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Water Treatment
   Seminar
  Cooling Towers & Chillers



Presented by International Chemtex P.R.Inc.
Water Treatment Seminar
Things you will learn in this seminar
   Properties of Water
       Hydrogen Bond
       Specific Heat of Water
       Water as a Coolant
       Water as a Solvent
Water Treatment Seminar
Things you will learn in this seminar
   Meaning of pH
       What is an acid ?
       What is a base ? ( Alkalinity)
       Effect of pH on solubility
Water Treatment Seminar
Things you will learn in this seminar
   Chiller Plant Operation
       How Chillers Work
       How Cooling Towers Work
Water Treatment Seminar
Things you will learn in this seminar
   Problems associated with Cooling Water
       Scale/ Deposits: Causes & Prevention
       Corrosion: Causes & Prevention
           Different Types of Corrosion
       Fouling: Causes & Prevention
       Microbiological Fouling: Causes &
        Prevention
Water Treatment Seminar
Things you will learn in this seminar
   Overview of Chemical Equipment
       Cooling Tower Controllers
       Chemical Pumps
       Water Softeners
       Sand Filters
Water Treatment Seminar
Things you will learn in this seminar
   Chemical Safety
       Explanation of MSDS
       Ten commandments of safe chemical
        handling
Water Treatment Seminar
Things you will learn in this seminar
   Testing Procedures
       Conductivity test using meter
       pH test using meter
       Hardness test to check softener
       Organo test to check residual of scale
        inhibitor chemical in the cooling tower
       Nitrite test to check residual of corrosion
        inhibitor in the chill loop system
Water Treatment Seminar



Let’s get started…
Properties of Water


           Water has a very simple
           atomic structure. It has
           two hydrogen atoms
           bonded to one oxygen
           atom.
Properties of Water

          Each hydrogen atom has one
          proton and one electron. The
          oxygen atom has 8 protons and
          8 electrons. Both hydrogen
          atoms share their electrons
          with the outer shell of the
          oxygen. Note there are more
          electrons on the oxygen side of
          the water molecule than on the
          hydrogen side.
Properties of Water

           Due to the unique
           geometry of the water
           molecule, the hydrogen
           side has a slight
           positive charge. The
           oxygen side has a slight
           negative charge.
Properties of Water




This molecular polarity causes water to be a
powerful solvent and is responsible for its
strong surface tension.
Properties of Water
          This polarity of charge
          causes molecules of
          water to be attracted to
          each other in a strong
          molecular bond called
          the “hydrogen bond”.
          Water molecules can
          bind together in
          chains.
Properties of Water
                                     Due to the hydrogen
                                      bond, water has a
                                      high “specific heat”.
                                     Specific heat is the
                                      amount of energy
Water as ice has a highly             required to change
organized structure. It takes         the temperature of a
large amounts of heat to make         substance.
a phase change to liquid water.
Properties of Water
                                      Water in the liquid
                                       form remains as a
                                       liquid over a wide
                                       temperature range
                                       from 0 C to 100 C.
                                      Because water can
As ice is heated and melts to
form water, the water mole-
                                       absorb so much heat
cules move apart and become            and still remain a
more energetic. But the hydro-         liquid, it makes a
gen bond keeps pulling them            good “coolant”.
back together like rubber bands.
Properties of Water
                                     Once enough heat is
                                      applied, water can
                                      make another phase
                                      change and turn to
                                      steam. Notice the
                                      water molecules as
Water molecules as steam have         steam have become so
enough kinetic energy to break        energetic they have
away from the hydrogen bond           broken away from the
binding it to other water mole-       hydrogen bond and
cules.                                now are separate
                                      atoms.
Properties of Water
             Another property of
              water caused by the
              hydrogen bond is the
              strong surface tension
              of water.
             Water can overfill a
              cup because the water
              underneath pulls
              down on the surface
              water.
Properties of Water

           The strong surface
           tension of water
           allows for the
            formation of
           water droplets and
           waves.
Properties of Water
          The diagram on the left
           is that of a salt
           molecule. Salt is made
           of sodium & chloride
           atoms.
Properties of Water
          When salt is dropped into
          water it dissolves. The
          positive regions of each
          water molecule is
          attracted to the
          negatively charged
          chloride atoms.
          Conversely the negative
          area of each water
          molecule is attracted to
          positively charged
          sodium atoms.
Properties of Water
                                      Water will dissolve
                                       different minerals, for
                                       example calcium. The
                                       calcium atom has a
                                       positive charge. The
                                       negative side of each
                                       water molecule is
It takes many water molecules to keep attracted to the positively
just one calcium molecule in solution. charged calcium atom.
Calcium’s atomic number is 20 but
Oxygen’s is only 8. So the calcium
atom is 2.5 times bigger than the
oxygen atom.
Properties of Water

          Water is called a
            universal solvent, but
            each volume of water
            has a saturation limit.
           Once any mineral has
            reached its saturation
            limit in a given
            volume of water, no
            more mineral can go
            into solution.
Properties of Water
             Once the saturation limit
              has been reached, any
              additional mineral
              added to the water will
              fall out of solution.
             In cooling water, calcium
              will precipitate to form
              hard scale deposits in
              chiller tubes and towers.
Properties of Water
   Each mineral has a distinct saturation limit in water
    which depends on certain factors.
   Calcium is the main scale forming mineral in cooling
    tower waters.
    Calcium’s saturation limit is affected or changed by
    factors such as the level of calcium hardness, pH,
    temperature, and alkalinity of the cooling tower water.
    Once the calcium saturation index has been exceeded,
    then the excess calcium will precipitate out of solution
    and form scale deposits in the heat exchange areas of the
    chiller system, namely the chiller tubes and the tower
    fill.
Meaning of pH
         Water in a pure state
         has a neutral pH.
         Water changes its
         pH when substances
         are dissolved in it.
         The pH scale is used
         to measure the
         acidity or alkalinity
         of a substance.
Meaning of pH
An acid is any chemical compound that, when
dissolved in water, gives a solution with a hydrogen ion
activity greater than in pure water, i.e. a pH less than
7.0. An acid will range from 0 to 7 on the pH scale.

A base can be thought of as the chemical opposite of
an acid. A base will range from 7 to 14 on the pH scale.
Bases and acids are opposites because the effect of
an acid is to increase the hydrogen ion (H3O+)
concentration in water, whereas bases reduce this
concentration. Bases react with acids to produce water
and salts.
Meaning of pH
For Example:

Acid + Base = Water + Salt

ACID: HCl is Hydrochloric Acid
BASE: NaOH is Sodium Hydroxide

When you combine: HCl+NaOH = H20 + NaCl
                       This is Water & Salt
Meaning of Ph
       The pH of cooling
       tower water is
       important to us
       because the pH will
       change the solubility
       of calcium in water.
       Lower the pH and
       more calcium can stay
       in solution. If pH is
       too alkaline, calcium
       will fall out of
       solution.
Chiller Plant Operation




Chiller & Cooling Tower work together
 to cool interior of the building
Chiller Plant Operation
                                         Chiller cools chill water
                                          down to 40 degrees, then
                                          circulates chill water to the
                                          building. Return chill
                                          water comes back at 50
                                          degrees and causes Freon
                                          gas to evaporate.
                                         Condenser water cools
                                          down Freon gas.
                                         Compressor turns Freon
                                          gas back to liquid ready to
Tower water enters condenser at           repeat the cycle.
85 degrees but leaves condenser
at 95 degrees and returns to tower.
Chiller Plant Operation
               Purpose of the cooling
                tower is to eject heat and
                cool down the condenser
                water by 10 degrees.

               By cooling the water, the
                same water can be used
                again and recycled to the
                condenser. This saves
                large amounts of water.
Chiller Plant Operation
               Cooling Towers cool water
                via the process of
                evaporation.

               The tower water is broken
                up into droplets and air is
                passed through the falling
                water. Every minute 1% of
                the tower water evaporates
                but the other 99% is cooled
                down by 10 degrees and is
                recycled to cool the
                condenser. This process
                repeats constantly.
Chiller Plant Operation
                                   Notice the condensation
                                   of the evaporating
                                   tower water. The
                                   evaporation process
                                   cools down the
                                   remaining tower water
                                   but leaves mineral
                                   impurities behind.

These mineral impurities in water takes us to our next subject,
Problems in Tower Water; the reason we need water treatment.
Problems in Tower Water
There are four main problems which occur
 in cooling tower water :
      Scale

      Corrosion

      Fouling

      Microbiological Fouling
Problems in Tower Water
   The first problem in tower water is:


            Scale
Problems in Tower Water
               As we have seen, water
                is a good solvent.
                Tower makeup water
                has mineral impurities
                in it like, calcium,
                magnesium & silica.
               These minerals left
                unchecked can cause
                scale deposits to form
                on condenser tubes.
Problems in Tower Water
            Scale will form on chiller tubes
             if mineral saturation level is
             exceeded and scale inhibitor
             residual falls too low in the
             tower water.
            Scale on tubes will increase
             energy costs by 10% to 30%
             depending on thickness.

            Preventing scale is one of the
             main objectives of the water
             treatment program.
Problems in Tower Water
           The dissolved solids in tower
            water if left to concentrate to
            high levels will also form
            scale deposits in the cooling
            tower fill and in the louvers.

           This may require expensive
            down time cleanouts.
Problems in Tower Water
   Scale is prevented by:

     The proper amount of   bleed off

     And the addition of chemical scale
     inhibitors to the tower water which
     prevent scale formation.
Problems in Tower Water
           Proper amount of bleed off limits
            the concentration of mineral
            solids

           Tower water is bled to drain
            before the saturation limit on the
            scale forming mineral is exceeded

           The exiting bleed off water
            contains a high level of dissolved
            solids ( minerals) and is replaced
            with fresh water which has a
            lower level of solids
Problems in Tower Water
               Bleed off alone can not
               prevent scale
              Scale inhibitors must be
               added to the tower water
               and maintained within
               desired ranges at all times
              Bleed off and injection of
               chemicals is done
               automatically with proper
               chemical equipment
Problems in Tower Water

   The chemical scale inhibitors we use to treat
    the tower water have two main properties:

     Crystal Distortion


     Dispersancy
Problems in Tower Water

   Crystal Distortion
       Polymers distort the crystal growth of the scale by disrupting
        the crystalline lattice which causes the hard dense adherent
        nature of scales. With the inclusion of a relatively large,
        irregularly shaped polymer in the crystalline lattice, scale
        does not develop or adhere to surfaces where it could cause
        heat transfer problems.
Problems in Tower Water

               This is an electron
                microscope photo of
                calcium carbonate
                crystals.
               Note the regular
                structure of the crystal,
                almost like building
                blocks.
Problems in Tower Water

             Once the water is
             treated with polymers,
             which distort the
             crystalline structure, the
             calcium can no longer
             adhere and build up
             scale deposits.
Problems in Tower Water

   Dispersancy
     Polymers are used for dispersing particles so they do
      not tend to settle. Anionic polymers are effective
      dispersants because they will increase the negative
      charges of particles causing the particles to repel
      each other and more easily keep them in suspension
      so they can be removed by normal bleed off.
Problems in Tower Water
   The second problem in tower water is:


           Corrosion
Problems in Tower Water
             Corrosion can be
              caused by many
              factors.

             If acid is added to tower
              water to help maintain
              calcium hardness in
              solution, an overfeed of
              acid can cause severe
              corrosion in the
              condenser.
Problems in Tower Water
   Acid Feed Primer:
    Adding acid to the tower water lowers the pH
    and increases the solubility of some scale
    forming minerals. For example adding sulfuric
    acid changes calcium carbonate ( the main scale
    forming mineral present in tower water) to
    calcium sulfate, which has a much higher
    solubility index than than calcium carbonate. An
    overfeed of acid can result in severe corrosion
    even catastrophic system failure.
Problems in Tower Water
            To avoid the potential for this
             type of corrosion, we
             recommend not to use an acid
             feed to control scale forming
             impurities.

            In high hardness waters where
             acid feed is necessary, we prefer
             to use a water softener and a
             high quality polymer scale &
             corrosion inhibitor chemical.
Problems in Tower Water
   There are other types of corrosion that can
    occur in tower systems. Some examples are:
       General Corrosion
       White Rust on new galvanized cooling towers
       M.I.C. - Microbiologically Induced Corrosion
       Erosion
       Galvanic Attack
       Cavitation
Problems in Tower Water
    Corrosion may be prevented or mitigated by
    the proper addition of corrosion inhibitors
    and biocide chemicals.

   However; some types of corrosion can not be
    prevented by chemicals. They must be
    remedied by mechanical or other means.
Problems in Tower Water
   Generalized corrosion is caused by oxygen in the
    water attacking the metal.
   This type of corrosion is reduced or mitigated by
    adding corrosion inhibitors to the tower water.
   The inhibitor works by laying down a thin
    protective film on the wetted metal surfaces in the
    tower water piping system. This film inhibits the
    oxygen from reaching the metal.
Problems in Tower Water
               The rate of generalized
                corrosion can be monitored
                by using corrosion coupons
               Metal coupons of steel and
                copper are inserted into the
                water stream for 60 to 90
                days
               They are then removed and
                analyzed for metal loss.
Problems in Tower Water
               No corrosion inhibitor will
                completely stop all
                corrosion. The idea is to
                reduce the rate of corrosion
                to acceptable limits.



               Acceptable limit for mild
                steel is 2 mils per yr. Limit
                for copper is 0.2 mils per
                year
Problems in Tower Water
               White Rust is a type of
                corrosion that can occur in
                new galvanized towers.
               White Rust refers  to the
                premature, rapid loss of
                galvanized coating on
                cooling tower metal
                surfaces.
               White Rust is evidenced
                by a white, waxy buildup
                on the surface of the
                galvanized metal.
Problems in Tower Water

              Once the
              galvanized coating
              has been removed,
              the underlying
              steel/iron rapidly
              corrodes
Problem in Tower Water
   Why White Rust occurs is a little
    complicated, but there are 3 main reasons:
     The imperfect manufacture of the galvanized
      coating of the tower metal
     Lack of passivation when tower first started up

     Running tower with high alkalinity levels in
      tower water
   Please refer to Chemtex Technical Topic on
    White Rust for a more in depth analysis
Problems in Tower Water
   The next type of corrosion to discuss is:
    M.I.C. - Microbiological Induced Corrosion

   M.I.C. is caused by bacteria, mostly by:
            SRB- Sulfate Reducing Bacteria
             IRB - Iron Reducing Bacteria
Problems in Tower Water
               SRB - Sulfate Reducing
                Bacteria are anaerobic
                (oxygen free) class of
                bacteria that can thrive
                under deposits of dirt and
                silt in basin of towers.
               SRB form nodules that
                cause pitting. This bacteria
                can actually eat through
                the basin of the tower
                and/or piping and cause
                leaks.
Problems in Tower Water
               SRB - Sulfate Reducing
                Bacteria are usually found
                in low flow areas of the
                tower system, like in the
                tower basin.

               Nodules are formed under
                dirt or other aerobic
                bacteria debris. These
                nodules start a reaction
                that leads to pitting.
Problems in Tower Water




   These are active SRB nodules in the cooling
    tower basin.
Problems in Tower Water
               IRB - Iron Reducing
                Bacteria are aerobic ( need
                oxygen) class of bacteria
                which feed on iron.
               IRB removes iron from the
                water and/or the piping
                and deposits it into sticky
                secretions.
               IRB can cause pitting and
                plugging. IRB can form
                tubercules inside piping
                reducing water flow.
Problems in Tower Water
   Erosion
      Sometimes in the tower, corrosion of the metal is
       caused by erosion. If sand or dirt particles are
       present in the air around the tower, the
       movement of air thru the tower can scratch the
       surface metal, removing the protective
       galvanizing thus opening up the underlying
       steel/iron for rapid corrosion.

       Please note the corrosion inhibitor can only work
        on fully wetted surfaces. In the tower the
        corrosion inhibitor can not protect any metal
        above the water line.
Problems in Tower Water
   It should be obvious that erosion corrosion
    occurring in the tower cannot be prevented by
    chemicals. Unfortunately the addition of the
    proper chemicals and good control of the
    chemistry will not prevent some types of
    corrosion.
   Don’t fall into the “Flag Pole Syndrome”…
    If the flag pole in front of the building falls
    down, call the water treater cause it must be
    his fault :)
Problems in Tower Water
   Galvanic attack is type of corrosion which can
    occur in cooling tower piping systems.
   If two dissimilar metals are connected in the
    presence of an electrolyte (water), they act as a
    short circuited galvanic cell and corrosion will
    occur.
   The farther apart the metals are on the
    galvanic series the greater potential for
    corrosion.
Problems in Tower Water
               The anode (negative)
                metal is giving up
                ions to the cathode
                (positive) metal.
               The results is
                corrosion and pitting
                in the anode metal.
Problems in Tower Water




The higher the dissolved solids level in the
water, the higher the potential for corrosion
Problems in Tower Water




   Corrosion starts when two dissimilar metals such as galvanized
    pipe (anode) is joined to a metal like copper (cathode) in an
    electrolyte (water).
   Corrosion can occur at the anode metal causing pitting.
Problems in Tower Water
               On the galvanic series,
                copper is on the cathodic
                end of the range and
                zinc (galvanized) is
                close to the top of the
                anodic range.
               When these two metals
                are joined together, there
                exists a high potential
                for galvanic corrosion.
   These photos show
    galvanic corrosion when
    a galvanized pipe is
    attached to a copper
    pipe.
   If a small section of
    galvanized pipe is
    connected to a large
    section of copper pipe,
    then the cathodic area
    will begin to corrode.
Problems in Tower Water
   Galvanic corrosion can not be prevented by
    chemical treatment.
   Mechanical measures need implementing to
    prevent galvanic attack.
     Avoid installing dissimilar metals
     Insert di-electric couplings between metals

     Reduce conductivity of the electrolyte
           Pure water will poorly conduct an electrical current
Problems with Tower Water
   Cavitation is another type of corrosion which
    can occur in cooling tower water piping
    systems.
   Cavitation occurs when gas bubbles trapped in
    the circulating water enter an elbow or make a
    turn and the pressure in the water changes
    rapidly. The gas bubbles can expand making
    microscopic gouges in the metal.
   Over time these gouges, erode away the metal.
   This is called Cavitation-Erosion.
Problems in Tower Water
               The drawing shows
                the turbulence of the
                gas bubbles
                expanding & making
                gouges in the metal.
   These two photos show
    the cavitation-erosion or
    impingement in the
    elbow of pipes.

The damage is done after
 the elbow in the area
 where the gas expands
 rapidly after making the
 curve.

   This type of corrosion can
    only be prevented by
    mechanical means and
    not by chemicals.
Problems in Tower Water
             Cavitation-erosion can
              occur inside chiller tubes
              where baffle supports
              hold the tubes.
             If support pinches the
              tubes, gas bubbles in
              water can expand to
              create turbulence and
              gouge metal inside
              chiller tubes.
Problems in Tower Water
                Vibration at the
                baffle support area
                can also lead to metal
                fatigue and corrosion
                resulting in leaks in
                the chiller tubes.
                Not all types of
                corrosion can be
                prevented by
                chemicals.
Problems in Tower Water
   Corrosion Section Summary
     We have reviewed some of the more common
      corrosion problems to occur in cooling
      systems.
     However, be aware there are other types of
      corrosion which can occur. Time does not
      permit us to mention them all.
     When corrosion does occur, the relative data
      needs to be collected, studied and analyzed
      before causes and cures can be assigned.
Problems in Tower Water
 The third problem in tower water is:

         Fouling
Problems in Tower Water
   Fouling is caused by dirt and other
    suspended solids in the cooling tower
    water accumulating in the tower basin
    and migrating to the chiller tubes.
Problems in Tower Water

               This photo shows the
                accumulation of sludge
                buildup in the tower
                basin.
               This dirt/mud/silt
                buildup is called
                fouling and has several
                sources.
Problems in Tower Water
   Sources of Fouling are:

       Suspended solids (dirt) in tower water makeup. Sometimes, the
        makeup water ( especially after a heavy rain) comes with a high
        amount of suspended solids ( dirt).

       Air borne dirt entering the tower. Cooling towers act like air
        washers; any dirt in the air gets sucked into the tower and can
        settle out in the basin of the tower. Some of this dirt can travel to
        the chiller causing fouling inside condenser tubes.

       Accumulations of dead algae & bacteria in tower basin and piping.
Problems in Tower Water
   Suspended Solids are different than dissolved solids. The dissolved
    solids in tower water which concern us are the scale forming minerals
    like calcium. Dissolved solids are at the molecular level and must be
    treated with chemicals.

   Suspended solids are the dirt and silt in the tower water you can see
    with your eye. Suspended solids are many thousands of time larger
    than dissolved solids.

   Some success can be achieved using chemicals like anionic
    dispersants to remove suspended solids from the tower water system.
    At times it is necessary to remove the suspended solids from the
    tower water by mechanical means, by filtering the water via a sand
    filter. Sand filters will be discussed in the “Equipment Overview”
    section later in this presentation.
Problems in Tower Water
   The fourth problem in tower water is:


          Microbiological Fouling
Problems in Tower Water
   Microbiological fouling refers to fouling
    that occurs when algae, bacteria and
    fungus grows out of control in cooling
    tower systems.
   This type of fouling can plug strainers,
    which reduces water flow to chillers.
Problems in Tower Water
               Algae & bacteria can
                grow unchecked in
                tower water and cause
                fouling in the tower
                basin and inside the
                condenser tubes.
               Fouled tubes increases
                energy consumption &
                can cause unscheduled
                shutdowns.
Problems with Tower Water
                To prevent
                 microbiological fouling of
                 the tower and chiller
                 tubes a good dual biocide
                 feed program must be
                 used at all times.


                Tower should be visually
                 inspected weekly and
                 bacteria dip slides run to
                 insure bacteria counts are
                 under control.
Problems in Tower Water
    Discussion of Biocides:

   Biocides are the chemicals that kill and control
    the growth of algae, bacteria and fungus in open
    cooling tower water systems.
   Biocides are usually slug fed to the tower.
   There are different classes of biocides. Some are
    oxiziders, like chlorine, and are slightly
    corrosive to use. While others are non-oxiziders
    and are non-corrosive.
Problems in Tower Water
    Discussion of Biocides continued:

    Different biocides have different mechanisms
    or ways to kill the organisms.
    Oxidizing biocides strip or burn thorough the
    cell wall thus exploding the bacteria.
    Non-oxidizing biocides control organic growth
    by preventing the bacteria from absorbing food
    or reproducing.
Problems in Tower Water
    Discussion of Biocides continued:

   Some biocides, due to the way they work, are
    excellent at killing algae but only average in
    killing bacteria.
   Conversely, other biocides are great at killing
    bacteria but only average to poor at killing
    algae.
   Some biocides do not work well in high
    hardness or high alkaline waters.
Problems in Tower Water
    Discussion of Biocides continued:

    The proper selection of biocides will depend on
    several factors such as what type of organism
    you are trying to kill and control and what is the
    chemical qualities of the tower water you are
    treating.
    It is important to use dual alternating biocides
    to insure no organism develops an immunity to
    a single biocide used constantly.
Problems in Tower Water
              Improper water treatment
               and/or lack of control will
               result in fouled chiller tubes
               and dirty towers costing
               thousands of dollars in
               excess energy and clean out
               expenses.
              A good, well controlled,
               water treatment program
               will prevent these problems
               from occurring.
Chemical Equipment Overview

   Chemical Equipment Review

        1.   Cooling Tower Controllers
        2.   Chemical Feed Pumps
        3.   Water Softeners
        4.   Sand Filters
Chemical Equipment Overview
                Photo shows a typical
                 chemical equipment
                 installation.
                It consists of:
                    tower bleed controller
                     & solenoid valve for
                     bleed off
                    one scale inhibitor
                     pump
                    two biocide pumps for
                     dual biocide feed
QuickTime™ and a
                                   decompressor
                           are needed to see this picture.




Schematic of Chemical Equipment Installation
Chemical Equipment Overview
                The main purpose of the
                 bleed controller is to
                 monitor via a electronic
                 sensor, the conductivity of
                 the tower water.
                Once the conductivity set
                 point has been reached, the
                 controller sends a signal to
                 the bleed solenoid valve to
                 open.
                Tower water is bled to drain
                 replaced with fresh makeup
                 water.
Chemical Equipment Overview
                The tower controller also
                 controls the operation of the
                 three chemical pumps.
                The scale inhibitor pump is
                 programmed to come on
                 once every 30 minutes for a
                 few minutes to inject the
                 scale inhibitor chemical.
                Each biocide pump only
                 comes on once a week for a
                 preset time to slug feed a
                 dose of biocide to the tower.
Chemical Equipment Overview
                All settings on the controller
                 are programmed by the
                 Chemtex technician.
                All functions work
                 automatically without the
                 need for the plant’s
                 personnel to do anything.
                However, from time to time
                 the controller may lose some
                 calibration on the
                 conductivity reading. If &
                 when this happens, the
                 Chemtex technician will re-
                 calibrate the controller.
Chemical Equipment Overview
                 Water Softener.
                The purpose of the
                 softener is to remove
                 the calcium &
                 magnesium hardness
                 from the tower
                 makeup water.
Chemical Equipment Overview
                A water softener consists
                 of a mineral tank that
                 holds the resin and a brine
                 tank that stores the salt.
                It also has a control valve
                 and a timer that initiates
                 and controls regeneration.
                 Once the resin bed is
                 exhausted, the
                 regeneration cycle starts.
Chemical Equipment Overview
                When softener tank is
                 online, hard water
                 enters the softener and
                 passes down through
                 the resin bed.
                Ion exchange takes
                 place with the calcium
                 & magnesium ions
                 sticking to the resin
                 and releasing sodium
                 ions in their place.
Chemical Equipment Overview
   Calcium & magnesium are scale forming ions.

   The sodium ion is non scaling. Sodium will stay
    in solution hundreds of times more than calcium.

   Replacing the calcium and magnesium ions for
    sodium makes the water soft ( non scaling).
Chemical Equipment Overview
                  The softener ion
                   exchange resin looks
                   like tiny beads.
                  Once all the resin
                   beads are saturated
                   with calcium, the
                   resin bed must be
                   recharged with salt
                  Salt is NaCl (sodium
                   chloride).
Chemical Equipment Overview
   Recharging the resin bed with salt is called
    regeneration.
   During regeneration the control valve passes the
    softener through 4 stages.
   During regeneration, salt ( sodium) is passed
    across the resin. Ion exchange takes place again.
    Now the sodium sticks to the resin and the
    calcium & magnesium are released and flushed
    to the drain.
Chemical Equipment Overview
The four stages of regeneration are:

         1. Backwash
         2.   Brine Draw
         3.   Slow Rinse
         4.   Fast Rinse
Chemical Equipment Overview
              Before regeneration starts
                 the softener is in the
                 normal service mode.
                The hard water enters
                 from the top passes down
                 through the resin.
                Ion exchange takes place.
                Soft water exits softener
                 and goes out to service.
Chemical Equipment Overview
              During the first stage of
                regeneration the softener
                enters the backwash
                mode.

              The water enters from the
                bottom passes up through
                the resin then out to drain.

              Backwash removes the
                dirt from the resin.
Chemical Equipment Overview
              During the second stage of
                 regeneration the softener
                 enters the brine draw
                 mode.
                The salt water enters from
                 the brine tank and passes
                 down through the resin
                 then out to drain.
                Brine draw releases the
                 calcium & magnesium
                 from the resin and flushes
                 it to drain.
Chemical Equipment Overview
             In the third stage of
               regeneration, once the
               brine tank is empty, the
               softener goes into the
               slow rinse mode.

             During slow rinse the
               excess salt water is
               slowly rinsed or purged
               from the mineral tank
               and flushed to the drain.
Chemical Equipment Overview
              In the fourth stage of
                 regeneration, the softener
                 goes into the fast rinse
                 mode.
                During fast rinse water is
                 rapidly passed across the
                 resin to remove any last salt
                 left in mineral tank from
                 the brine draw.
                After fast rinse, the softener
                 is returned to service or
                 placed in standby ( if a twin
                 unit).
Chemical Equipment Overview
 In a twin alternating water softener systems, one tank is
   in service and one tank is on standby. When the unit
   online goes into regeneration, it goes offline and the
   standby unit goes into service. Thus soft water always
   goes out to the system.

 In a single tank unit, when the mineral tank goes into
   regeneration there are two options:

    Hard Water Bypass- While the unit is in regeneration, hard
      water by-passes the softener and goes out to the system.

    NO Hard Water Bypass- While the softener is in regeneration,
      NO water goes out to the system.
Chemical Equipment Overview
 Sand Filter

 While the sand filter is not a piece of chemical
   treatment equipment, it does help us achieve the
   goals of the water treatment program.

 Sand filters by eliminating the sludge buildup in
   the tower basin, prevents fouling.
Chemical Equipment Overview
 When a sand filter is installed on a tower there is little or
    no buildup of dirt in the tower basin. This makes the
    biocide/ chemical program more efficient.

 Less biocide/ chemicals are used. When a tower is
    fouled with sludge deposits, this layer of dirt gives a
    place for the bacteria to hide and prevents the biocide/
    chemicals from penetrating down through the dirt and
    completing killing all the algae and bacteria. The
    remaining bacteria quickly re-infect the tower water
    system.
Chemical Equipment Overview




These are photos of typical sand filters installed
on cooling towers
Chemical Equipment Overview




This is a cut away view of the sand filter. The
sand only fills up 2/3 of the vessel.
Chemical Equipment Overview
   When in service mode, the water in a sand filter
    flows from the top to the bottom. The space
    between the sand is only 5 microns. The dirt gets
    trapped between the sand particles. As the sand
    filter becomes dirty it actually filters better and
    better but the outlet flow starts to diminish.
   When flow is reduced, the filters’ back pressure
    goes up. The pressure sensor on the filter senses
    this and automatically puts the filter into the
    backwash mode for 2 to 3 minutes.
Chemical Equipment Overview
   In backwash, the flow is reversed from the
    bottom to the top of the filter. The sand bed is
    uplifted. Because the dirt trapped between the
    sand is lighter than the sand, the dirt is shaken
    loose and flows up and away to the drain.
   The water flow up through filter in the backwash
    mode is controlled so that the sand media is
    slightly uplifted but not enough to wash the sand
    up and over to the drain.
   After 2 minutes of backwash, the sand filter is
    then again put back into the service mode.
Chemical Equipment Overview




The sweeper piping installation in the tower basin improves
operating efficiency of the sand filter. Sweeper jets push the
dirt to center of the tower towards suction piping of the filter.
Chemical Equipment Overview




Sand filters come in different sizes, from small, medium and large
Safety Guidelines
   The next section of our presentation is
    called:


       Safety Guidelines
Safety Guidelines
What is a MSDS ?
   MSDS stands for Material Saftey Data Sheets.
   MSDS give the following types of information:
       Identifies the chemical and lists hazard ingredients
       Lists the health hazards to personnel who handle any specific
        chemical product
       List protective equipment personnel should use while handling
        the chemical
       Lists the First Aid measures to give in case of accident
       Gives instructions on preventive measures in case of a spill or
        leak
Safety Guidelines
   In your handouts are copies of MSDS on all
    chemical products Int’l Chemtex supplies to this
    site.
   While Chemtex employees usually handle and
    place all chemicals online and refill drums, if you
    handle any of these chemicals or if there ever is a
    leak or spill,please refer to the appropriate MSDS
    and follow the instructions.
Safety Guidelines
The next series of slides are called the:

 10 Commandments of Handling Chemicals



 We will discuss each slide as we go along.
Testing Procedures
Testing Procedures

                      In this section you will
                      learn how to run tests to
                      check for the chemical
                      residuals in the tower
                      and chill water systems.
Testing Procedures
            You will learn how to use
             the conductivity meter.
            The meter is used to check
             level of dissolved solids in
             the tower & chill water.
            Using the meter double
             checks the operation of
             bleed controller & insures
             the controller is calibrated
             and working correctly.
Testing Procedures
            You will learn how to use
             the pH meter.
            The pH meter is used to
             check pH level of the
             tower & chill water.
            At this site you may also
             need to check the pH of
             the tower effluent.
            The pH meter can verify if
             tower pH controller is
             properly calibrated.
Testing Procedure
   The next three tests are done using
    reagents. These tests are:
       Hardness Test
            Checks for level of hardness in softener effluent
             and in the tower and chill water
       Organo Test
            Checks for the residual of the scale inhibitor
             chemical present in the cooling tower water
       Nitrite Test
            Checks for the residual of the corrosion inhibitor
             chemical present in the chill water
Testing Procedures

            Please refer to your
             handouts for the
             instructions for each
             test.
Water Treatment Seminar
              This ends our water
               treatment seminar.
              Congratulations ! You
               are now graduates of a
               Water Treatment
               Seminar.
              Now put you new
               knowledge to work.
              Thank you for your
               attention !
Water Treatment
      Seminar
                The End

Presented by International Chemtex PR Inc

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Water Treatment Seminar: Cooling Towers, Chillers, pH and More

  • 1. Water Treatment Seminar Cooling Towers & Chillers Presented by International Chemtex P.R.Inc.
  • 2. Water Treatment Seminar Things you will learn in this seminar  Properties of Water  Hydrogen Bond  Specific Heat of Water  Water as a Coolant  Water as a Solvent
  • 3. Water Treatment Seminar Things you will learn in this seminar  Meaning of pH  What is an acid ?  What is a base ? ( Alkalinity)  Effect of pH on solubility
  • 4. Water Treatment Seminar Things you will learn in this seminar  Chiller Plant Operation  How Chillers Work  How Cooling Towers Work
  • 5. Water Treatment Seminar Things you will learn in this seminar  Problems associated with Cooling Water  Scale/ Deposits: Causes & Prevention  Corrosion: Causes & Prevention  Different Types of Corrosion  Fouling: Causes & Prevention  Microbiological Fouling: Causes & Prevention
  • 6. Water Treatment Seminar Things you will learn in this seminar  Overview of Chemical Equipment  Cooling Tower Controllers  Chemical Pumps  Water Softeners  Sand Filters
  • 7. Water Treatment Seminar Things you will learn in this seminar  Chemical Safety  Explanation of MSDS  Ten commandments of safe chemical handling
  • 8. Water Treatment Seminar Things you will learn in this seminar  Testing Procedures  Conductivity test using meter  pH test using meter  Hardness test to check softener  Organo test to check residual of scale inhibitor chemical in the cooling tower  Nitrite test to check residual of corrosion inhibitor in the chill loop system
  • 10. Properties of Water Water has a very simple atomic structure. It has two hydrogen atoms bonded to one oxygen atom.
  • 11. Properties of Water Each hydrogen atom has one proton and one electron. The oxygen atom has 8 protons and 8 electrons. Both hydrogen atoms share their electrons with the outer shell of the oxygen. Note there are more electrons on the oxygen side of the water molecule than on the hydrogen side.
  • 12. Properties of Water Due to the unique geometry of the water molecule, the hydrogen side has a slight positive charge. The oxygen side has a slight negative charge.
  • 13. Properties of Water This molecular polarity causes water to be a powerful solvent and is responsible for its strong surface tension.
  • 14. Properties of Water This polarity of charge causes molecules of water to be attracted to each other in a strong molecular bond called the “hydrogen bond”. Water molecules can bind together in chains.
  • 15. Properties of Water  Due to the hydrogen bond, water has a high “specific heat”.  Specific heat is the amount of energy Water as ice has a highly required to change organized structure. It takes the temperature of a large amounts of heat to make substance. a phase change to liquid water.
  • 16. Properties of Water  Water in the liquid form remains as a liquid over a wide temperature range from 0 C to 100 C.  Because water can As ice is heated and melts to form water, the water mole- absorb so much heat cules move apart and become and still remain a more energetic. But the hydro- liquid, it makes a gen bond keeps pulling them good “coolant”. back together like rubber bands.
  • 17. Properties of Water  Once enough heat is applied, water can make another phase change and turn to steam. Notice the water molecules as Water molecules as steam have steam have become so enough kinetic energy to break energetic they have away from the hydrogen bond broken away from the binding it to other water mole- hydrogen bond and cules. now are separate atoms.
  • 18. Properties of Water  Another property of water caused by the hydrogen bond is the strong surface tension of water.  Water can overfill a cup because the water underneath pulls down on the surface water.
  • 19. Properties of Water The strong surface tension of water allows for the formation of water droplets and waves.
  • 20. Properties of Water The diagram on the left is that of a salt molecule. Salt is made of sodium & chloride atoms.
  • 21. Properties of Water When salt is dropped into water it dissolves. The positive regions of each water molecule is attracted to the negatively charged chloride atoms. Conversely the negative area of each water molecule is attracted to positively charged sodium atoms.
  • 22. Properties of Water Water will dissolve different minerals, for example calcium. The calcium atom has a positive charge. The negative side of each water molecule is It takes many water molecules to keep attracted to the positively just one calcium molecule in solution. charged calcium atom. Calcium’s atomic number is 20 but Oxygen’s is only 8. So the calcium atom is 2.5 times bigger than the oxygen atom.
  • 23. Properties of Water Water is called a universal solvent, but each volume of water has a saturation limit.  Once any mineral has reached its saturation limit in a given volume of water, no more mineral can go into solution.
  • 24. Properties of Water  Once the saturation limit has been reached, any additional mineral added to the water will fall out of solution.  In cooling water, calcium will precipitate to form hard scale deposits in chiller tubes and towers.
  • 25. Properties of Water  Each mineral has a distinct saturation limit in water which depends on certain factors.  Calcium is the main scale forming mineral in cooling tower waters.  Calcium’s saturation limit is affected or changed by factors such as the level of calcium hardness, pH, temperature, and alkalinity of the cooling tower water. Once the calcium saturation index has been exceeded, then the excess calcium will precipitate out of solution and form scale deposits in the heat exchange areas of the chiller system, namely the chiller tubes and the tower fill.
  • 26. Meaning of pH Water in a pure state has a neutral pH. Water changes its pH when substances are dissolved in it. The pH scale is used to measure the acidity or alkalinity of a substance.
  • 27. Meaning of pH An acid is any chemical compound that, when dissolved in water, gives a solution with a hydrogen ion activity greater than in pure water, i.e. a pH less than 7.0. An acid will range from 0 to 7 on the pH scale. A base can be thought of as the chemical opposite of an acid. A base will range from 7 to 14 on the pH scale. Bases and acids are opposites because the effect of an acid is to increase the hydrogen ion (H3O+) concentration in water, whereas bases reduce this concentration. Bases react with acids to produce water and salts.
  • 28. Meaning of pH For Example: Acid + Base = Water + Salt ACID: HCl is Hydrochloric Acid BASE: NaOH is Sodium Hydroxide When you combine: HCl+NaOH = H20 + NaCl This is Water & Salt
  • 29. Meaning of Ph The pH of cooling tower water is important to us because the pH will change the solubility of calcium in water. Lower the pH and more calcium can stay in solution. If pH is too alkaline, calcium will fall out of solution.
  • 30. Chiller Plant Operation Chiller & Cooling Tower work together to cool interior of the building
  • 31. Chiller Plant Operation  Chiller cools chill water down to 40 degrees, then circulates chill water to the building. Return chill water comes back at 50 degrees and causes Freon gas to evaporate.  Condenser water cools down Freon gas.  Compressor turns Freon gas back to liquid ready to Tower water enters condenser at repeat the cycle. 85 degrees but leaves condenser at 95 degrees and returns to tower.
  • 32. Chiller Plant Operation  Purpose of the cooling tower is to eject heat and cool down the condenser water by 10 degrees.  By cooling the water, the same water can be used again and recycled to the condenser. This saves large amounts of water.
  • 33. Chiller Plant Operation  Cooling Towers cool water via the process of evaporation.  The tower water is broken up into droplets and air is passed through the falling water. Every minute 1% of the tower water evaporates but the other 99% is cooled down by 10 degrees and is recycled to cool the condenser. This process repeats constantly.
  • 34. Chiller Plant Operation Notice the condensation of the evaporating tower water. The evaporation process cools down the remaining tower water but leaves mineral impurities behind. These mineral impurities in water takes us to our next subject, Problems in Tower Water; the reason we need water treatment.
  • 35. Problems in Tower Water There are four main problems which occur in cooling tower water :  Scale  Corrosion  Fouling  Microbiological Fouling
  • 36. Problems in Tower Water  The first problem in tower water is: Scale
  • 37. Problems in Tower Water  As we have seen, water is a good solvent. Tower makeup water has mineral impurities in it like, calcium, magnesium & silica.  These minerals left unchecked can cause scale deposits to form on condenser tubes.
  • 38. Problems in Tower Water  Scale will form on chiller tubes if mineral saturation level is exceeded and scale inhibitor residual falls too low in the tower water.  Scale on tubes will increase energy costs by 10% to 30% depending on thickness.  Preventing scale is one of the main objectives of the water treatment program.
  • 39. Problems in Tower Water  The dissolved solids in tower water if left to concentrate to high levels will also form scale deposits in the cooling tower fill and in the louvers.  This may require expensive down time cleanouts.
  • 40. Problems in Tower Water  Scale is prevented by:  The proper amount of bleed off  And the addition of chemical scale inhibitors to the tower water which prevent scale formation.
  • 41. Problems in Tower Water  Proper amount of bleed off limits the concentration of mineral solids  Tower water is bled to drain before the saturation limit on the scale forming mineral is exceeded  The exiting bleed off water contains a high level of dissolved solids ( minerals) and is replaced with fresh water which has a lower level of solids
  • 42. Problems in Tower Water Bleed off alone can not prevent scale  Scale inhibitors must be added to the tower water and maintained within desired ranges at all times  Bleed off and injection of chemicals is done automatically with proper chemical equipment
  • 43. Problems in Tower Water  The chemical scale inhibitors we use to treat the tower water have two main properties:  Crystal Distortion  Dispersancy
  • 44. Problems in Tower Water  Crystal Distortion  Polymers distort the crystal growth of the scale by disrupting the crystalline lattice which causes the hard dense adherent nature of scales. With the inclusion of a relatively large, irregularly shaped polymer in the crystalline lattice, scale does not develop or adhere to surfaces where it could cause heat transfer problems.
  • 45. Problems in Tower Water  This is an electron microscope photo of calcium carbonate crystals.  Note the regular structure of the crystal, almost like building blocks.
  • 46. Problems in Tower Water Once the water is treated with polymers, which distort the crystalline structure, the calcium can no longer adhere and build up scale deposits.
  • 47. Problems in Tower Water  Dispersancy  Polymers are used for dispersing particles so they do not tend to settle. Anionic polymers are effective dispersants because they will increase the negative charges of particles causing the particles to repel each other and more easily keep them in suspension so they can be removed by normal bleed off.
  • 48. Problems in Tower Water  The second problem in tower water is: Corrosion
  • 49. Problems in Tower Water  Corrosion can be caused by many factors.  If acid is added to tower water to help maintain calcium hardness in solution, an overfeed of acid can cause severe corrosion in the condenser.
  • 50. Problems in Tower Water  Acid Feed Primer: Adding acid to the tower water lowers the pH and increases the solubility of some scale forming minerals. For example adding sulfuric acid changes calcium carbonate ( the main scale forming mineral present in tower water) to calcium sulfate, which has a much higher solubility index than than calcium carbonate. An overfeed of acid can result in severe corrosion even catastrophic system failure.
  • 51. Problems in Tower Water  To avoid the potential for this type of corrosion, we recommend not to use an acid feed to control scale forming impurities.  In high hardness waters where acid feed is necessary, we prefer to use a water softener and a high quality polymer scale & corrosion inhibitor chemical.
  • 52. Problems in Tower Water  There are other types of corrosion that can occur in tower systems. Some examples are:  General Corrosion  White Rust on new galvanized cooling towers  M.I.C. - Microbiologically Induced Corrosion  Erosion  Galvanic Attack  Cavitation
  • 53. Problems in Tower Water  Corrosion may be prevented or mitigated by the proper addition of corrosion inhibitors and biocide chemicals.  However; some types of corrosion can not be prevented by chemicals. They must be remedied by mechanical or other means.
  • 54. Problems in Tower Water  Generalized corrosion is caused by oxygen in the water attacking the metal.  This type of corrosion is reduced or mitigated by adding corrosion inhibitors to the tower water.  The inhibitor works by laying down a thin protective film on the wetted metal surfaces in the tower water piping system. This film inhibits the oxygen from reaching the metal.
  • 55. Problems in Tower Water  The rate of generalized corrosion can be monitored by using corrosion coupons  Metal coupons of steel and copper are inserted into the water stream for 60 to 90 days  They are then removed and analyzed for metal loss.
  • 56. Problems in Tower Water  No corrosion inhibitor will completely stop all corrosion. The idea is to reduce the rate of corrosion to acceptable limits.  Acceptable limit for mild steel is 2 mils per yr. Limit for copper is 0.2 mils per year
  • 57. Problems in Tower Water  White Rust is a type of corrosion that can occur in new galvanized towers.  White Rust refers  to the premature, rapid loss of galvanized coating on cooling tower metal surfaces.  White Rust is evidenced by a white, waxy buildup on the surface of the galvanized metal.
  • 58. Problems in Tower Water Once the galvanized coating has been removed, the underlying steel/iron rapidly corrodes
  • 59. Problem in Tower Water  Why White Rust occurs is a little complicated, but there are 3 main reasons:  The imperfect manufacture of the galvanized coating of the tower metal  Lack of passivation when tower first started up  Running tower with high alkalinity levels in tower water  Please refer to Chemtex Technical Topic on White Rust for a more in depth analysis
  • 60. Problems in Tower Water  The next type of corrosion to discuss is: M.I.C. - Microbiological Induced Corrosion  M.I.C. is caused by bacteria, mostly by: SRB- Sulfate Reducing Bacteria IRB - Iron Reducing Bacteria
  • 61. Problems in Tower Water  SRB - Sulfate Reducing Bacteria are anaerobic (oxygen free) class of bacteria that can thrive under deposits of dirt and silt in basin of towers.  SRB form nodules that cause pitting. This bacteria can actually eat through the basin of the tower and/or piping and cause leaks.
  • 62. Problems in Tower Water  SRB - Sulfate Reducing Bacteria are usually found in low flow areas of the tower system, like in the tower basin.  Nodules are formed under dirt or other aerobic bacteria debris. These nodules start a reaction that leads to pitting.
  • 63. Problems in Tower Water  These are active SRB nodules in the cooling tower basin.
  • 64. Problems in Tower Water  IRB - Iron Reducing Bacteria are aerobic ( need oxygen) class of bacteria which feed on iron.  IRB removes iron from the water and/or the piping and deposits it into sticky secretions.  IRB can cause pitting and plugging. IRB can form tubercules inside piping reducing water flow.
  • 65. Problems in Tower Water  Erosion  Sometimes in the tower, corrosion of the metal is caused by erosion. If sand or dirt particles are present in the air around the tower, the movement of air thru the tower can scratch the surface metal, removing the protective galvanizing thus opening up the underlying steel/iron for rapid corrosion.  Please note the corrosion inhibitor can only work on fully wetted surfaces. In the tower the corrosion inhibitor can not protect any metal above the water line.
  • 66. Problems in Tower Water  It should be obvious that erosion corrosion occurring in the tower cannot be prevented by chemicals. Unfortunately the addition of the proper chemicals and good control of the chemistry will not prevent some types of corrosion.  Don’t fall into the “Flag Pole Syndrome”… If the flag pole in front of the building falls down, call the water treater cause it must be his fault :)
  • 67. Problems in Tower Water  Galvanic attack is type of corrosion which can occur in cooling tower piping systems.  If two dissimilar metals are connected in the presence of an electrolyte (water), they act as a short circuited galvanic cell and corrosion will occur.  The farther apart the metals are on the galvanic series the greater potential for corrosion.
  • 68. Problems in Tower Water  The anode (negative) metal is giving up ions to the cathode (positive) metal.  The results is corrosion and pitting in the anode metal.
  • 69. Problems in Tower Water The higher the dissolved solids level in the water, the higher the potential for corrosion
  • 70. Problems in Tower Water  Corrosion starts when two dissimilar metals such as galvanized pipe (anode) is joined to a metal like copper (cathode) in an electrolyte (water).  Corrosion can occur at the anode metal causing pitting.
  • 71. Problems in Tower Water  On the galvanic series, copper is on the cathodic end of the range and zinc (galvanized) is close to the top of the anodic range.  When these two metals are joined together, there exists a high potential for galvanic corrosion.
  • 72. These photos show galvanic corrosion when a galvanized pipe is attached to a copper pipe.  If a small section of galvanized pipe is connected to a large section of copper pipe, then the cathodic area will begin to corrode.
  • 73. Problems in Tower Water  Galvanic corrosion can not be prevented by chemical treatment.  Mechanical measures need implementing to prevent galvanic attack.  Avoid installing dissimilar metals  Insert di-electric couplings between metals  Reduce conductivity of the electrolyte  Pure water will poorly conduct an electrical current
  • 74. Problems with Tower Water  Cavitation is another type of corrosion which can occur in cooling tower water piping systems.  Cavitation occurs when gas bubbles trapped in the circulating water enter an elbow or make a turn and the pressure in the water changes rapidly. The gas bubbles can expand making microscopic gouges in the metal.  Over time these gouges, erode away the metal.  This is called Cavitation-Erosion.
  • 75. Problems in Tower Water  The drawing shows the turbulence of the gas bubbles expanding & making gouges in the metal.
  • 76. These two photos show the cavitation-erosion or impingement in the elbow of pipes. The damage is done after the elbow in the area where the gas expands rapidly after making the curve.  This type of corrosion can only be prevented by mechanical means and not by chemicals.
  • 77. Problems in Tower Water  Cavitation-erosion can occur inside chiller tubes where baffle supports hold the tubes.  If support pinches the tubes, gas bubbles in water can expand to create turbulence and gouge metal inside chiller tubes.
  • 78. Problems in Tower Water  Vibration at the baffle support area can also lead to metal fatigue and corrosion resulting in leaks in the chiller tubes.  Not all types of corrosion can be prevented by chemicals.
  • 79. Problems in Tower Water  Corrosion Section Summary  We have reviewed some of the more common corrosion problems to occur in cooling systems.  However, be aware there are other types of corrosion which can occur. Time does not permit us to mention them all.  When corrosion does occur, the relative data needs to be collected, studied and analyzed before causes and cures can be assigned.
  • 80. Problems in Tower Water  The third problem in tower water is: Fouling
  • 81. Problems in Tower Water  Fouling is caused by dirt and other suspended solids in the cooling tower water accumulating in the tower basin and migrating to the chiller tubes.
  • 82. Problems in Tower Water  This photo shows the accumulation of sludge buildup in the tower basin.  This dirt/mud/silt buildup is called fouling and has several sources.
  • 83. Problems in Tower Water  Sources of Fouling are:  Suspended solids (dirt) in tower water makeup. Sometimes, the makeup water ( especially after a heavy rain) comes with a high amount of suspended solids ( dirt).  Air borne dirt entering the tower. Cooling towers act like air washers; any dirt in the air gets sucked into the tower and can settle out in the basin of the tower. Some of this dirt can travel to the chiller causing fouling inside condenser tubes.  Accumulations of dead algae & bacteria in tower basin and piping.
  • 84. Problems in Tower Water  Suspended Solids are different than dissolved solids. The dissolved solids in tower water which concern us are the scale forming minerals like calcium. Dissolved solids are at the molecular level and must be treated with chemicals.  Suspended solids are the dirt and silt in the tower water you can see with your eye. Suspended solids are many thousands of time larger than dissolved solids.  Some success can be achieved using chemicals like anionic dispersants to remove suspended solids from the tower water system. At times it is necessary to remove the suspended solids from the tower water by mechanical means, by filtering the water via a sand filter. Sand filters will be discussed in the “Equipment Overview” section later in this presentation.
  • 85. Problems in Tower Water  The fourth problem in tower water is: Microbiological Fouling
  • 86. Problems in Tower Water  Microbiological fouling refers to fouling that occurs when algae, bacteria and fungus grows out of control in cooling tower systems.  This type of fouling can plug strainers, which reduces water flow to chillers.
  • 87. Problems in Tower Water  Algae & bacteria can grow unchecked in tower water and cause fouling in the tower basin and inside the condenser tubes.  Fouled tubes increases energy consumption & can cause unscheduled shutdowns.
  • 88. Problems with Tower Water  To prevent microbiological fouling of the tower and chiller tubes a good dual biocide feed program must be used at all times.  Tower should be visually inspected weekly and bacteria dip slides run to insure bacteria counts are under control.
  • 89. Problems in Tower Water Discussion of Biocides:  Biocides are the chemicals that kill and control the growth of algae, bacteria and fungus in open cooling tower water systems.  Biocides are usually slug fed to the tower.  There are different classes of biocides. Some are oxiziders, like chlorine, and are slightly corrosive to use. While others are non-oxiziders and are non-corrosive.
  • 90. Problems in Tower Water Discussion of Biocides continued:  Different biocides have different mechanisms or ways to kill the organisms.  Oxidizing biocides strip or burn thorough the cell wall thus exploding the bacteria.  Non-oxidizing biocides control organic growth by preventing the bacteria from absorbing food or reproducing.
  • 91. Problems in Tower Water Discussion of Biocides continued:  Some biocides, due to the way they work, are excellent at killing algae but only average in killing bacteria.  Conversely, other biocides are great at killing bacteria but only average to poor at killing algae.  Some biocides do not work well in high hardness or high alkaline waters.
  • 92. Problems in Tower Water Discussion of Biocides continued:  The proper selection of biocides will depend on several factors such as what type of organism you are trying to kill and control and what is the chemical qualities of the tower water you are treating.  It is important to use dual alternating biocides to insure no organism develops an immunity to a single biocide used constantly.
  • 93. Problems in Tower Water  Improper water treatment and/or lack of control will result in fouled chiller tubes and dirty towers costing thousands of dollars in excess energy and clean out expenses.  A good, well controlled, water treatment program will prevent these problems from occurring.
  • 94. Chemical Equipment Overview  Chemical Equipment Review 1. Cooling Tower Controllers 2. Chemical Feed Pumps 3. Water Softeners 4. Sand Filters
  • 95. Chemical Equipment Overview  Photo shows a typical chemical equipment installation.  It consists of:  tower bleed controller & solenoid valve for bleed off  one scale inhibitor pump  two biocide pumps for dual biocide feed
  • 96. QuickTime™ and a decompressor are needed to see this picture. Schematic of Chemical Equipment Installation
  • 97. Chemical Equipment Overview  The main purpose of the bleed controller is to monitor via a electronic sensor, the conductivity of the tower water.  Once the conductivity set point has been reached, the controller sends a signal to the bleed solenoid valve to open.  Tower water is bled to drain replaced with fresh makeup water.
  • 98. Chemical Equipment Overview  The tower controller also controls the operation of the three chemical pumps.  The scale inhibitor pump is programmed to come on once every 30 minutes for a few minutes to inject the scale inhibitor chemical.  Each biocide pump only comes on once a week for a preset time to slug feed a dose of biocide to the tower.
  • 99. Chemical Equipment Overview  All settings on the controller are programmed by the Chemtex technician.  All functions work automatically without the need for the plant’s personnel to do anything.  However, from time to time the controller may lose some calibration on the conductivity reading. If & when this happens, the Chemtex technician will re- calibrate the controller.
  • 100. Chemical Equipment Overview  Water Softener.  The purpose of the softener is to remove the calcium & magnesium hardness from the tower makeup water.
  • 101. Chemical Equipment Overview  A water softener consists of a mineral tank that holds the resin and a brine tank that stores the salt.  It also has a control valve and a timer that initiates and controls regeneration.  Once the resin bed is exhausted, the regeneration cycle starts.
  • 102. Chemical Equipment Overview  When softener tank is online, hard water enters the softener and passes down through the resin bed.  Ion exchange takes place with the calcium & magnesium ions sticking to the resin and releasing sodium ions in their place.
  • 103. Chemical Equipment Overview  Calcium & magnesium are scale forming ions.  The sodium ion is non scaling. Sodium will stay in solution hundreds of times more than calcium.  Replacing the calcium and magnesium ions for sodium makes the water soft ( non scaling).
  • 104. Chemical Equipment Overview  The softener ion exchange resin looks like tiny beads.  Once all the resin beads are saturated with calcium, the resin bed must be recharged with salt  Salt is NaCl (sodium chloride).
  • 105. Chemical Equipment Overview  Recharging the resin bed with salt is called regeneration.  During regeneration the control valve passes the softener through 4 stages.  During regeneration, salt ( sodium) is passed across the resin. Ion exchange takes place again.  Now the sodium sticks to the resin and the calcium & magnesium are released and flushed to the drain.
  • 106. Chemical Equipment Overview The four stages of regeneration are: 1. Backwash 2. Brine Draw 3. Slow Rinse 4. Fast Rinse
  • 107. Chemical Equipment Overview  Before regeneration starts the softener is in the normal service mode.  The hard water enters from the top passes down through the resin.  Ion exchange takes place.  Soft water exits softener and goes out to service.
  • 108. Chemical Equipment Overview  During the first stage of regeneration the softener enters the backwash mode.  The water enters from the bottom passes up through the resin then out to drain.  Backwash removes the dirt from the resin.
  • 109. Chemical Equipment Overview  During the second stage of regeneration the softener enters the brine draw mode.  The salt water enters from the brine tank and passes down through the resin then out to drain.  Brine draw releases the calcium & magnesium from the resin and flushes it to drain.
  • 110. Chemical Equipment Overview  In the third stage of regeneration, once the brine tank is empty, the softener goes into the slow rinse mode.  During slow rinse the excess salt water is slowly rinsed or purged from the mineral tank and flushed to the drain.
  • 111. Chemical Equipment Overview  In the fourth stage of regeneration, the softener goes into the fast rinse mode.  During fast rinse water is rapidly passed across the resin to remove any last salt left in mineral tank from the brine draw.  After fast rinse, the softener is returned to service or placed in standby ( if a twin unit).
  • 112. Chemical Equipment Overview  In a twin alternating water softener systems, one tank is in service and one tank is on standby. When the unit online goes into regeneration, it goes offline and the standby unit goes into service. Thus soft water always goes out to the system.  In a single tank unit, when the mineral tank goes into regeneration there are two options:  Hard Water Bypass- While the unit is in regeneration, hard water by-passes the softener and goes out to the system.  NO Hard Water Bypass- While the softener is in regeneration, NO water goes out to the system.
  • 113. Chemical Equipment Overview  Sand Filter  While the sand filter is not a piece of chemical treatment equipment, it does help us achieve the goals of the water treatment program.  Sand filters by eliminating the sludge buildup in the tower basin, prevents fouling.
  • 114. Chemical Equipment Overview  When a sand filter is installed on a tower there is little or no buildup of dirt in the tower basin. This makes the biocide/ chemical program more efficient.  Less biocide/ chemicals are used. When a tower is fouled with sludge deposits, this layer of dirt gives a place for the bacteria to hide and prevents the biocide/ chemicals from penetrating down through the dirt and completing killing all the algae and bacteria. The remaining bacteria quickly re-infect the tower water system.
  • 115. Chemical Equipment Overview These are photos of typical sand filters installed on cooling towers
  • 116. Chemical Equipment Overview This is a cut away view of the sand filter. The sand only fills up 2/3 of the vessel.
  • 117. Chemical Equipment Overview  When in service mode, the water in a sand filter flows from the top to the bottom. The space between the sand is only 5 microns. The dirt gets trapped between the sand particles. As the sand filter becomes dirty it actually filters better and better but the outlet flow starts to diminish.  When flow is reduced, the filters’ back pressure goes up. The pressure sensor on the filter senses this and automatically puts the filter into the backwash mode for 2 to 3 minutes.
  • 118. Chemical Equipment Overview  In backwash, the flow is reversed from the bottom to the top of the filter. The sand bed is uplifted. Because the dirt trapped between the sand is lighter than the sand, the dirt is shaken loose and flows up and away to the drain.  The water flow up through filter in the backwash mode is controlled so that the sand media is slightly uplifted but not enough to wash the sand up and over to the drain.  After 2 minutes of backwash, the sand filter is then again put back into the service mode.
  • 119. Chemical Equipment Overview The sweeper piping installation in the tower basin improves operating efficiency of the sand filter. Sweeper jets push the dirt to center of the tower towards suction piping of the filter.
  • 120. Chemical Equipment Overview Sand filters come in different sizes, from small, medium and large
  • 121. Safety Guidelines  The next section of our presentation is called: Safety Guidelines
  • 122. Safety Guidelines What is a MSDS ?  MSDS stands for Material Saftey Data Sheets.  MSDS give the following types of information:  Identifies the chemical and lists hazard ingredients  Lists the health hazards to personnel who handle any specific chemical product  List protective equipment personnel should use while handling the chemical  Lists the First Aid measures to give in case of accident  Gives instructions on preventive measures in case of a spill or leak
  • 123. Safety Guidelines  In your handouts are copies of MSDS on all chemical products Int’l Chemtex supplies to this site.  While Chemtex employees usually handle and place all chemicals online and refill drums, if you handle any of these chemicals or if there ever is a leak or spill,please refer to the appropriate MSDS and follow the instructions.
  • 124. Safety Guidelines The next series of slides are called the: 10 Commandments of Handling Chemicals We will discuss each slide as we go along.
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  • 135. Testing Procedures Testing Procedures In this section you will learn how to run tests to check for the chemical residuals in the tower and chill water systems.
  • 136. Testing Procedures  You will learn how to use the conductivity meter.  The meter is used to check level of dissolved solids in the tower & chill water.  Using the meter double checks the operation of bleed controller & insures the controller is calibrated and working correctly.
  • 137. Testing Procedures  You will learn how to use the pH meter.  The pH meter is used to check pH level of the tower & chill water.  At this site you may also need to check the pH of the tower effluent.  The pH meter can verify if tower pH controller is properly calibrated.
  • 138. Testing Procedure  The next three tests are done using reagents. These tests are:  Hardness Test  Checks for level of hardness in softener effluent and in the tower and chill water  Organo Test  Checks for the residual of the scale inhibitor chemical present in the cooling tower water  Nitrite Test  Checks for the residual of the corrosion inhibitor chemical present in the chill water
  • 139. Testing Procedures  Please refer to your handouts for the instructions for each test.
  • 140. Water Treatment Seminar  This ends our water treatment seminar.  Congratulations ! You are now graduates of a Water Treatment Seminar.  Now put you new knowledge to work.  Thank you for your attention !
  • 141. Water Treatment Seminar The End Presented by International Chemtex PR Inc