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Introduction to Thermoplastic
Elastomers
TERMOPOL Polimer Anonim Şirketi
Mr. YALÇIN ÇANAK – Mr. Oğuz TURAN
2013
IntroductionIntroduction andand PurposePurpose
Information and practical tips about
Thermoplastic Elastomers and processing guide.
Smart processing and smart choice
of polimeric compounds is possible with ;
 Understanding the raw material.
 Good analysis of the process
 Design of the final product
What is TPE?
Thermoplastic Elastomers(TPEs) are the products which contains plastic
and elastromeric properties. TPEs are fast and economic proccesible materials as
plastics, beside of their plastic behiavour advantages, TPEs contain also common-
known properties of rubber such as physical and performanse behaviours.
Elastomeric Phase,
Elasticity,
Soft touch
Flexibility,
Compression Set
Minimum processing temperature
Hard Phase
Recycle,
Hardness, Rigidity,
Processability
Elastromeric Phase
Hard Phase
CapacityTechnical Values
TechnicalTechnical andand
HighHigh Performance TPEPerformance TPE
•• AutomotiveAutomotive partsparts
•• MedicalMedical ApplicationsApplications
•• IndustrialIndustrial ApplicationsApplications
•• ElectricElectric andand ElectronicElectronic
ApplicationsApplications
•• AverageAverage Performance TPEPerformance TPE
CableCable andand IsolotionIsolotion ApplicationApplication
AutomotiveAutomotive PartsParts
WhiteWhite GoodsGoods
PackagingPackaging
GymGym toolstools
StandartStandart Performance TPEPerformance TPE
ShoesolesShoesoles
ContructionContruction
ToysToys
StationerStationer ApplicationsApplications
Capacity
8800%% StandartStandart andand AverageAverage
PPerformanceerformance
Technical Properties
EuropeanEuropean TPETPE consumptionconsumption
TPE-S
TPE-OTPE-V
TPE-U
TPE-E
%12
SectorSector--specificspecific EuropeanEuropean TPETPE--SS consumptionconsumption
25.000
20.000
15.000
10.000
5.000
0
2005 2010
SectorSector--specificspecific EuropeanEuropean TPETPE--VV consumptionconsumption
50.000
50.000
45.000
40.000
35.000
30.000
25.000
20.000
15.000
10.000
5.000
0
- Hardness
-Compression Set
-Heat Resistance
-Oil Resistance
- Over-moulding
TechnicalTechnical ComprassionsComprassions forfor ThermoplasticThermoplastic ElastomersElastomers
CompressionCompression SetSet
- Compression Set:
72 hours at 23°C
22 hours at 70°C
22 hours at 100°C
MaximumMaximum andand MinimumMinimum workingworking
TemperaturesTemperatures..
TERMOPLASTIKLERE YAPıŞMA ÖZELLIKLERI
NEDEN SBC TERMOPLASTIK ELASTOMER’DIR?
-Hard segment(Polystyrene Domain )
Strong and rigid
-Soft segment( Polybutadiene matrix)
C C x
Ethylene-ButylenePS(S) PS(S)
C C
m
C
C
C
C
n
C C
z
Hard phase :
Polystyrene
Rubberphase :
Ethylene-butylene
PP matrix
PP matrix
SEBS
PHYSICAL
CROSSLINKS
0.1 1


 EPDM
CHEMICAL
CROSSLINKS
TPVTPE-S
General Properties
TPE-S TPV
Hardness Range 10 shore A 60 shore D 25 shore A 60 shore D
Density Values 0.90 - 1.20 0.98
Maximum Working Temp. 120°C 135°C
Enviromental Resistance Excellent UV resistance Excellent UV resistance
Görünüş Shiny and transparent or mat
surface
Mat surface, Transparent or
shiny surface is not possible
General Properties
TPE-S TPV
Compression Set Good up to 100°C Good over 100°C
Compatibility Compatible with
Engineering Plastics.
Limited compatiblty with
Engineering Plastics.
Abrasion Resistance Good Good
Scent None Some
Fogging Good Good
Oil and Gasoline
Resistance
Limited Limited
General Properties
TPE-S TPV
Colorable Easy to color and shiny
surface
Easy to color
Paint Applicable Applicable
Pre-processing No need for drying Should be dried , 2 hours –
80C
Foaming Classic Extrusion Underwater Extrusion
Manufacturing Compounding process Vulcanization process
Compression Set
0
20
40
60
80
100
22 hrs at
23°C
22 hrs at
70°C
22 hrs at
100°C
70 hrs at
125°C
%
TPE-S 60 ShA TPV 60 ShA
Nota : TPE-S with improved compression set properties
Compatibility
TPE-S TPV
PP Excellent Excellent
PE Good Medium
ABS PC
PMMA SAN
Good -
PA Good Medium
PBT PET Medium -
PVCPVC ((softsoft)) SBS/SEBSSBS/SEBS
MainMain ComponentComponent Chloric hydrocarbon Hydrocarbon
PropertiesProperties Injection or Extrusion Injection or Extrusion
Not completely re-cyclable Completely Re-cycable
Over scent during processing No scent during processing
Hydrochloric acid ve dioxin gasses
released during burning
Water and Carbondioxide gasses
relaesed during burning
phathalates
ProcessingProcessing
TemperaturesTemperatures
-10 – 80 c -50- 120 c
DensityDensity 1.3 – 1.4 0.9 – 1.3
HardnessHardness 40A – 98A 10A – 60D
OtherOther Prohibited in European Market
CCompressionompression TPETPE withwith SoftSoft PVCPVC :
Material Choice in TPE
TypeType TermatonTermaton--OO TermatonTermaton--KK TermatonTermaton--VV TermatonTermaton--SS
PP/EPDM, PP/EPM SEBSPP/EPDM, PP/EPM SEBS PP/ vulc. EPDM SBSPP/ vulc. EPDM SBS
Hardness(Shore) 45AHardness(Shore) 45A -- 60D 10A60D 10A -- 60D60D 45A45A -- 60D 10A60D 10A -- 60D60D
Density (g/cm ) 0.88Density (g/cm ) 0.88 -- 1.05 0.901.05 0.90 -- 1.31.3 0.950.95 -- 1.05 0.901.05 0.90 -- 1.31.3
CompressionCompressionset √set √ √√√√√√ √√√ √√√√√ √√
ContinuoususeContinuoususe --30 to 9030 to 90 --50 to50 to 112200 --40 to 13540 to 135 --50 to 8050 to 80
Resistanceto acids √√ √√Resistanceto acids √√ √√ √√√ √√√√√ √√
ResistanceResistancetoto √ √√√ √√ √√ √√
hydrocarbonshydrocarbons
WeatheringWeathering √√ √√√√√ √√√ √√√√√√ √√
resistanceresistance
Wear resistance √ √Wear resistance √ √ √√ √√√ √
Special gradesSpecial grades •2K multi•2K multi--component •Improved CScomponent •Improved CS
•Flame•Flame--retardantretardant •Copper Stabilized•Copper Stabilized
•Transparent•Transparent •High Flow•High Flow
••HighHigh tensile FDA •UVtensile FDA •UV--StabilizedStabilized
Criterias of material choice in TPE
• Application Area
–Automotive, Industrial, Consumer goods etc.
• Right Questions ;
–Processing Methods ;(Injection, Extrusion, Blow Moulding, 2K, etc.)
–Enviromental Effects (Çalışma Ortamı, Sıcaklık, Kimyasallar vb)
–Special Requirements ( RoHS, WEEE, FDA vb.)
• Special Formulation for each and every costumers.
- Costumer Needs
- Hardness
- Colour
-MFI
-Etc.
TPE ; Moulding Technics
1-Extrusion
Kalıp Sıcaklığı Besleme Sıkıştırma Basınç
50 ShA 140±10 150±10 170±10 170±10
60 ShA 150±10 155±10 170±10 175±10
70 ShA 165±10 160±10 180±10 190±10
80 ShA 170±10 175±10 190±10 195±10
40 ShD 185±10 180±10 195±10 200±10
TERMOTON- S
Kalıp Sıcaklığı Besleme Sıkıştırma Basınç
50 ShA 180±10 170±10 180±10 185±10
60 ShA 180±10 175±10 185±10 190±10
70 ShA 190±10 180±10 185±10 195±10
80 ShA 200±10 185±10 190±10 200±10
40 ShD 200±10 190±10 200±10 210±10
TERMOTON- K
Kalıp Sıcaklığı Besleme Sıkıştırma Basınç
50 ShA 180±10 180±10 185±10 190±10
60 ShA 180±10 185±10 190±10 190±10
70 ShA 190±10 190±10 195±10 200±10
80 ShA 200±10 190±10 200±10 205±10
40 ShD 200±10 200±10 205±10 210±10
TERMOTON- V
Mould Shrinkage: %5-10
TPE Extrusion Problems
TPE Moulding Technics
2-Injection
Mould Shrinkage: %1-3
TPE Extrusion Problems
TPE Moulding Technics
3-Blow Molding
TPE Moulding Technics
4-Vacuum Molding
Technical Termopol presentation
Technical Termopol presentation
Technical Termopol presentation
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Technical Termopol presentation

  • 1. Introduction to Thermoplastic Elastomers TERMOPOL Polimer Anonim Şirketi Mr. YALÇIN ÇANAK – Mr. Oğuz TURAN 2013
  • 2. IntroductionIntroduction andand PurposePurpose Information and practical tips about Thermoplastic Elastomers and processing guide. Smart processing and smart choice of polimeric compounds is possible with ;  Understanding the raw material.  Good analysis of the process  Design of the final product
  • 3. What is TPE? Thermoplastic Elastomers(TPEs) are the products which contains plastic and elastromeric properties. TPEs are fast and economic proccesible materials as plastics, beside of their plastic behiavour advantages, TPEs contain also common- known properties of rubber such as physical and performanse behaviours. Elastomeric Phase, Elasticity, Soft touch Flexibility, Compression Set Minimum processing temperature Hard Phase Recycle, Hardness, Rigidity, Processability Elastromeric Phase Hard Phase
  • 4.
  • 5.
  • 7. TechnicalTechnical andand HighHigh Performance TPEPerformance TPE •• AutomotiveAutomotive partsparts •• MedicalMedical ApplicationsApplications •• IndustrialIndustrial ApplicationsApplications •• ElectricElectric andand ElectronicElectronic ApplicationsApplications •• AverageAverage Performance TPEPerformance TPE CableCable andand IsolotionIsolotion ApplicationApplication AutomotiveAutomotive PartsParts WhiteWhite GoodsGoods PackagingPackaging GymGym toolstools StandartStandart Performance TPEPerformance TPE ShoesolesShoesoles ContructionContruction ToysToys StationerStationer ApplicationsApplications Capacity 8800%% StandartStandart andand AverageAverage PPerformanceerformance Technical Properties
  • 9. SectorSector--specificspecific EuropeanEuropean TPETPE--SS consumptionconsumption 25.000 20.000 15.000 10.000 5.000 0 2005 2010
  • 10. SectorSector--specificspecific EuropeanEuropean TPETPE--VV consumptionconsumption 50.000 50.000 45.000 40.000 35.000 30.000 25.000 20.000 15.000 10.000 5.000 0
  • 11. - Hardness -Compression Set -Heat Resistance -Oil Resistance - Over-moulding TechnicalTechnical ComprassionsComprassions forfor ThermoplasticThermoplastic ElastomersElastomers
  • 12.
  • 13.
  • 14. CompressionCompression SetSet - Compression Set: 72 hours at 23°C 22 hours at 70°C 22 hours at 100°C
  • 15.
  • 16. MaximumMaximum andand MinimumMinimum workingworking TemperaturesTemperatures..
  • 17.
  • 19. NEDEN SBC TERMOPLASTIK ELASTOMER’DIR? -Hard segment(Polystyrene Domain ) Strong and rigid -Soft segment( Polybutadiene matrix) C C x Ethylene-ButylenePS(S) PS(S) C C m C C C C n C C z
  • 20. Hard phase : Polystyrene Rubberphase : Ethylene-butylene PP matrix PP matrix SEBS PHYSICAL CROSSLINKS 0.1 1    EPDM CHEMICAL CROSSLINKS TPVTPE-S
  • 21. General Properties TPE-S TPV Hardness Range 10 shore A 60 shore D 25 shore A 60 shore D Density Values 0.90 - 1.20 0.98 Maximum Working Temp. 120°C 135°C Enviromental Resistance Excellent UV resistance Excellent UV resistance Görünüş Shiny and transparent or mat surface Mat surface, Transparent or shiny surface is not possible
  • 22. General Properties TPE-S TPV Compression Set Good up to 100°C Good over 100°C Compatibility Compatible with Engineering Plastics. Limited compatiblty with Engineering Plastics. Abrasion Resistance Good Good Scent None Some Fogging Good Good Oil and Gasoline Resistance Limited Limited
  • 23. General Properties TPE-S TPV Colorable Easy to color and shiny surface Easy to color Paint Applicable Applicable Pre-processing No need for drying Should be dried , 2 hours – 80C Foaming Classic Extrusion Underwater Extrusion Manufacturing Compounding process Vulcanization process
  • 24. Compression Set 0 20 40 60 80 100 22 hrs at 23°C 22 hrs at 70°C 22 hrs at 100°C 70 hrs at 125°C % TPE-S 60 ShA TPV 60 ShA Nota : TPE-S with improved compression set properties
  • 25. Compatibility TPE-S TPV PP Excellent Excellent PE Good Medium ABS PC PMMA SAN Good - PA Good Medium PBT PET Medium -
  • 26. PVCPVC ((softsoft)) SBS/SEBSSBS/SEBS MainMain ComponentComponent Chloric hydrocarbon Hydrocarbon PropertiesProperties Injection or Extrusion Injection or Extrusion Not completely re-cyclable Completely Re-cycable Over scent during processing No scent during processing Hydrochloric acid ve dioxin gasses released during burning Water and Carbondioxide gasses relaesed during burning phathalates ProcessingProcessing TemperaturesTemperatures -10 – 80 c -50- 120 c DensityDensity 1.3 – 1.4 0.9 – 1.3 HardnessHardness 40A – 98A 10A – 60D OtherOther Prohibited in European Market CCompressionompression TPETPE withwith SoftSoft PVCPVC :
  • 27. Material Choice in TPE TypeType TermatonTermaton--OO TermatonTermaton--KK TermatonTermaton--VV TermatonTermaton--SS PP/EPDM, PP/EPM SEBSPP/EPDM, PP/EPM SEBS PP/ vulc. EPDM SBSPP/ vulc. EPDM SBS Hardness(Shore) 45AHardness(Shore) 45A -- 60D 10A60D 10A -- 60D60D 45A45A -- 60D 10A60D 10A -- 60D60D Density (g/cm ) 0.88Density (g/cm ) 0.88 -- 1.05 0.901.05 0.90 -- 1.31.3 0.950.95 -- 1.05 0.901.05 0.90 -- 1.31.3 CompressionCompressionset √set √ √√√√√√ √√√ √√√√√ √√ ContinuoususeContinuoususe --30 to 9030 to 90 --50 to50 to 112200 --40 to 13540 to 135 --50 to 8050 to 80 Resistanceto acids √√ √√Resistanceto acids √√ √√ √√√ √√√√√ √√ ResistanceResistancetoto √ √√√ √√ √√ √√ hydrocarbonshydrocarbons WeatheringWeathering √√ √√√√√ √√√ √√√√√√ √√ resistanceresistance Wear resistance √ √Wear resistance √ √ √√ √√√ √ Special gradesSpecial grades •2K multi•2K multi--component •Improved CScomponent •Improved CS •Flame•Flame--retardantretardant •Copper Stabilized•Copper Stabilized •Transparent•Transparent •High Flow•High Flow ••HighHigh tensile FDA •UVtensile FDA •UV--StabilizedStabilized
  • 28. Criterias of material choice in TPE • Application Area –Automotive, Industrial, Consumer goods etc. • Right Questions ; –Processing Methods ;(Injection, Extrusion, Blow Moulding, 2K, etc.) –Enviromental Effects (Çalışma Ortamı, Sıcaklık, Kimyasallar vb) –Special Requirements ( RoHS, WEEE, FDA vb.) • Special Formulation for each and every costumers. - Costumer Needs - Hardness - Colour -MFI -Etc.
  • 29. TPE ; Moulding Technics 1-Extrusion Kalıp Sıcaklığı Besleme Sıkıştırma Basınç 50 ShA 140±10 150±10 170±10 170±10 60 ShA 150±10 155±10 170±10 175±10 70 ShA 165±10 160±10 180±10 190±10 80 ShA 170±10 175±10 190±10 195±10 40 ShD 185±10 180±10 195±10 200±10 TERMOTON- S Kalıp Sıcaklığı Besleme Sıkıştırma Basınç 50 ShA 180±10 170±10 180±10 185±10 60 ShA 180±10 175±10 185±10 190±10 70 ShA 190±10 180±10 185±10 195±10 80 ShA 200±10 185±10 190±10 200±10 40 ShD 200±10 190±10 200±10 210±10 TERMOTON- K Kalıp Sıcaklığı Besleme Sıkıştırma Basınç 50 ShA 180±10 180±10 185±10 190±10 60 ShA 180±10 185±10 190±10 190±10 70 ShA 190±10 190±10 195±10 200±10 80 ShA 200±10 190±10 200±10 205±10 40 ShD 200±10 200±10 205±10 210±10 TERMOTON- V Mould Shrinkage: %5-10