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Atmospheric
Compositions
Composition of the Atmosphere
Air is composed of a mixture of gases:

Gas
N2
O2
Ar

concentration (%)
78
21
0.9

99.9%

Major
constituents
Composition of the Atmosphere
Air is composed of a mixture of gases:

Gas

greenhouse
gases

concentration (%)

N2
O2
Ar
H2O
CO2
CH4
N2O
O3

78
21
0.9
variable
0.037

Minor
constituents
Water Vapor
H2O
Water? Or water vapor?

Water vapor  H2O
 Invisible
 The most abundant greenhouse gas
 Variable, why?
 Only substance is naturally in three phases:
solid, liquid, and a gas

solid

liquid

gas
Composition of the Atmosphere
Air is composed of a mixture of gases:

Gas

greenhouse
gases

concentration (%)

N2
O2
Ar
H2O
CO2
CH4
N2O
O3

78
21
0.9
variable
0.037

Minor
constituents
Carbon Dioxide
CO2
The dashed land-use change line does not include management-climate interactions
The land sink was a source in 1987 and 1998 (1997 visible as an emission)
Source: Le Quéré et al. 2012; Global Carbon Project 2012
Source: Le Quéré et al. 2012; Global Carbon Project 2012
Composition of the Atmosphere
Air is composed of a mixture of gases:

Gas

greenhouse
gases

concentration (%)

N2
O2
Ar
H2O
CO2
CH4
N2O
O3

78
21
0.9
variable
0.037

Minor
constituents
Freon (CFC)
and Ozone (O3)
Freon-11

Freon-12
Refrigerators, air conditioners

Source:
Freons are greenhouse
gases but, more
importantly, they also
affect ozone…
Ozone (O3) production
• Concentrated in
stratosphere (10-50km)
• Produced by absorbing UV
radiation through the
ozone-oxygen cycle:
O2 + UV  O + O,
O + O2  O3
• Ground-level ozone
(troposphere) is created
when intense sunlight
reacts with nitrogen oxides
(NOx) and volatile organic
compounds (VOCs), which
mainly come from vehicles,
power plants, and industrial
facilities.

VOC + NOx +

+

= ozone
Good ozone up high

Bad ozone near by
Ozone (O3) destruction
CFCs: float up to stratosphere and constantly react with O3 to form
ClO and O2:

Cl + O3  ClO+ O2
ClO + O  Cl +O2
Scientists estimate that one chlorine
atom can destroy 100,000
"good" ozone molecules.

The Antarctic ozone hole,
seen from space, Sept. 16,
2000. More Dobson units =
more ozone. Image from
NASA/TOMS

CFCChlorofluorocarbons
CIO chlorine monoxide

Figure 1-6 Simultaneous measurements
of ozone (O3) and chlorine monoxide
(CIO) made from a NASA aircraft as it flew
into the Antarctic ozone hole in
Global average
See The Earth System, ed. 2, of 1-6
Figure 1-6 Simultaneous measurementsFig. ozone (O3) and
chlorine monoxide (CIO) made from a NASA aircraft as it
flew into the Antarctic ozone hole in September 1987.
The Nobel Prize in Chemistry 1995

Paul J. Crutzen
Max-Planck-Institute

Mario J. Molina

F. Sherwood Rowland

MIT

UC Irvine

Paul Crutzen, Mario Molina and Sherwood Rowland have all made
pioneering contributions to explaining how ozone is formed and decomposes through
chemical processes in the atmosphere. Most importantly, they have in this way showed
how sensitive the ozone layer is to the influence of anthropogenic emissions of certain
compounds. The thin ozone layer has proved to be an Achilles heel that may be seriously
injured by apparently moderate changes in the composition of the atmosphere. By
explaining the chemical mechanisms that affect the thickness of the ozone layer, the three
researchers have contributed to our salvation from a global environmental problem that
could have catastrophic consequences.
Atmospheric
Structure
Air density?
Air pressure?
Air temperature?
Vertical Profiles of Density

The density =

Mass
Volume

The density of air
decreases with height.
Density profile cannot be
used to describe
atmospheric structure!
Atmospheric Pressure

Pressure = force per unit area

Atmospheric Pressure at Sea Level:
1013.25 millibars (mb)
Pressure profile cannot
be used to describe
atmospheric structure!
Vertical Profiles of Temperature
How do you think
the temperature
varies with height?
 Temperature decreases with height.
lapse rate (6.5 oC/km)
top of troposphere  the tropopause
higher is summer, lower in winter
tropopause is proportional to mean tropospheric temperature
 where all the weather occurs
Unstable
90% of all the gases on Earth is in this layer
Tropopause
Why is a fire always going up?
Hot and lighter!

28
Why this balloon can carry so many people?
Fire hot air

Because the air density is less than surroundings
Stable State
example: if you push the rock A along either side of the hill and
then let go, it will return to its original position
Unstable State

example: if the rock rests on the top of the hill, a slight push will
set it moving away from its original position
Brick

Stable?

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Lecture4 sep16-bb

  • 1. 1
  • 2. 2
  • 4. Composition of the Atmosphere Air is composed of a mixture of gases: Gas N2 O2 Ar concentration (%) 78 21 0.9 99.9% Major constituents
  • 5. Composition of the Atmosphere Air is composed of a mixture of gases: Gas greenhouse gases concentration (%) N2 O2 Ar H2O CO2 CH4 N2O O3 78 21 0.9 variable 0.037 Minor constituents
  • 7. Water? Or water vapor? Water vapor  H2O  Invisible  The most abundant greenhouse gas  Variable, why?  Only substance is naturally in three phases: solid, liquid, and a gas solid liquid gas
  • 8. Composition of the Atmosphere Air is composed of a mixture of gases: Gas greenhouse gases concentration (%) N2 O2 Ar H2O CO2 CH4 N2O O3 78 21 0.9 variable 0.037 Minor constituents
  • 10. The dashed land-use change line does not include management-climate interactions The land sink was a source in 1987 and 1998 (1997 visible as an emission) Source: Le Quéré et al. 2012; Global Carbon Project 2012
  • 11. Source: Le Quéré et al. 2012; Global Carbon Project 2012
  • 12. Composition of the Atmosphere Air is composed of a mixture of gases: Gas greenhouse gases concentration (%) N2 O2 Ar H2O CO2 CH4 N2O O3 78 21 0.9 variable 0.037 Minor constituents
  • 15. Freons are greenhouse gases but, more importantly, they also affect ozone…
  • 16. Ozone (O3) production • Concentrated in stratosphere (10-50km) • Produced by absorbing UV radiation through the ozone-oxygen cycle: O2 + UV  O + O, O + O2  O3 • Ground-level ozone (troposphere) is created when intense sunlight reacts with nitrogen oxides (NOx) and volatile organic compounds (VOCs), which mainly come from vehicles, power plants, and industrial facilities. VOC + NOx + + = ozone
  • 17. Good ozone up high Bad ozone near by
  • 18. Ozone (O3) destruction CFCs: float up to stratosphere and constantly react with O3 to form ClO and O2: Cl + O3  ClO+ O2 ClO + O  Cl +O2 Scientists estimate that one chlorine atom can destroy 100,000 "good" ozone molecules. The Antarctic ozone hole, seen from space, Sept. 16, 2000. More Dobson units = more ozone. Image from NASA/TOMS CFCChlorofluorocarbons CIO chlorine monoxide Figure 1-6 Simultaneous measurements of ozone (O3) and chlorine monoxide (CIO) made from a NASA aircraft as it flew into the Antarctic ozone hole in
  • 20. See The Earth System, ed. 2, of 1-6 Figure 1-6 Simultaneous measurementsFig. ozone (O3) and chlorine monoxide (CIO) made from a NASA aircraft as it flew into the Antarctic ozone hole in September 1987.
  • 21. The Nobel Prize in Chemistry 1995 Paul J. Crutzen Max-Planck-Institute Mario J. Molina F. Sherwood Rowland MIT UC Irvine Paul Crutzen, Mario Molina and Sherwood Rowland have all made pioneering contributions to explaining how ozone is formed and decomposes through chemical processes in the atmosphere. Most importantly, they have in this way showed how sensitive the ozone layer is to the influence of anthropogenic emissions of certain compounds. The thin ozone layer has proved to be an Achilles heel that may be seriously injured by apparently moderate changes in the composition of the atmosphere. By explaining the chemical mechanisms that affect the thickness of the ozone layer, the three researchers have contributed to our salvation from a global environmental problem that could have catastrophic consequences.
  • 23. Vertical Profiles of Density The density = Mass Volume The density of air decreases with height. Density profile cannot be used to describe atmospheric structure!
  • 24. Atmospheric Pressure Pressure = force per unit area Atmospheric Pressure at Sea Level: 1013.25 millibars (mb) Pressure profile cannot be used to describe atmospheric structure!
  • 25. Vertical Profiles of Temperature How do you think the temperature varies with height?
  • 26.  Temperature decreases with height. lapse rate (6.5 oC/km) top of troposphere  the tropopause higher is summer, lower in winter tropopause is proportional to mean tropospheric temperature  where all the weather occurs Unstable 90% of all the gases on Earth is in this layer
  • 28. Why is a fire always going up? Hot and lighter! 28
  • 29. Why this balloon can carry so many people? Fire hot air Because the air density is less than surroundings
  • 30. Stable State example: if you push the rock A along either side of the hill and then let go, it will return to its original position
  • 31. Unstable State example: if the rock rests on the top of the hill, a slight push will set it moving away from its original position