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GROUP MEMBERS:
 Ong Hui Jin                        152161
 Norshafidah Bt Abu Shafian         151897
 Siti Nor Rafidah Bt Mohd Ali Jinnah 152025

 Hazwani Bt Mokhtar                 151802
 Mohd Nasrudin B. Rahiman           152090
Fatty Acids       Glyceride
               composition ( % )


Diglyceride          6.32


Triglyceride        93.60
Triunsaturated   Composition ( %)

     OOO               3.90


     OOL               1.22         M- Myristic (C 14 : 0)

                                    P- Palmitic (C 16 : 0)
Monosaturated    Composition ( %)
                                    S- Stearic (C 18 : 0)

     PLO               10.02         O- Oleic (C 18 : 0)

     POO               21.39        L- Linoleic (C 18 : 2)

     OOS               2.78
Disaturated    Composition ( % )
   MPL                3.03

    PPL               9.37

   PPO               27.39
                                   M- Myristic (C 14 : 0)
    POS              5.29

    SOS               1.36         P- Palmitic (C 16 : 0)

                                   S- Stearic (C 18 : 0)
Trisaturated   Composition ( % )
                                    O- Oleic (C 18 : 0)
    MMM               0.76

    MMP               2.38         L-Linoleic (C 18 : 2)
     PPP              4.81
   Some minor components in CPO bring
    undesirable effects to oil
   E.g: phospholipids (surface active agent:
    disperse impurities in oil)
   Remove by refining to produce good quality
    of refined oil
Minor components            Amount     Structure
                            (ppm)
Carotenoids                 500-700

Tocopherols& tocotrienols   600-1000


Sterols                     326-527




Ubiquinone (Coenzyme Q10)   10-80


Squalene                    200-500


Phospholipids               5-130


Triterpene alcohols         40-80

Aliphatic alcohols          100-200    R-OH
Aliphatic hydrocarbon       50
Carotenoids    Composition(%)


ẞ- carotene    56.0


α-carotene     35.1


phytoene       1.3


lycopene       1.3


γ- carotene    0.8


Neurosporene   0.3


phytofluene    0.1
Minor components                        Amount (%)
Sterols
Cholesterol                             4.1
Campesterol                             22.8

Stigmasterol                            11.3
ẞ- sitosterol                           57.5
Phosphatides
Phosphatidylcholine                     36
Phosphatidylethanolamine                24
phosphatidylinositol                    33
Phosphatidyglycerol                     9
Diphosphatidyglycerol                   4
Phosphatidic acid                       3
Monoglycerides (MGs)                    ~ <1
Diglycerides (DGs)                      ~2-7
Free fatty acids (FFAs) e.g myristic,   ~2-5
palmitic, stearic, oleic, linoleic
Phosphatidylethanolamine
Phosphatidylcholine




                          Phosphatidyglycerol
phosphatidylinositol




                        Phosphatidic acid
Diphosphatidyglycerol
(Cardiolipin)
MINOR CONSTITUENTS OF PALM OIL                     BENEFICIAL EFFECT
                                 • human body uses carotenoids as Vitamin A.

                                 • enhance immune function by a variety of mechanisms
                                 & can improve cardiovascular health.
         CAROTENOIDS
                                 • acting as biological antioxidants, protecting cells &
                                 tissues from the damaging effect of free radicals.




                                 • Natural vitamin E exists in eight different forms or
                                 isomers,four tocopherols & four tocotrienols.

                                 • Tocotrienols in Vitamin E have been found to have
                                 antioxidant & anticancer activities.

                                 • preventing skin aging, preventing fat oxidation &
        TOCOPHEROLS &            reducing blood pressure.
        TOCOTRIENOLS
                                 • palm tocotrienols have the ability to reverse blockage
                                 of the carotid artery & platelet aggregation.

                                 • Tocotrienol-rich fraction of palm oil is capable of
                                 protecting brain against oxidative damage & thereby
                                 from the ensuing adverse alterations that accompany
                                 aging.
MINOR CONSTITUENTS OF PALM OIL              BENEFICIAL EFFECT




Fatty acid                        • focus of attention in determining its
                                  nutritional adequacy in relation to coronary
                                  heart disease (CHD) risk factors




Monoglycerides                    • used as emulsifiers in foods




Mineral oil                       • medicinal uses

                                  • use in the kitchen is to saturate the
                                  cutting board and other wood items to
                                  make them water resistant
Types of fatty acid
Saturated - 50%
unsaturated – 50%
Saturated :
44.0% Palmitic acid
5.0% stearic acid
1.0% myristic acid
Unsaturated :
39.0% oleic acid
11.0% linoleic acid
Fractionation :
   a physical method using the crystallization
   properties of triglycerides to separate a mixture
   into:
 low melting liquid fraction
 high melting liquid fraction


Components consists :
  palm olein (liquid oil)
  palm stearin (solid form)
Palm olein (liquid)                   Palm stearin (solid)


Fatty acid composition :               Fatty acid composition :
  45% saturated fat                      60% saturated fat
   55% unsaturated fat                   40% unsaturated fat


The main saturated fatty acid :        The main saturated fatty acid :
   40% palmitic acid                     54% palmitic acid
    5% stearic acid                      5% stearic acid
                                         1% myristic acid


The unsaturated fatty acid :           The unsaturated fatty acid :
   43%oleic acid(monounsaturates)        33%oleic acid(monounsaturates)
   12% linoleic acid(polyunsturates)     7%linoleic acid(polyunsturates)
Minor components of cpo

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Minor components of cpo

  • 1.
  • 2. GROUP MEMBERS:  Ong Hui Jin 152161  Norshafidah Bt Abu Shafian 151897  Siti Nor Rafidah Bt Mohd Ali Jinnah 152025  Hazwani Bt Mokhtar 151802  Mohd Nasrudin B. Rahiman 152090
  • 3.
  • 4.
  • 5. Fatty Acids Glyceride composition ( % ) Diglyceride 6.32 Triglyceride 93.60
  • 6. Triunsaturated Composition ( %) OOO 3.90 OOL 1.22 M- Myristic (C 14 : 0) P- Palmitic (C 16 : 0) Monosaturated Composition ( %) S- Stearic (C 18 : 0) PLO 10.02 O- Oleic (C 18 : 0) POO 21.39 L- Linoleic (C 18 : 2) OOS 2.78
  • 7. Disaturated Composition ( % ) MPL 3.03 PPL 9.37 PPO 27.39 M- Myristic (C 14 : 0) POS 5.29 SOS 1.36 P- Palmitic (C 16 : 0) S- Stearic (C 18 : 0) Trisaturated Composition ( % ) O- Oleic (C 18 : 0) MMM 0.76 MMP 2.38 L-Linoleic (C 18 : 2) PPP 4.81
  • 8. Some minor components in CPO bring undesirable effects to oil  E.g: phospholipids (surface active agent: disperse impurities in oil)  Remove by refining to produce good quality of refined oil
  • 9. Minor components Amount Structure (ppm) Carotenoids 500-700 Tocopherols& tocotrienols 600-1000 Sterols 326-527 Ubiquinone (Coenzyme Q10) 10-80 Squalene 200-500 Phospholipids 5-130 Triterpene alcohols 40-80 Aliphatic alcohols 100-200 R-OH Aliphatic hydrocarbon 50
  • 10. Carotenoids Composition(%) ẞ- carotene 56.0 α-carotene 35.1 phytoene 1.3 lycopene 1.3 γ- carotene 0.8 Neurosporene 0.3 phytofluene 0.1
  • 11. Minor components Amount (%) Sterols Cholesterol 4.1 Campesterol 22.8 Stigmasterol 11.3 ẞ- sitosterol 57.5 Phosphatides Phosphatidylcholine 36 Phosphatidylethanolamine 24 phosphatidylinositol 33 Phosphatidyglycerol 9 Diphosphatidyglycerol 4 Phosphatidic acid 3 Monoglycerides (MGs) ~ <1 Diglycerides (DGs) ~2-7 Free fatty acids (FFAs) e.g myristic, ~2-5 palmitic, stearic, oleic, linoleic
  • 12.
  • 13.
  • 14. Phosphatidylethanolamine Phosphatidylcholine Phosphatidyglycerol phosphatidylinositol Phosphatidic acid Diphosphatidyglycerol (Cardiolipin)
  • 15. MINOR CONSTITUENTS OF PALM OIL BENEFICIAL EFFECT • human body uses carotenoids as Vitamin A. • enhance immune function by a variety of mechanisms & can improve cardiovascular health. CAROTENOIDS • acting as biological antioxidants, protecting cells & tissues from the damaging effect of free radicals. • Natural vitamin E exists in eight different forms or isomers,four tocopherols & four tocotrienols. • Tocotrienols in Vitamin E have been found to have antioxidant & anticancer activities. • preventing skin aging, preventing fat oxidation & TOCOPHEROLS & reducing blood pressure. TOCOTRIENOLS • palm tocotrienols have the ability to reverse blockage of the carotid artery & platelet aggregation. • Tocotrienol-rich fraction of palm oil is capable of protecting brain against oxidative damage & thereby from the ensuing adverse alterations that accompany aging.
  • 16. MINOR CONSTITUENTS OF PALM OIL BENEFICIAL EFFECT Fatty acid • focus of attention in determining its nutritional adequacy in relation to coronary heart disease (CHD) risk factors Monoglycerides • used as emulsifiers in foods Mineral oil • medicinal uses • use in the kitchen is to saturate the cutting board and other wood items to make them water resistant
  • 17. Types of fatty acid Saturated - 50% unsaturated – 50% Saturated : 44.0% Palmitic acid 5.0% stearic acid 1.0% myristic acid Unsaturated : 39.0% oleic acid 11.0% linoleic acid
  • 18.
  • 19. Fractionation : a physical method using the crystallization properties of triglycerides to separate a mixture into:  low melting liquid fraction  high melting liquid fraction Components consists :  palm olein (liquid oil)  palm stearin (solid form)
  • 20. Palm olein (liquid) Palm stearin (solid) Fatty acid composition : Fatty acid composition : 45% saturated fat 60% saturated fat 55% unsaturated fat 40% unsaturated fat The main saturated fatty acid : The main saturated fatty acid : 40% palmitic acid 54% palmitic acid 5% stearic acid 5% stearic acid 1% myristic acid The unsaturated fatty acid : The unsaturated fatty acid : 43%oleic acid(monounsaturates) 33%oleic acid(monounsaturates) 12% linoleic acid(polyunsturates) 7%linoleic acid(polyunsturates)