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PART I

1 Generalities on photovoltaic (PV) plants
1.1	Operating principle                                       1.2	Energy from the Sun




                                                                                                                                                              1 Generalities on photovoltaic (PV) plants
A photovoltaic (PV) plant transforms directly and instan-     In the solar core thermonuclear fusion reactions occur
taneously solar energy into electrical energy without us-     unceasingly at millions of degrees; they release huge
ing any fuels. As a matter of fact, the photovoltaic (PV)     quantities of energy in the form of electromagnetic ra-
technology exploits the photoelectric effect, through         diations. A part of this energy reaches the outer area of
which some semiconductors suitably “doped” generate           the Earth’s atmosphere with an average irradiance (solar
electricity when exposed to solar radiation.                  constant) of about 1,367 W/m2 ± 3%, a value which varies
                                                              as a function of the Earth-to-Sun distance (Figure 1.1)1
The main advantages of photovoltaic (PV) plants can be        and of the solar activity (sunspots).
summarized as follows:                                        Figure 1.1 - Extra-atmospheric radiation
•	 distribuited generation where needed;                      W/m2
•	 no emission of polluting materials;                         1400
•	 saving of fossil fuels;
•	 reliability of the plants since they do not have moving      1380

   parts (useful life usually over 20 years);
                                                                1360
•	 reduced operating and maintenance costs;
•	 system modularity (to increase the plant power it is         1340
   sufficient to raise the number of panels) according to
   the real requirements of users.                              1320
However, the initial cost for the development of a PV plant
                                                                1300
is quite high due to a market which has not reached its                   J      F      M      A     M       J   J        A      S      O      N      D
full maturity from a technical and economical point of                                                        Month

view. Moreover the generation of power is erratic due to      With solar irradiance we mean the intensity of the solar
the variability of the solar energy source.                   electromagnetic radiation incident on a surface of 1
                                                              square meter [kW/m2]. Such intensity is equal to the
The annual electrical power output of a PV plant depends      integral of the power associated to each value of the
on different factors. Among them:                             frequency of the solar radiation spectrum.
•	 solar radiation incident on the installation site;         When passing through the atmosphere, the solar radia-
•	 inclination and orientation of the panels;                 tion diminishes in intensity because it is partially reflected
•	 presence or not of shading;                                and absorbed (above all by the water vapor and by the
•	 technical performances of the plant components             other atmospheric gases). The radiation which passes
   (mainly modules and inverters).                            through is partially diffused by the air and by the solid par-
                                                              ticles suspended in the air (Figure 1.2).
The main applications of PV plants are:                       Figure 1.2 - Energy flow between the sun, the atmosphere and the ground
	 1.	installations (with storage systems) for users iso-
                                                                                       25% reflected
     lated from the grid;                                                            by the atmosphere
	 2.	installations for users connected to the LV grid;
	 3.	solar PV power plants, usually connected to the
     MV grid. Feed-in Tariff incentives are granted only                                                                             18% diffused by
                                                                                                                                     the atmosphere
     for the applications of type 2 and 3, in plants with        5% reflected
                                                                 by the ground
     rated power not lower than 1 kW.
                                                                                                                              5% absorbed by
                                                                                                                              the atmosphere
A PV plant is essentially constituted by a generator (PV
panels), by a supporting frame to mount the panels on
the ground, on a building or on any building structure, by
a system for power control and conditioning, by a pos-
sible energy storage system, by electrical switchboards
and switchgear assemblies housing the switching and
protection equipment and by the connection cables.                            27% absorbed by the
                                                                                  soil surface




                                                              1
                                                                Due to its elliptical orbit the Earth is at its least distance from the Sun (perihelion) in
                                                              December and January and at its greatest distance (aphelion) in June and July.


                                                                                                                       Photovoltaic plants 5
Technical Application Papers




                                               With solar irradiation we mean the integral of the solar                    The reflected radiation depends on the capability of a
                                               irradiance over a specified period of time [kWh/m 2].                       surface to reflect the solar radiation and it is measured
1 Generalities on photovoltaic (PV) plants




                                               Therefore the radiation falling on a horizontal surface is                  by the albedo coefficient calculated for each material
                                               constituted by a direct radiation, associated to the direct                 (figure 1.4).
                                               irradiance on the surface, by a diffuse radiation which                     Figure 1.4 - Reflected radiation
                                               strikes the surface from the whole sky and not from a
                                                                                                                            Surface type                                   albedo
                                               specific part of it and by a radiation reflected on a given
                                                                                                                            Dirt roads                                      0.04
                                               surface by the ground and by the surrounding environ-
                                               ment (Figure 1.3). In winter the sky is overcast and the                     Aqueous surfaces                                 0.07
                                               diffuse component is greater than the direct one.                            Coniferous forest in winter                      0.07

                                               Figure 1.3 - Components of solar radiation                                   Worn asphalt                                     0.10
                                                                                                                            Bitumen roofs and terraces                       0.13
                                                                                                                            Soil (clay, marl)                                0.14
                                                                                                                            Dry grass                                        0.20
                                                                                                                            Rubble                                           0.20
                                                                                                        solar constant      Worn concrete                                    0.22
                                                 Reduction of solar
                                                     radiation                                                              Forest in autumn / fields                        0.26
                                                                                                                            Green grass                                      0.26
                                                                                                                            Dark surfaces of buildings                       0.27
                                                                                                        Diffuse
                                                                                     Direct                                 Dead leaves                                      0.30
                                                                                                                            Bright surfaces of buildings                     0.60
                                                                                            Reflected
                                                                                                                            Fresh snow                                       0.75

                                                                                                                            Figure 1.5 shows the world atlas of the average solar
                                               Figure 1.5 - Solar Atlas
                                                                                                                            irradiance on an inclined plan 30° South [kWh/m2/day]




                                                   1 kWh/m2           2 kWh/m2        3 kWh/m2              4 kWh/m2     5 kWh/m2        6 kWh/m2             7 kWh/m2




                                             6 Photovoltaic plants
In Italy the average annual irradiance varies from the 3.6                          about 2 MWh (5.4 . 365) per year from each square meter,
kWh/m2 a day of the Po Valley to the 4.7 kWh/m2 a day                               that is the energetic equivalent of 1.5 petroleum barrels




                                                                                                                                                                  1 Generalities on photovoltaic (PV) plants
in the South-Centre and the 5.4 kWh/m2/day of Sicily                                for each square meter, whereas the rest of Italy ranges
(Figure 1.6).                                                                       from the 1750 kWh/m2 of the Tyrrhenian strip and the
Therefore, in the favorable regions it is possible to draw                          1300 kWh/m2 of the Po Valley.

Figure 1.6 - Daily global irradiation in kWh/m2



                                                                                                                                              3.6

                                                                                                                                              3.8

                                                                                     4.4                                                      4.0
                                                                     Bolzano
                                                                                   4.0                                                         4.2

                                                         Milan            Venice           Trieste                                              4.4
                                                                                                                                                           4.6
                                                               3.8


                                                      Genoa                                                                                                 4.8
                                                                                         Ancona
                                                                                                           5.0
                  4.8

                        5.0




                                                                                                                           5.2
                                                                                                     4
                                                                                                  4.




                                                              Pianosa


                                                                                    Rome
                                                                                                                     4.8




                                                                                                                             Brindisi
                                                                                              Naples

               5.2                       Alghero

                                             5.
                                                  2




                                                                                                           Messina
                                                                               Trapani



                                                                         5.2
                                                                           Pantelleria
                                                                                                                                                     5.0
                                                                                                     5.0




                                                                                                                                        Photovoltaic plants 7
Technical Application Papers




                                               1.3	Main components of a photovoltaic plants                      In the contact area between the two layers differently
                                                                                                                 doped (P-N junction), the electrons tend to move from
1 Generalities on photovoltaic (PV) plants




                                                                                                                 the electron rich half (N) to the electron poor half (P), thus
                                               1.3.1	 Photovoltaic generator                                     generating an accumulation of negative charge in the P
                                               The elementary component of a PV generator is the pho-            region. A dual phenomenon occurs for the electron holes,
                                               tovoltaic cell where the conversion of the solar radiation        with an accumulation of positive charge in the region N.
                                               into electric current is carried out. The cell is constituted     Therefore an electric field is created across the junction
                                               by a thin layer of semiconductor material, generally silicon      and it opposes the further diffusion of electric charges.
                                               properly treated, with a thickness of about 0.3 mm and            By applying a voltage from the outside, the junction
                                               a surface from 100 to 225 cm2.                                    allows the current to flow in one direction only (diode
                                               Silicon, which has four valence electrons (tetravalent), is       functioning).
                                               “doped” by adding trivalent atoms (e.g. boron – P doping)         When the cell is exposed to light, due to the photovoltaic
                                               on one “layer” and quantities of pentavalent atoms (e.g.          effect2 some electron-hole couples arise both in the N
                                               phosphorus – N doping) on the other one. The P-type               region as well as in the P region. The internal electric field
                                               region has an excess of holes, whereas the N-type region          allows the excess electrons (derived from the absorption
                                               has an excess of electrons (Figure 1.7).                          of the photons from part of the material) to be separated
                                                                                                                 from the holes and pushes them in opposite directions
                                                                                                                 in relation one to another. As a consequence, once the
                                                                                                                 electrons have passed the depletion region they cannot
                                                                                                                 move back since the field prevents them from flowing in
                                               Figure 1.7 - The photovoltaic cell                                the reverse direction. By connecting the junction with an
                                                                                                                 external conductor, a closed circuit is obtained, in which
                                               Silicon doped                                                     the current flows from the layer N, having higher potential,
                                                                                                                 to the layer N, having lower potential, as long as the cell
                                                                                                                 is illuminated (Figure 1.8).
                                                                  Si                Si        Si                 Figure 1.8 - How a photovoltaic cell works

                                                                                                      Free
                                                                        Hole                        electron                                                                                    Load

                                                                  B                 Si        P
                                                                                                                              Luminous                                    Electric current
                                                     BORON                                                                    radiation
                                                                                                    PHOSPHORUS
                                                      Atom                                             Atom


                                                                  Si                Si        Si
                                                                                                                                                                    N-type silicon
                                                                                                                                                              P-N junction
                                                                                                                                                   P-type silicon
                                                                                                                           Electron
                                                                                                                   Photons flow
                                                                                          Depletion region
                                                                                          Junction

                                                                                                                            Hole flow

                                                             +5        +5           +5   +3        +3      +3

                                                             +5        +5           +5   +3        +3      +3

                                                             +5        +5           +5   +3        +3      +3
                                                                                                                 2
                                                                                                                   The photovoltaic effect occurs when an electron in the valence band of a material
                                                                                                                 (generally a semiconductor) is promoted to the conduction band due to the absorption of
                                                             +5        +5           +5   +3        +3      +3    one sufficiently energetic photon (quantum of electromagnetic radiation) incident on the
                                                                                                                 material. In fact, in the semiconductor materials, as for insulating materials, the valence
                                                             +5        +5           +5   +3        +3      +3    electrons cannot move freely, but comparing semiconductor with insulating materials the
                                                                                                                 energy gap between the valence band and the conduction band (typical of conducting
                                                                                                                 materials) is small, so that the electrons can easily move to the conduction band when they
                                                             +5        +5           +5   +3        +3      +3    receive energy from the outside. Such energy can be supplied by the luminous radiation,
                                                                                                                 hence the photovoltaic effect.




                                             8 Photovoltaic plants
The silicon region which contributes to supply the cur-             On the market there are photovoltaic modules for sale
rent is the area surrounding the P-N junction; the electric         constituted by an assembly of cells. The most common




                                                                                                                                                       1 Generalities on photovoltaic (PV) plants
charges form in the far off areas, but there is not the             ones comprise 36 cells in 4 parallel rows connected in
electric field which makes them move and therefore they             series, with an area ranging from 0.5 to 1m2.
                                                                    Several modules mechanically and electrically connected
recombine. As a consequence it is important that the
                                                                    form a panel, that is a common structure which can be
PV cell has a great surface: the greater the surface, the           anchored to the ground or to a building (Figure 1.10).
higher the generated current.
                                                                    Figure 1.10
Figure 1.9 represents the photovoltaic effect and the
energy balance showing the considerable percentage
of incident solar energy which is not converted into
electric energy.

Figure 1.9 - Photovoltaic effect

  1 Separation of the charge
  2 Recombination
  3 Transmission
  4 Reflection and shading of the front contacts




                                                   Negative
                                                   electrode
                                       4                            Several panels electrically connected in series constitute
                                                         N Layer    an array and several arrays, electrically connected in
                                                                    parallel to generate the required power, constitute the
                                                                    generator or photovoltaic field (Figures 1.11 and 1.12).
       1                                                            Figure 1.11
                                                                                                               Panel
                                                                                                               several modules assembled
                                                                                                               into a single structure


              2                        1                                   Cell      Module
                                                                                                                                 Array
                                                       P-N region                                                                assembly of panels
                                                                                                                                 connected in series
 Positive
 contact                           1         P layer
                   3


100% of the incident solar energy
- 	3% reflection losses and shading of the front contacts
- 	23% photons with high wavelength, with insufficient
   energy to free electrons; heat is generated
- 	32% photons with short wavelength, with excess energy
                                                                    Photovoltaic generator
   (transmission) 	                                                 assembly of arrays connected
                                                                    in parallel to obtain the required power
- 	8.5% recombination of the free charge carriers
- 	20% electric gradient in the cell, above all in the transition
                                                                    Figure 1.12
   regions
- 	0.5% resistance in series, representing the conduction
   losses
= 13% usable electric energy



Under standard operating conditions (1W/m2 irradiance
at a temperature of 25° C) a PV cell generates a current
of about 3A with a voltage of 0.5V and a peak power
equal to 1.5-1.7Wp.

                                                                                                                    Photovoltaic plants 9
Technical Application Papers




                                                The PV cells in the modules are not exactly alike due to           esses where the lamination phase is required Ethylene
                                                the unavoidable manufacturing deviations; as a conse-              Vinyl Acetate (EVA) is often used;
1 Generalities on photovoltaic (PV) plants




                                                quence, two blocks of cells connected in parallel between       •	 a supporting substratum (glass, metal, plastic) on the
                                                them can have not the same voltage. As a consequence,              back;
                                                a flowing current is created from the block of cells at         •	 a metal frame, usually made of aluminum.
                                                higher voltage towards the block at lower voltage. There-
                                                fore a part of the power generated by the module is lost
                                                within the module itself (mismatch losses).
                                                The inequality of the cells can be determined also by a
                                                different solar irradiance, for example when a part of cells
                                                are shaded or when they are deteriorated. These cells
                                                                                                                Figure 1.13
                                                behave as a diode, blocking the current generated by the
                                                other cells. The diode is subject to the voltage of the other    Aluminum frame
                                                cells and it may cause the perforation of the junction with
                                                local overheating and damages to the module.
                                                Therefore the modules are equipped with by-pass diodes
                                                to limit such phenomenon by short-circuiting the shaded
                                                or damaged part of the module. The phenomenon of mis-
                                                match arises also between the arrays of the photovoltaic
                                                field, due to inequality of modules, different irradiance
                                                of the arrays, shadings and faults in an array. To avoid
                                                reverse current flowing among the arrays it is possible
                                                to insert diodes.
                                                The cells forming the module are encapsulated in an
                                                assembly system which:
                                                •	 electrically insulates the cells towards the outside;
                                                •	 protects the cells against the atmospheric agents and
                                                   against the mechanical stresses;
                                                •	 resists ultra violet rays, at low temperatures, sudden        Glass

                                                   changes of temperature and abrasion;
                                                                                                                              Supporting
                                                •	 gets rid of heat easily to prevent the temperature rise                    substratum                        Cells
                                                   from reducing the power supplied by the module.                                         EVA
                                                Such properties shall remain for the expected lifetime
                                                of the module. Figure 1.13 shows the cross-section of a
                                                standard module in crystalline silicon, made up by:
                                                •	 a protective sheet on the upper side exposed to light,
                                                   characterized by high transparency (the most used            In the crystal silicon modules, to connect the cells, metal-
                                                   material is tempered glass);                                 lic contacts soldered after the construction of the cells are
                                                •	 an encapsulation material to avoid the direct contact        used; in the thin film modules the electrical connection
                                                   between glass and cell, to eliminate the interstices due     is a part of the manufacturing process of the cells and it
                                                   to surface imperfections of the cells and electrically       is ensured by a layer of transparent metal oxides, such
                                                   insulate the cell from the rest of the panel; in the proc-   as zinc oxide or tin oxide.




                                             10 Photovoltaic plants
1.3.2	 Inverter                                                                         The power delivered by a PV generator depends on the
                                                                                        point where it operates. In order to maximize the energy




                                                                                                                                                                 1 Generalities on photovoltaic (PV) plants
The power conditioning and control system is constituted
                                                                                        supply by the plant, the generator shall adapt to the load,
by an inverter that converts direct current to alternating
                                                                                        so that the operating point always corresponds to the
current and controls the quality of the output power to                                 maximum power point.
be delivered to the grid, also by means of an L-C filter                                To this purpose, a controlled chopper called Maximum
inside the inverter itself. Figure 1.14 shows the principle                             Power Point Tracker (MPPT) is used inside the inverter.
scheme of an inverter. The transistors, used as static                                  The MPPT calculates instant by instant the pair of values
switches, are controlled by an opening-closing signal                                   “voltage-current” of the generator at which the maximum
which, in the simplest mode, would result in an output                                  available power is produced. Starting from the I-V curve
square waveform.                                                                        of the PV generator:
Figure 1.14 – Principle scheme of a single-phase inverter

+                                                                                   L
                                                                                        Maximum Power Point (MPP) for a photovoltaic generator
                                                                                        I




                                                                                                                          Maximum Power Point


-                                                                                   N


To obtain a waveform as sinusoidal as possible, a more
sophisticated technique – Pulse Width Modulation                                                                                                 V . I = const
(PWM) – is used; PWM technique allows a regulation to
be achieved on the frequency as well as on the r.m.s.
value of the output waveform (Figure 1.15).
                                                                                        0                                                                   V

Figure 1.15 – Operating principle of the PWM technology                                 The maximum point of power transfer corresponds to the
                                                                                        point of tangency between the I-V characteristic for a giv-
                   8                                                                    en value of solar radiation and the hyperbola of equation
                   6                                                                    V . I = const.
Vtr                                                                                     The MPPT systems commercially used identify the maxi-
        Vsin 4
                                                                                        mum power point on the characteristic curve of the gen-
                   2
                                                                                        erator by causing, at regular intervals, small variations of
        Volt (V)




                   0                                                                    loads which determine deviations of the voltage-current
                   -2                                                                   values and evaluating if the new product I-V is higher or
                                                                                        lower then the previous one. In case of a rise, the load
                   -4
                                                                                        conditions are kept varying in the considered direction.
                   -6                                                                   Otherwise, the conditions are modified in the opposite
                   -8                                                                   direction.
                        0    0,002   0,004   0,006   0,008       0,01   0,012   0,014

                                                             time (s)                   Due to the characteristics of the required performances
                                                                                        the inverters for stand-alone plants and for grid-connect-
                                                                                        ed plants shall have different characteristics:
                                                                                        •	 in the stand-alone plants the inverters shall be able to
                                                                                           supply a voltage AC side as constant as possible at
                                                                                           the varying of the production of the generator and of
                                                                                           the load demand;
                                                                                        •	 in the grid-connected plants the inverters shall repro-
                                                                                           duce, as exactly as possible, the network voltage and
                        m = Vsin / Vtr <1                                                  at the same time try to optimize and maximize the
                                                                                           energy output of the PV panels.



                                                                                                                                   Photovoltaic plants 11
Technical Application Papers




                                                1.4	Typologies of photovoltaic panels                          •	 polycrystalline silicon panels (Figure 1.17), where the
                                                                                                                  crystals constituting the cells aggregate taking different
1 Generalities on photovoltaic (PV) plants




                                                                                                                  forms and directions. In fact, the iridescences typical of
                                                1.4.1	 Crystal silicon panels                                     polycrystalline silicon cells are caused by the different
                                                For the time being the crystal silicon panels are the most        direction of the crystals and the consequent different
                                                used and are divided into two categories:                         behavior with respect to light. The polycrystalline silicon
                                                •	 single crystalline silicon (Figure 1.16), homogeneous          ingot is obtained by melting and casting the silicon
                                                  single crystal panels are made of silicon crystal of high       into a parallelepiped-shaped mould. The wafers thus
                                                  purity. The single-crystal silicon ingot has cylindrical        obtained are square shape and have typical striations
                                                  form, 13-20 cm diameter and 200 cm length, and is               of 180-300 μm thickness.
                                                  obtained by growth of a filiform crystal in slow rotation.   	 The efficiency is lower in comparison with single
                                                  Afterwards, this cylinder is sliced into wafers 200-250         crystalline silicon (12 to 14%), but also the cost, 2.8
                                                  μm thick and the upper surface is treated to obtain             to 3.3 €/W. Anyway the duration is high (comparable
                                                  “microgrooves” aimed at minimizing the reflection               to single crystalline silicon) and also the maintenance
                                                  losses.                                                         of performances in time (85% of the initial efficiency
                                                	 The main advantage of these cells is the efficiency (14         after 20 years).
                                                  to 17%), together with high duration and maintenance         	 The cells made with such technology can be recog-
                                                  of the characteristics in time3 .                               nized because of the surface aspect where crystal
                                                	 The cost of these module is about 3.2 to 3.5 €/W                grains are quite visible.
                                                  and the panels made with this technology are usually
                                                  characterized by a homogenous dark blue color4.




                                                Figure 1.16 – Single crystalline silicon panel                 Figure 1.17 – Polycrystalline silicon panel




                                                                                                               3
                                                                                                                Some manufacturers guarantee the panels for 20 years with a maximum loss of efficiency
                                                                                                               of 10% with respect to the nominal value.
                                                                                                               4
                                                                                                                The dark blue color is due to the titan oxide antireflective coating, which has the purpose
                                                                                                               of improving the collection of solar radiation.



                                             12 Photovoltaic plants
Nowadays the market is dominated by crystal silicon             Amorphous Silicon (symbol a-Si) deposited as film on
technology, which represents about 90% of it. Such              a support (e.g. aluminum) offers the opportunity of hav-




                                                                                                                                        1 Generalities on photovoltaic (PV) plants
technology is ripe in terms of both obtainable efficiency       ing PV technology at reduced costs in comparison with
and manufacturing costs and it will probably continue           crystalline silicon, but the efficiency of these cells tends
to dominate the market in the short-medium period.              to get worse in the time. Amorphous silicon can also be
Only some slight improvements are expected in terms             “sprayed” on a thin sheet of plastic or flexible material.
of efficiency (new industrial products declare 18%,             It is used above all when it is necessary to reduce maxi-
with a laboratory record of 24.7%, which is considered          mally the weight of the panel and to adapt it to curved
practically insurmountable) and a possible reduction of         surfaces. The efficiency of a-Si (5% to 6%) is very low
the costs linked both to the introduction in the industrial     due to the many resistances that the electrons have to
processes of bigger and thinner wafers as well as to the        face in their flux. Also in this case the cell performances
economies of scale. Besides, the PV industry based on           tend to get worse in the time. An interesting application
such technology uses the surplus of silicon intended for        of this technology is the “tandem” one, combining an
the electronics industry but, due to the constant develop-      amorphous silicon layer with one or more multi-junction
ment of the last and to the exponential growth of the PV        crystalline silicon layers; thanks to the separation of the
production at an average rate of 40% in the last six years,     solar spectrum, each junction positioned in sequence
the availability on the market of raw material to be used       works at its best and guarantees higher levels in terms
in the photovoltaic sector is becoming more limited.            both of efficiency as well as endurance.

                                                                CdTeS solar cells consist of one P-layer (CdTe) and one
1.4.2	 Thin film panels                                         N-layer (CdS) which form a hetero-junction P-N.
                                                                CdTeS cells have higher efficiency than amorphous
Thin film cells are composed by semiconducting material
                                                                silicon cells: 10% to 11% for industrial products (15.8%
deposited, usually as gas mixtures, on supports as glass,
                                                                in test laboratories). The production on a large scale of
polymers, aluminum, which give physical consistency to
                                                                CdTeS technology involves the environmental problem
the mixture. The semiconductor film layer is a few µm in
                                                                as regards the CdTe contained in the cell: since it is not
thickness with respect to crystalline silicon cells which
                                                                soluble in water and it is more stable than other com-
are some hundreds µm. As a consequence, the saving
                                                                pounds containing cadmium, it may become a problem
of material is remarkable and the possibility of having a
                                                                when not properly recycled or used (Figure 1.19). The
flexible support increases the application field of thin film
                                                                unit cost of such modules is 1.5 to 2.2 €/W.
cells (Figure 1.18).
                                                                Nowadays GaAs technology is the most interesting one
The used materials are:
                                                                if considered from the point of view of the obtained ef-
•	 Amorphous Silicon;
                                                                ficiency, higher than 25 to 30%, but the production of
•	 CdTeS (Cadmium Telluride-Cadmium Sulfide);
                                                                such cells is limited by the high costs and by the scarcity
•	 GaAs (Gallum Arsenide);
•	 CIS, CIGS and CIGSS (Copper Iridium Diselenide al-           Figure 1.19 – Structures of thin film cells based on CdTe-CdS
   loys).
                                                                                                                  Calcic-sodium glass

Figure 1.18 – Thin film module
                                                                                                                  Indium-Tin Oxide
                                                                                                                  (ITO 400nm)


                                                                                                                  Buffer layer
                                                                                                                  100-200nm


                                                                                                                  Cadmium Sulfide
                                                                                                                  (CdS 60nm)



                                                                                                                  Cadmium Telluride
                                                                                                                  (CdTe 6nm)



                                                                                                                  Tellurium Antinomy
                                                                                                                  (Sb2 Te3 200nm)


                                                                                                                  Molybdenum
                                                                                                                  (Mo 200nm)


                                                                                                             Photovoltaic plants 13
Technical Application Papers




                                                of the material, which is prevailingly used in the “high                                light component is more marked and the radiation levels
                                                speed semiconductors” and optoelectronics industry.                                     are low, above all on cloudy days.
1 Generalities on photovoltaic (PV) plants




                                                In fact, GaAs technology is used mainly for space ap-
                                                plications where weights and reduced dimensions play
                                                an important role.

                                                CIS/CIGS/CIGSS modules are part of a technology
                                                which is still under study and being developed. Silicon
                                                is replaced with special alloys such as:
                                                •	 copper, indium and selenite (CIS);
                                                                                                                                        Table 1.1
                                                •	 copper, indium, gallium and selenite (CIGS);
                                                                                                                                                        Single crystalline       Polycrystalline          Thin film
                                                •	 copper, indium, gallium, selenite and sulphur (CIGSS).                                                    silicon                 silicon            (amorphous
                                                Nowadays the efficiency is 10 to 11% and the perform-                                                                                                      silicon)
                                                                                                                                                           14% - 17%               12% - 14%            4-6% single
                                                ances remain constant in time; as for single crystalline and                            η cell
                                                                                                                                                                                                       7-10% tandem
                                                polycrystalline silicon a reduction in the production cost                                                    high η               lower cost            lower cost
                                                is foreseen, for the time being around 2.2-2.5 €/W.                                                        constant η           simpler production reduced influence
                                                                                                                                                                                                   of the temperature
                                                                                                                                        Advantages
                                                The market share of thin film technologies is still very lim-                                                reliable            optimum overall        higher energy
                                                                                                                                                           technology              dimensions             output with
                                                ited (≈7%), but the solutions with the highest capacities in                                                                                          diffused radiation
                                                the medium-long term are being taken into consideration                                                   higher energy            sensitivity to     bigger dimensions
                                                for a substantial price reduction. By depositing the thin                                                                        impurities in the
                                                                                                                                        Disadvantages quantity necessary          manufacturing
                                                                                                                                                                                                         cost of the
                                                                                                                                                        for production                                 structure and
                                                film directly on a large scale, more than 5 m2, the scraps,                                                                         processes          assembly time
                                                which are typical of the slicing operation to get crystal-
                                                line silicon wafers from the initial ingot, are avoided.
                                                The deposition techniques are low power consumption
                                                                                                                                        Table 1.2
                                                processes and consequently the relevant payback time
                                                is short, that is only the time for which a PV plant shall                                                 GaAs (Gallum                 CdTe             CIS (Copper
                                                                                                                                                            Arsenide)                (Cadmium         Iridium Selenide
                                                be running before the power used to build it has been                                                                                 Telluride)            alloys)
                                                generated (about 1 year for amorphous silicon thin films                                η cell                 32,5%                    11%                 12%
                                                against the 2 years of crystalline silicon). In comparison                                           high resistance at
                                                with crystalline silicon modules thin film modules show                                 Advantages   high temperatures                low cost          very constant
                                                                                                                                                   (ok for concentrators)
                                                a lower dependence of efficiency on the operating tem-
                                                                                                                                                               toxicity                toxicity
                                                perature and a good response also when the diffused                                     Disadvantages                                                      toxicity
                                                                                                                                                          availability of the       availability of
                                                                                                                                                              materials             the materials
                                                5
                                                  According to some studies in this field, by 2020 the market share of thin films may
                                                reach 30% to 40%.




                                             14 Photovoltaic plants
1.5 Typologies of photovoltaic plants                         Figure 1.20 – Photovoltaic shelters and street lamps supplied by photo-
                                                              voltaic power




                                                                                                                                                  1 Generalities on photovoltaic (PV) plants
1.5.1 Stand-alone plants
Stand-alone plants are plants which are not connected to
the grid and consist of PV panels and of a storage system
which guarantees electric energy supply also when light-
ing is poor or when it is dark. Since the current delivered
by the PV generator is DC power, if the user plant needs
AC current an inverter becomes necessary.
Such plants are advantageous from a technical and fi-
nancial point of view whenever the electric network is not
present or whenever it is not easy to reach, since they can
replace motor generator sets. Besides, in a stand-alone
configuration, the PV field is over-dimensioned so that,
during the insolation hours, both the load supply as well
as the recharge of the storing batteries can be guaranteed
with a certain safety margin taking into account the days
of poor insolation.

At present the most common applications are used to
supply (Figure 1.20):
•	 pumping water equipment;
•	 radio repeaters, weather or seismic observation and
   data transmission stations;
•	 lightning systems;
•	 systems of signs for roads, harbors and airports;
•	 service supply in campers;
•	 advertising installations;
•	 refuges at high altitudes.

                                                              Figure 1.21 shows the principle diagram of a stand-alone
                                                              PV plant.

Figure 1.21




                                                                         5                                7




                                                                     3               6



                                                          2
                                                                                                4


                                                              1 PV generator                          5       Possible DC loads
                                                              2 Switchboards on DC side               6       DC/AC static converter (inverter)
                                   1
                                                              3 Load regulator                        7       AC loads

                                                              4 Storage system (battery)                      DC connections
                                                                                                              AC connections



                                                                                                               Photovoltaic plants 15
Technical Application Papers




                                                1.5.2	 Grid-connected plants                               Figure 1.23

                                                Permanently grid-connected plants draw power from
1 Generalities on photovoltaic (PV) plants




                                                the grid during the hours when the PV generator cannot                                                  LV grid
                                                produce the energy necessary to satisfy the needs of the
                                                                                                                                                                  Power from
                                                consumer. On the contrary, if the PV system produces                                                              the grid
                                                excess electric power, the surplus is put into the grid,
                                                                                                                                                                        Power to the
                                                which therefore can operate as a big accumulator: as a                                                                  grid
                                                consequence, grid-connected systems don’t need ac-
                                                cumulator banks (Figure 1.22).

                                                These plants (Figure 1.23) offer the advantage of dis-                                       Inverter
                                                tributed - instead of centralized – generation: in fact
                                                Figure 1.22




                                                                                                           the energy produced near the consumption area has a
                                                                                                           value higher than that produced in traditional large power
                                                                                                           plants, because the transmission losses are limited and
                                                                                                           the expenses of the big transport and dispatch electric
                                                                                                           systems are reduced. In addition, the energy produc-
                                                                                                           tion in the insolation hours allows the requirements for
                                                                                                           the grid to be reduced during the day, that is when the
                                                                                                           demand is higher.

                                                                                                           Figure 1.24 shows the principle diagram of a grid-con-
                                                                                                           nected photovoltaic plant.


                                                Figure 1.24




                                                                                                                                                                  5

                                                                                                                                            4



                                                                                                                               3


                                                                                                       2




                                                                                                                1 PV generator

                                                                                                                2 Switchboards on DC side
                                                                                  1
                                                                                                                3 DC/AC static converter (inverter)
                                                                                                                4 Switchboard on AC side                          DC connections
                                                                                                                5 Distributor network                             AC connections



                                             16 Photovoltaic plants
1.6	Intermittence of generation and storage of                   batteries and the hydrogen one. At the state of the art
     the produced power




                                                                                                                              1 Generalities on photovoltaic (PV) plants
                                                                 of these two technologies, the electrochemical storage
                                                                 seems feasible, in the short-medium term, to store the
The PV utilization on a large scale is affected by a techni-     energy for some hours to some days. Therefore, in rela-
cal limit due to the uncertain intermittency of production.      tion to photovoltaics applied to small grid-connected
In fact, the national electrical distribution network can        plants, the insertion of a storage sub-system consist-
accept a limited quantity of intermittent input power, after     ing in batteries of small dimensions may improve the
which serious problems for the stability of the network          situation of the inconveniences due to intermittency,
can rise. The acceptance limit depends on the network            thus allowing a partial overcoming of the acceptance
configuration and on the degree of interconnection with          limit of the network. As regards the seasonal storage of
the contiguous grids.                                            the huge quantity of electric power required to replace
In particular, in the Italian situation, it is considered dan-   petroleum in all the usage sectors, hydrogen seems to
gerous when the total intermittent power introduced into         be the most suitable technology for the long term since
the network exceeds a value from 10% to 20% of the total         it takes advantage of the fact that solar electric produc-
power of the traditional power generation plants.                tivity in summer is higher than the winter productivity of
As a consequence, the presence of a constraint due to            about a factor 3. The exceeding energy stored in summer
the intermittency of power generation restricts the real         could be used to optimize the annual capacity factor of
possibility of giving a significant PV contribution to the       renewable source power plants, increasing it from the
national energy balance and this remark can be extended          present value of 1500-1600 hours without storage to a
to all intermittent renewable sources.                           value nearer to the average one of the conventional power
To get round this negative aspect it would be necessary          plants (about 6000 hours). In this case the power from
to store for sufficiently long times the intermittent electric   renewable source could replace the thermoelectric one
power thus produced to put it into the network in a more         in its role, since the acceptance limit of the grid would
continuous and stable form. Electric power can be stored         be removed.
either in big superconducting coils or converting it into
other form of energy: kinetic energy stored in flywheels or
compressed gases, gravitational energy in water basins,
chemical energy in synthesis fuels and electrochemical
energy in electric accumulators (batteries). Through a
technical selection of these options according to the
requirement of maintaining energy efficiently for days
and/or months, two storage systems emerge: that using




                                                                                                    Photovoltaic plants 17

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Lezione 1

  • 1. PART I 1 Generalities on photovoltaic (PV) plants 1.1 Operating principle 1.2 Energy from the Sun 1 Generalities on photovoltaic (PV) plants A photovoltaic (PV) plant transforms directly and instan- In the solar core thermonuclear fusion reactions occur taneously solar energy into electrical energy without us- unceasingly at millions of degrees; they release huge ing any fuels. As a matter of fact, the photovoltaic (PV) quantities of energy in the form of electromagnetic ra- technology exploits the photoelectric effect, through diations. A part of this energy reaches the outer area of which some semiconductors suitably “doped” generate the Earth’s atmosphere with an average irradiance (solar electricity when exposed to solar radiation. constant) of about 1,367 W/m2 ± 3%, a value which varies as a function of the Earth-to-Sun distance (Figure 1.1)1 The main advantages of photovoltaic (PV) plants can be and of the solar activity (sunspots). summarized as follows: Figure 1.1 - Extra-atmospheric radiation • distribuited generation where needed; W/m2 • no emission of polluting materials; 1400 • saving of fossil fuels; • reliability of the plants since they do not have moving 1380 parts (useful life usually over 20 years); 1360 • reduced operating and maintenance costs; • system modularity (to increase the plant power it is 1340 sufficient to raise the number of panels) according to the real requirements of users. 1320 However, the initial cost for the development of a PV plant 1300 is quite high due to a market which has not reached its J F M A M J J A S O N D full maturity from a technical and economical point of Month view. Moreover the generation of power is erratic due to With solar irradiance we mean the intensity of the solar the variability of the solar energy source. electromagnetic radiation incident on a surface of 1 square meter [kW/m2]. Such intensity is equal to the The annual electrical power output of a PV plant depends integral of the power associated to each value of the on different factors. Among them: frequency of the solar radiation spectrum. • solar radiation incident on the installation site; When passing through the atmosphere, the solar radia- • inclination and orientation of the panels; tion diminishes in intensity because it is partially reflected • presence or not of shading; and absorbed (above all by the water vapor and by the • technical performances of the plant components other atmospheric gases). The radiation which passes (mainly modules and inverters). through is partially diffused by the air and by the solid par- ticles suspended in the air (Figure 1.2). The main applications of PV plants are: Figure 1.2 - Energy flow between the sun, the atmosphere and the ground 1. installations (with storage systems) for users iso- 25% reflected lated from the grid; by the atmosphere 2. installations for users connected to the LV grid; 3. solar PV power plants, usually connected to the MV grid. Feed-in Tariff incentives are granted only 18% diffused by the atmosphere for the applications of type 2 and 3, in plants with 5% reflected by the ground rated power not lower than 1 kW. 5% absorbed by the atmosphere A PV plant is essentially constituted by a generator (PV panels), by a supporting frame to mount the panels on the ground, on a building or on any building structure, by a system for power control and conditioning, by a pos- sible energy storage system, by electrical switchboards and switchgear assemblies housing the switching and protection equipment and by the connection cables. 27% absorbed by the soil surface 1 Due to its elliptical orbit the Earth is at its least distance from the Sun (perihelion) in December and January and at its greatest distance (aphelion) in June and July. Photovoltaic plants 5
  • 2. Technical Application Papers With solar irradiation we mean the integral of the solar The reflected radiation depends on the capability of a irradiance over a specified period of time [kWh/m 2]. surface to reflect the solar radiation and it is measured 1 Generalities on photovoltaic (PV) plants Therefore the radiation falling on a horizontal surface is by the albedo coefficient calculated for each material constituted by a direct radiation, associated to the direct (figure 1.4). irradiance on the surface, by a diffuse radiation which Figure 1.4 - Reflected radiation strikes the surface from the whole sky and not from a Surface type albedo specific part of it and by a radiation reflected on a given Dirt roads 0.04 surface by the ground and by the surrounding environ- ment (Figure 1.3). In winter the sky is overcast and the Aqueous surfaces 0.07 diffuse component is greater than the direct one. Coniferous forest in winter 0.07 Figure 1.3 - Components of solar radiation Worn asphalt 0.10 Bitumen roofs and terraces 0.13 Soil (clay, marl) 0.14 Dry grass 0.20 Rubble 0.20 solar constant Worn concrete 0.22 Reduction of solar radiation Forest in autumn / fields 0.26 Green grass 0.26 Dark surfaces of buildings 0.27 Diffuse Direct Dead leaves 0.30 Bright surfaces of buildings 0.60 Reflected Fresh snow 0.75 Figure 1.5 shows the world atlas of the average solar Figure 1.5 - Solar Atlas irradiance on an inclined plan 30° South [kWh/m2/day] 1 kWh/m2 2 kWh/m2 3 kWh/m2 4 kWh/m2 5 kWh/m2 6 kWh/m2 7 kWh/m2 6 Photovoltaic plants
  • 3. In Italy the average annual irradiance varies from the 3.6 about 2 MWh (5.4 . 365) per year from each square meter, kWh/m2 a day of the Po Valley to the 4.7 kWh/m2 a day that is the energetic equivalent of 1.5 petroleum barrels 1 Generalities on photovoltaic (PV) plants in the South-Centre and the 5.4 kWh/m2/day of Sicily for each square meter, whereas the rest of Italy ranges (Figure 1.6). from the 1750 kWh/m2 of the Tyrrhenian strip and the Therefore, in the favorable regions it is possible to draw 1300 kWh/m2 of the Po Valley. Figure 1.6 - Daily global irradiation in kWh/m2 3.6 3.8 4.4 4.0 Bolzano 4.0 4.2 Milan Venice Trieste 4.4 4.6 3.8 Genoa 4.8 Ancona 5.0 4.8 5.0 5.2 4 4. Pianosa Rome 4.8 Brindisi Naples 5.2 Alghero 5. 2 Messina Trapani 5.2 Pantelleria 5.0 5.0 Photovoltaic plants 7
  • 4. Technical Application Papers 1.3 Main components of a photovoltaic plants In the contact area between the two layers differently doped (P-N junction), the electrons tend to move from 1 Generalities on photovoltaic (PV) plants the electron rich half (N) to the electron poor half (P), thus 1.3.1 Photovoltaic generator generating an accumulation of negative charge in the P The elementary component of a PV generator is the pho- region. A dual phenomenon occurs for the electron holes, tovoltaic cell where the conversion of the solar radiation with an accumulation of positive charge in the region N. into electric current is carried out. The cell is constituted Therefore an electric field is created across the junction by a thin layer of semiconductor material, generally silicon and it opposes the further diffusion of electric charges. properly treated, with a thickness of about 0.3 mm and By applying a voltage from the outside, the junction a surface from 100 to 225 cm2. allows the current to flow in one direction only (diode Silicon, which has four valence electrons (tetravalent), is functioning). “doped” by adding trivalent atoms (e.g. boron – P doping) When the cell is exposed to light, due to the photovoltaic on one “layer” and quantities of pentavalent atoms (e.g. effect2 some electron-hole couples arise both in the N phosphorus – N doping) on the other one. The P-type region as well as in the P region. The internal electric field region has an excess of holes, whereas the N-type region allows the excess electrons (derived from the absorption has an excess of electrons (Figure 1.7). of the photons from part of the material) to be separated from the holes and pushes them in opposite directions in relation one to another. As a consequence, once the electrons have passed the depletion region they cannot move back since the field prevents them from flowing in Figure 1.7 - The photovoltaic cell the reverse direction. By connecting the junction with an external conductor, a closed circuit is obtained, in which Silicon doped the current flows from the layer N, having higher potential, to the layer N, having lower potential, as long as the cell is illuminated (Figure 1.8). Si Si Si Figure 1.8 - How a photovoltaic cell works Free Hole electron Load B Si P Luminous Electric current BORON radiation PHOSPHORUS Atom Atom Si Si Si N-type silicon P-N junction P-type silicon Electron Photons flow Depletion region Junction Hole flow +5 +5 +5 +3 +3 +3 +5 +5 +5 +3 +3 +3 +5 +5 +5 +3 +3 +3 2 The photovoltaic effect occurs when an electron in the valence band of a material (generally a semiconductor) is promoted to the conduction band due to the absorption of +5 +5 +5 +3 +3 +3 one sufficiently energetic photon (quantum of electromagnetic radiation) incident on the material. In fact, in the semiconductor materials, as for insulating materials, the valence +5 +5 +5 +3 +3 +3 electrons cannot move freely, but comparing semiconductor with insulating materials the energy gap between the valence band and the conduction band (typical of conducting materials) is small, so that the electrons can easily move to the conduction band when they +5 +5 +5 +3 +3 +3 receive energy from the outside. Such energy can be supplied by the luminous radiation, hence the photovoltaic effect. 8 Photovoltaic plants
  • 5. The silicon region which contributes to supply the cur- On the market there are photovoltaic modules for sale rent is the area surrounding the P-N junction; the electric constituted by an assembly of cells. The most common 1 Generalities on photovoltaic (PV) plants charges form in the far off areas, but there is not the ones comprise 36 cells in 4 parallel rows connected in electric field which makes them move and therefore they series, with an area ranging from 0.5 to 1m2. Several modules mechanically and electrically connected recombine. As a consequence it is important that the form a panel, that is a common structure which can be PV cell has a great surface: the greater the surface, the anchored to the ground or to a building (Figure 1.10). higher the generated current. Figure 1.10 Figure 1.9 represents the photovoltaic effect and the energy balance showing the considerable percentage of incident solar energy which is not converted into electric energy. Figure 1.9 - Photovoltaic effect 1 Separation of the charge 2 Recombination 3 Transmission 4 Reflection and shading of the front contacts Negative electrode 4 Several panels electrically connected in series constitute N Layer an array and several arrays, electrically connected in parallel to generate the required power, constitute the generator or photovoltaic field (Figures 1.11 and 1.12). 1 Figure 1.11 Panel several modules assembled into a single structure 2 1 Cell Module Array P-N region assembly of panels connected in series Positive contact 1 P layer 3 100% of the incident solar energy - 3% reflection losses and shading of the front contacts - 23% photons with high wavelength, with insufficient energy to free electrons; heat is generated - 32% photons with short wavelength, with excess energy Photovoltaic generator (transmission) assembly of arrays connected in parallel to obtain the required power - 8.5% recombination of the free charge carriers - 20% electric gradient in the cell, above all in the transition Figure 1.12 regions - 0.5% resistance in series, representing the conduction losses = 13% usable electric energy Under standard operating conditions (1W/m2 irradiance at a temperature of 25° C) a PV cell generates a current of about 3A with a voltage of 0.5V and a peak power equal to 1.5-1.7Wp. Photovoltaic plants 9
  • 6. Technical Application Papers The PV cells in the modules are not exactly alike due to esses where the lamination phase is required Ethylene the unavoidable manufacturing deviations; as a conse- Vinyl Acetate (EVA) is often used; 1 Generalities on photovoltaic (PV) plants quence, two blocks of cells connected in parallel between • a supporting substratum (glass, metal, plastic) on the them can have not the same voltage. As a consequence, back; a flowing current is created from the block of cells at • a metal frame, usually made of aluminum. higher voltage towards the block at lower voltage. There- fore a part of the power generated by the module is lost within the module itself (mismatch losses). The inequality of the cells can be determined also by a different solar irradiance, for example when a part of cells are shaded or when they are deteriorated. These cells Figure 1.13 behave as a diode, blocking the current generated by the other cells. The diode is subject to the voltage of the other Aluminum frame cells and it may cause the perforation of the junction with local overheating and damages to the module. Therefore the modules are equipped with by-pass diodes to limit such phenomenon by short-circuiting the shaded or damaged part of the module. The phenomenon of mis- match arises also between the arrays of the photovoltaic field, due to inequality of modules, different irradiance of the arrays, shadings and faults in an array. To avoid reverse current flowing among the arrays it is possible to insert diodes. The cells forming the module are encapsulated in an assembly system which: • electrically insulates the cells towards the outside; • protects the cells against the atmospheric agents and against the mechanical stresses; • resists ultra violet rays, at low temperatures, sudden Glass changes of temperature and abrasion; Supporting • gets rid of heat easily to prevent the temperature rise substratum Cells from reducing the power supplied by the module. EVA Such properties shall remain for the expected lifetime of the module. Figure 1.13 shows the cross-section of a standard module in crystalline silicon, made up by: • a protective sheet on the upper side exposed to light, characterized by high transparency (the most used In the crystal silicon modules, to connect the cells, metal- material is tempered glass); lic contacts soldered after the construction of the cells are • an encapsulation material to avoid the direct contact used; in the thin film modules the electrical connection between glass and cell, to eliminate the interstices due is a part of the manufacturing process of the cells and it to surface imperfections of the cells and electrically is ensured by a layer of transparent metal oxides, such insulate the cell from the rest of the panel; in the proc- as zinc oxide or tin oxide. 10 Photovoltaic plants
  • 7. 1.3.2 Inverter The power delivered by a PV generator depends on the point where it operates. In order to maximize the energy 1 Generalities on photovoltaic (PV) plants The power conditioning and control system is constituted supply by the plant, the generator shall adapt to the load, by an inverter that converts direct current to alternating so that the operating point always corresponds to the current and controls the quality of the output power to maximum power point. be delivered to the grid, also by means of an L-C filter To this purpose, a controlled chopper called Maximum inside the inverter itself. Figure 1.14 shows the principle Power Point Tracker (MPPT) is used inside the inverter. scheme of an inverter. The transistors, used as static The MPPT calculates instant by instant the pair of values switches, are controlled by an opening-closing signal “voltage-current” of the generator at which the maximum which, in the simplest mode, would result in an output available power is produced. Starting from the I-V curve square waveform. of the PV generator: Figure 1.14 – Principle scheme of a single-phase inverter + L Maximum Power Point (MPP) for a photovoltaic generator I Maximum Power Point - N To obtain a waveform as sinusoidal as possible, a more sophisticated technique – Pulse Width Modulation V . I = const (PWM) – is used; PWM technique allows a regulation to be achieved on the frequency as well as on the r.m.s. value of the output waveform (Figure 1.15). 0 V Figure 1.15 – Operating principle of the PWM technology The maximum point of power transfer corresponds to the point of tangency between the I-V characteristic for a giv- 8 en value of solar radiation and the hyperbola of equation 6 V . I = const. Vtr The MPPT systems commercially used identify the maxi- Vsin 4 mum power point on the characteristic curve of the gen- 2 erator by causing, at regular intervals, small variations of Volt (V) 0 loads which determine deviations of the voltage-current -2 values and evaluating if the new product I-V is higher or lower then the previous one. In case of a rise, the load -4 conditions are kept varying in the considered direction. -6 Otherwise, the conditions are modified in the opposite -8 direction. 0 0,002 0,004 0,006 0,008 0,01 0,012 0,014 time (s) Due to the characteristics of the required performances the inverters for stand-alone plants and for grid-connect- ed plants shall have different characteristics: • in the stand-alone plants the inverters shall be able to supply a voltage AC side as constant as possible at the varying of the production of the generator and of the load demand; • in the grid-connected plants the inverters shall repro- duce, as exactly as possible, the network voltage and m = Vsin / Vtr <1 at the same time try to optimize and maximize the energy output of the PV panels. Photovoltaic plants 11
  • 8. Technical Application Papers 1.4 Typologies of photovoltaic panels • polycrystalline silicon panels (Figure 1.17), where the crystals constituting the cells aggregate taking different 1 Generalities on photovoltaic (PV) plants forms and directions. In fact, the iridescences typical of 1.4.1 Crystal silicon panels polycrystalline silicon cells are caused by the different For the time being the crystal silicon panels are the most direction of the crystals and the consequent different used and are divided into two categories: behavior with respect to light. The polycrystalline silicon • single crystalline silicon (Figure 1.16), homogeneous ingot is obtained by melting and casting the silicon single crystal panels are made of silicon crystal of high into a parallelepiped-shaped mould. The wafers thus purity. The single-crystal silicon ingot has cylindrical obtained are square shape and have typical striations form, 13-20 cm diameter and 200 cm length, and is of 180-300 μm thickness. obtained by growth of a filiform crystal in slow rotation. The efficiency is lower in comparison with single Afterwards, this cylinder is sliced into wafers 200-250 crystalline silicon (12 to 14%), but also the cost, 2.8 μm thick and the upper surface is treated to obtain to 3.3 €/W. Anyway the duration is high (comparable “microgrooves” aimed at minimizing the reflection to single crystalline silicon) and also the maintenance losses. of performances in time (85% of the initial efficiency The main advantage of these cells is the efficiency (14 after 20 years). to 17%), together with high duration and maintenance The cells made with such technology can be recog- of the characteristics in time3 . nized because of the surface aspect where crystal The cost of these module is about 3.2 to 3.5 €/W grains are quite visible. and the panels made with this technology are usually characterized by a homogenous dark blue color4. Figure 1.16 – Single crystalline silicon panel Figure 1.17 – Polycrystalline silicon panel 3 Some manufacturers guarantee the panels for 20 years with a maximum loss of efficiency of 10% with respect to the nominal value. 4 The dark blue color is due to the titan oxide antireflective coating, which has the purpose of improving the collection of solar radiation. 12 Photovoltaic plants
  • 9. Nowadays the market is dominated by crystal silicon Amorphous Silicon (symbol a-Si) deposited as film on technology, which represents about 90% of it. Such a support (e.g. aluminum) offers the opportunity of hav- 1 Generalities on photovoltaic (PV) plants technology is ripe in terms of both obtainable efficiency ing PV technology at reduced costs in comparison with and manufacturing costs and it will probably continue crystalline silicon, but the efficiency of these cells tends to dominate the market in the short-medium period. to get worse in the time. Amorphous silicon can also be Only some slight improvements are expected in terms “sprayed” on a thin sheet of plastic or flexible material. of efficiency (new industrial products declare 18%, It is used above all when it is necessary to reduce maxi- with a laboratory record of 24.7%, which is considered mally the weight of the panel and to adapt it to curved practically insurmountable) and a possible reduction of surfaces. The efficiency of a-Si (5% to 6%) is very low the costs linked both to the introduction in the industrial due to the many resistances that the electrons have to processes of bigger and thinner wafers as well as to the face in their flux. Also in this case the cell performances economies of scale. Besides, the PV industry based on tend to get worse in the time. An interesting application such technology uses the surplus of silicon intended for of this technology is the “tandem” one, combining an the electronics industry but, due to the constant develop- amorphous silicon layer with one or more multi-junction ment of the last and to the exponential growth of the PV crystalline silicon layers; thanks to the separation of the production at an average rate of 40% in the last six years, solar spectrum, each junction positioned in sequence the availability on the market of raw material to be used works at its best and guarantees higher levels in terms in the photovoltaic sector is becoming more limited. both of efficiency as well as endurance. CdTeS solar cells consist of one P-layer (CdTe) and one 1.4.2 Thin film panels N-layer (CdS) which form a hetero-junction P-N. CdTeS cells have higher efficiency than amorphous Thin film cells are composed by semiconducting material silicon cells: 10% to 11% for industrial products (15.8% deposited, usually as gas mixtures, on supports as glass, in test laboratories). The production on a large scale of polymers, aluminum, which give physical consistency to CdTeS technology involves the environmental problem the mixture. The semiconductor film layer is a few µm in as regards the CdTe contained in the cell: since it is not thickness with respect to crystalline silicon cells which soluble in water and it is more stable than other com- are some hundreds µm. As a consequence, the saving pounds containing cadmium, it may become a problem of material is remarkable and the possibility of having a when not properly recycled or used (Figure 1.19). The flexible support increases the application field of thin film unit cost of such modules is 1.5 to 2.2 €/W. cells (Figure 1.18). Nowadays GaAs technology is the most interesting one The used materials are: if considered from the point of view of the obtained ef- • Amorphous Silicon; ficiency, higher than 25 to 30%, but the production of • CdTeS (Cadmium Telluride-Cadmium Sulfide); such cells is limited by the high costs and by the scarcity • GaAs (Gallum Arsenide); • CIS, CIGS and CIGSS (Copper Iridium Diselenide al- Figure 1.19 – Structures of thin film cells based on CdTe-CdS loys). Calcic-sodium glass Figure 1.18 – Thin film module Indium-Tin Oxide (ITO 400nm) Buffer layer 100-200nm Cadmium Sulfide (CdS 60nm) Cadmium Telluride (CdTe 6nm) Tellurium Antinomy (Sb2 Te3 200nm) Molybdenum (Mo 200nm) Photovoltaic plants 13
  • 10. Technical Application Papers of the material, which is prevailingly used in the “high light component is more marked and the radiation levels speed semiconductors” and optoelectronics industry. are low, above all on cloudy days. 1 Generalities on photovoltaic (PV) plants In fact, GaAs technology is used mainly for space ap- plications where weights and reduced dimensions play an important role. CIS/CIGS/CIGSS modules are part of a technology which is still under study and being developed. Silicon is replaced with special alloys such as: • copper, indium and selenite (CIS); Table 1.1 • copper, indium, gallium and selenite (CIGS); Single crystalline Polycrystalline Thin film • copper, indium, gallium, selenite and sulphur (CIGSS). silicon silicon (amorphous Nowadays the efficiency is 10 to 11% and the perform- silicon) 14% - 17% 12% - 14% 4-6% single ances remain constant in time; as for single crystalline and η cell 7-10% tandem polycrystalline silicon a reduction in the production cost high η lower cost lower cost is foreseen, for the time being around 2.2-2.5 €/W. constant η simpler production reduced influence of the temperature Advantages The market share of thin film technologies is still very lim- reliable optimum overall higher energy technology dimensions output with ited (≈7%), but the solutions with the highest capacities in diffused radiation the medium-long term are being taken into consideration higher energy sensitivity to bigger dimensions for a substantial price reduction. By depositing the thin impurities in the Disadvantages quantity necessary manufacturing cost of the for production structure and film directly on a large scale, more than 5 m2, the scraps, processes assembly time which are typical of the slicing operation to get crystal- line silicon wafers from the initial ingot, are avoided. The deposition techniques are low power consumption Table 1.2 processes and consequently the relevant payback time is short, that is only the time for which a PV plant shall GaAs (Gallum CdTe CIS (Copper Arsenide) (Cadmium Iridium Selenide be running before the power used to build it has been Telluride) alloys) generated (about 1 year for amorphous silicon thin films η cell 32,5% 11% 12% against the 2 years of crystalline silicon). In comparison high resistance at with crystalline silicon modules thin film modules show Advantages high temperatures low cost very constant (ok for concentrators) a lower dependence of efficiency on the operating tem- toxicity toxicity perature and a good response also when the diffused Disadvantages toxicity availability of the availability of materials the materials 5 According to some studies in this field, by 2020 the market share of thin films may reach 30% to 40%. 14 Photovoltaic plants
  • 11. 1.5 Typologies of photovoltaic plants Figure 1.20 – Photovoltaic shelters and street lamps supplied by photo- voltaic power 1 Generalities on photovoltaic (PV) plants 1.5.1 Stand-alone plants Stand-alone plants are plants which are not connected to the grid and consist of PV panels and of a storage system which guarantees electric energy supply also when light- ing is poor or when it is dark. Since the current delivered by the PV generator is DC power, if the user plant needs AC current an inverter becomes necessary. Such plants are advantageous from a technical and fi- nancial point of view whenever the electric network is not present or whenever it is not easy to reach, since they can replace motor generator sets. Besides, in a stand-alone configuration, the PV field is over-dimensioned so that, during the insolation hours, both the load supply as well as the recharge of the storing batteries can be guaranteed with a certain safety margin taking into account the days of poor insolation. At present the most common applications are used to supply (Figure 1.20): • pumping water equipment; • radio repeaters, weather or seismic observation and data transmission stations; • lightning systems; • systems of signs for roads, harbors and airports; • service supply in campers; • advertising installations; • refuges at high altitudes. Figure 1.21 shows the principle diagram of a stand-alone PV plant. Figure 1.21 5 7 3 6 2 4 1 PV generator 5 Possible DC loads 2 Switchboards on DC side 6 DC/AC static converter (inverter) 1 3 Load regulator 7 AC loads 4 Storage system (battery) DC connections AC connections Photovoltaic plants 15
  • 12. Technical Application Papers 1.5.2 Grid-connected plants Figure 1.23 Permanently grid-connected plants draw power from 1 Generalities on photovoltaic (PV) plants the grid during the hours when the PV generator cannot LV grid produce the energy necessary to satisfy the needs of the Power from consumer. On the contrary, if the PV system produces the grid excess electric power, the surplus is put into the grid, Power to the which therefore can operate as a big accumulator: as a grid consequence, grid-connected systems don’t need ac- cumulator banks (Figure 1.22). These plants (Figure 1.23) offer the advantage of dis- Inverter tributed - instead of centralized – generation: in fact Figure 1.22 the energy produced near the consumption area has a value higher than that produced in traditional large power plants, because the transmission losses are limited and the expenses of the big transport and dispatch electric systems are reduced. In addition, the energy produc- tion in the insolation hours allows the requirements for the grid to be reduced during the day, that is when the demand is higher. Figure 1.24 shows the principle diagram of a grid-con- nected photovoltaic plant. Figure 1.24 5 4 3 2 1 PV generator 2 Switchboards on DC side 1 3 DC/AC static converter (inverter) 4 Switchboard on AC side DC connections 5 Distributor network AC connections 16 Photovoltaic plants
  • 13. 1.6 Intermittence of generation and storage of batteries and the hydrogen one. At the state of the art the produced power 1 Generalities on photovoltaic (PV) plants of these two technologies, the electrochemical storage seems feasible, in the short-medium term, to store the The PV utilization on a large scale is affected by a techni- energy for some hours to some days. Therefore, in rela- cal limit due to the uncertain intermittency of production. tion to photovoltaics applied to small grid-connected In fact, the national electrical distribution network can plants, the insertion of a storage sub-system consist- accept a limited quantity of intermittent input power, after ing in batteries of small dimensions may improve the which serious problems for the stability of the network situation of the inconveniences due to intermittency, can rise. The acceptance limit depends on the network thus allowing a partial overcoming of the acceptance configuration and on the degree of interconnection with limit of the network. As regards the seasonal storage of the contiguous grids. the huge quantity of electric power required to replace In particular, in the Italian situation, it is considered dan- petroleum in all the usage sectors, hydrogen seems to gerous when the total intermittent power introduced into be the most suitable technology for the long term since the network exceeds a value from 10% to 20% of the total it takes advantage of the fact that solar electric produc- power of the traditional power generation plants. tivity in summer is higher than the winter productivity of As a consequence, the presence of a constraint due to about a factor 3. The exceeding energy stored in summer the intermittency of power generation restricts the real could be used to optimize the annual capacity factor of possibility of giving a significant PV contribution to the renewable source power plants, increasing it from the national energy balance and this remark can be extended present value of 1500-1600 hours without storage to a to all intermittent renewable sources. value nearer to the average one of the conventional power To get round this negative aspect it would be necessary plants (about 6000 hours). In this case the power from to store for sufficiently long times the intermittent electric renewable source could replace the thermoelectric one power thus produced to put it into the network in a more in its role, since the acceptance limit of the grid would continuous and stable form. Electric power can be stored be removed. either in big superconducting coils or converting it into other form of energy: kinetic energy stored in flywheels or compressed gases, gravitational energy in water basins, chemical energy in synthesis fuels and electrochemical energy in electric accumulators (batteries). Through a technical selection of these options according to the requirement of maintaining energy efficiently for days and/or months, two storage systems emerge: that using Photovoltaic plants 17