen diffusion in lithium
1.addition of metal oxide
Moreover, addition of the metal oxide in the described manner apparently increases the macroporosity and total pore volume of the
activated carbon.
EP-2289609 A1Method for making activated carbon for odor control

2.special treatment
Special treatments have been developed for increasing the pore volume and the specific surface area of activated carbons (T.
Ottawa, R. Tanibata, M. Itoh, G Separation Purification 1993, 7, 241).
O Gas S f )
US-20110005392 A1PROCESS FOR SEPARATION OF CO2 BY PRESSURE-MODULATED ADSORPTION ON A POROUS CARBON
SOLID

3.application of acid treatment with aqueous solution of hydrofluoric acid
It was confirmed that the pore volumes of the porous carbon materials according to the present invention ...the mercury
invention... the
penetration method were significantly increased by the application of an acid treatment with an aqueous solution of hydrofluoric
acid (expressed as “hydrofluoric acid...
US-20100069507 A1Porous Carbon Materials and Production Process Thereof, and Adsorbents, Masks, Adsorbing Sheets and
Carriers

4.thermal activation process
The thermal activation process greatly increases the pore volume and surface area of the carbon particles by elimination of volatile
pyrolysis products and from carbonaceous burn-off.
US-5769933Activated carbon foundry sand additives and method of casting metal for reduced VOC emissions
EP-0813921 A1Foundry sand additive and method of casting metal

5.Mg deposition, decreasing specific surface area of parent carbon
Mg deposition either increases or decreases the specific surface area, pore volume, and average micropore width of the parent
carbon depending on the preoxidation temperatures.
MEDLINE/PubMed Abstracts: Changes in microporosity and CH4 adsorptivity of preoxidized pitch-based activated carbon fibers by
Mg deposition.

Solution to such problem identification as early research directions
.


3. Solution to such problem identification as early research directions.



Graphene uses in articles of lithium air (Source Elsevier)



An example of lithium anode limitations overcome by commercial
solutions : Polyplus.

Pat nº US 7824806 B2


4. CONCLUSIONS.

The mining of thousands of documents and patents can bring
some more rigorous clues of what are the key trends. The main
research line around improving cathode performance with LiFePO4 material was
p g p
identified.

Among emergent technologies was feasible to identify Li-Ar as
the most promising. Leap in articles and patents production indicators in last
years may suggest that Li-Ar is coming from the design to the improvement phase.


4. CONCLUSIONS.

the TRIZ inventive principles and laws come in hand to understand
many of the current limitations and its possible outcome in next
research results.

The usage of Tech Mining d
T h Mi i and syntactic-semantic t l better if
t ti ti tools,
complemented with a knowledge of TRIZ, can short cut the time needed
to analyze what is progressing as well as to ascertain in a more objective
and accurate way the trends identified, based on a vast array of
research, patented inventions and innovation, directions.


Questions?

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t i XXI: V l i Madrid, Floridablanca-Santander, Santiago d Chil Sâo Paulo, Monterrey
S t d S ti de Chile, Sâ P l M t

THANKS!
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Ponencia TRIZ XXI: EAEC -13 European Automotive Congress – Valencia - Jun 2011

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Ponencia TRIZ XXI: EAEC -13 European Automotive Congress – Valencia - Jun 2011