SlideShare ist ein Scribd-Unternehmen logo
1 von 4
BIG AND SMALL – COVALENT MOLECULES

When 2 or moreatoms are covalently bonded to form molecules, they move as one and the
molecule is considered one unit all by itself.

The energy of a typical single covalent bond is ~80 kilocalories per mole (kcal/mol).
However, this bond energy can vary from ~50 kcal/mol to ~110 kcal/mol depending on the
elements involved. Once formed, covalent bonds rarely break spontaneously.

This is due to simple energetic considerations; the thermal energy of a molecule at room
temperature (298 K) is only ~0.6 kcal/mol, much lower than the energy required to break a
covalent bond.

Molecules come in different sizes depending on the extensiveness of the number of covalent
bonds formed per atom. A molecule formed completely of carbon would have a very large
size, while that formed of hydrogen and oxygen has a formula of just H2O.

                                 The smallest level is the diatomic molecule which is the
                                 elemental form of group 7 atoms as they just need to form
                                 just one covalent bond to attain octet electronic
                                 configuration.



                               Very large molecules are called macro-molecules and they
can contain over 1000 atoms and more.




Look at how many water molecules can fit in the space of ONE diamond molecule.

There is very little intermolecular forces for diamond or for the sand on the seashore, because
one molecule is so big… but it is very significant for simple covalent compounds! 



Temporary dipoles

                      An molecule has an electron cloud combining the electrons from the
                      atoms that make up the molecule



                       As electrons are very mobile, the majority of them may move to one
end of the cloud at an instant, and cause a temporary negative charge to form at that end.
While at the other end which has very few electrons, a slightly positive charge will be the
result.

This is very temporary and electrons move very very fast and… the polarity may be reversed
very quickly



            The uneven distribution of electrons can occur in atoms of noble gases even, such
            as helium!


Because the end are slightly charged, consider what happens here



The positive end repels electrons from a nearby molecule to the opposite end and induces a
temporary dipole to form on it!




And even if the electrons move to the other end, the attraction is still maintained!



And this doesn’t just occur between 2 molecules, remember the image of water molecules all
bunched up earlier?




A large number of molecules can be held together by intermolecular forces 

Molecular size and strength of van der waal forces

Let us look at the boiling point of the noble gases

helium           -269°C
neon             -246°C
argon            -186°C
krypton          -152°C
xenon            -108°C
radon            -62°C
boiling point increase  means stronger intermolecular attraction down group

strong intermolecular forces  because down the group, the number of electrons increase,
and the size of the atom becomes bigger.

                                More electrons  means that the temporary dipoles are
                                stronger

                                Larger size of atom  more surface area to interact with other
                                molecules



Melting and boiling points

Melting and boiling points represent the temperature at which a change of state occurs.




Heat, once absorbed as energy, contributes to the overall internal energy of the object. One
form of this internal energy is kinetic energy; the particles begin to move faster, resulting in a
greater kinetic energy.

This more vigorous motion of particles is reflected by a temperature increase. The reverse
logic applies as well. Energy, once released as heat, results in a decrease in the overall
internal energy of the object.

1) At temperatures lower than its melting point if a solid is heated, its KE increases
2) Just at the melting point, heat supplied is used to overcome the attractive forces between
particles, therefore temperature remains the same.
3) After melting is completed, the additional heat increases the KE of the particles.
From the graph above, explain what the state of matter which the compound being heated is
in between time D and E.

It is in both liquid and gaseous phase
It is only after point E that all of the compound has been converted to gaseous state

Flat line indicate that temperature is constant
As the compound is melting between point D and E. energy supplied is used to break bonds
only




Additional stuff

The big energy change when water freezes is in the potential energy of
interactions between the water molecules. In the ice, the molecules arrange to
touch in a way that lowers this energy. In the liquid, the arrangement is less
regular and the energy is not lowered as much.

Freezing is a change in the ordering, or structure of the molecules. An ice crystal
has less spatial symmetry (specific crystal axes are defined in space) than water
(every direction is as good as every other direction). There is an energy
associated with this transition -- 80 calories per gram of ice are needed to melt
ice at 0C at ordinary pressure, and 80 calories per gram of water are given off
during the freezing process.

http://van.physics.illinois.edu/qa/listing.php?id=1730

Weitere ähnliche Inhalte

Was ist angesagt?

Power Point Solids & Liquids
Power Point   Solids & LiquidsPower Point   Solids & Liquids
Power Point Solids & Liquids
gabelpam
 
Biochem 1: Properties of Water
Biochem 1: Properties of WaterBiochem 1: Properties of Water
Biochem 1: Properties of Water
tbowde1
 
Atomic combinations
Atomic combinationsAtomic combinations
Atomic combinations
Siyavula
 
Properties of water
Properties of waterProperties of water
Properties of water
Leigh Aaron
 
01 intermolecular forces
01 intermolecular forces01 intermolecular forces
01 intermolecular forces
zehnerm2
 
AP Chemistry Chapter 12 Outline
AP Chemistry Chapter 12 OutlineAP Chemistry Chapter 12 Outline
AP Chemistry Chapter 12 Outline
Jane Hamze
 
intermolecular forces
intermolecular forcesintermolecular forces
intermolecular forces
vxiiayah
 
Intermolecular Forces
Intermolecular ForcesIntermolecular Forces
Intermolecular Forces
glenn adams
 
Water’s life supporting properties
Water’s life supporting propertiesWater’s life supporting properties
Water’s life supporting properties
Sofía Paz Mogro
 

Was ist angesagt? (20)

Molecular structure, properties and state of matter
Molecular structure, properties and state of matterMolecular structure, properties and state of matter
Molecular structure, properties and state of matter
 
Power Point Solids & Liquids
Power Point   Solids & LiquidsPower Point   Solids & Liquids
Power Point Solids & Liquids
 
Biochem 1: Properties of Water
Biochem 1: Properties of WaterBiochem 1: Properties of Water
Biochem 1: Properties of Water
 
Kmt, intermolecular forces, intro energy
Kmt, intermolecular forces, intro energyKmt, intermolecular forces, intro energy
Kmt, intermolecular forces, intro energy
 
General Chemistry 2 - Chapter 1: The Kinetic Molecular Model and Intermolecul...
General Chemistry 2 - Chapter 1: The Kinetic Molecular Model and Intermolecul...General Chemistry 2 - Chapter 1: The Kinetic Molecular Model and Intermolecul...
General Chemistry 2 - Chapter 1: The Kinetic Molecular Model and Intermolecul...
 
Chapter 11 Lecture- Intermolecular Forces, Liquids, & Solids
Chapter 11 Lecture- Intermolecular Forces, Liquids, & SolidsChapter 11 Lecture- Intermolecular Forces, Liquids, & Solids
Chapter 11 Lecture- Intermolecular Forces, Liquids, & Solids
 
Vander waals forces and its significance
Vander waals forces and its significanceVander waals forces and its significance
Vander waals forces and its significance
 
Ch11 outline
Ch11 outlineCh11 outline
Ch11 outline
 
Atomic combinations
Atomic combinationsAtomic combinations
Atomic combinations
 
Properties of water
Properties of waterProperties of water
Properties of water
 
01 intermolecular forces
01 intermolecular forces01 intermolecular forces
01 intermolecular forces
 
AP Chemistry Chapter 12 Outline
AP Chemistry Chapter 12 OutlineAP Chemistry Chapter 12 Outline
AP Chemistry Chapter 12 Outline
 
Tang 09 intermolecular forces and solubility
Tang 09   intermolecular forces and solubilityTang 09   intermolecular forces and solubility
Tang 09 intermolecular forces and solubility
 
intermolecular forces
intermolecular forcesintermolecular forces
intermolecular forces
 
hydrogen bond by KK Sahu sir
hydrogen bond by KK Sahu sirhydrogen bond by KK Sahu sir
hydrogen bond by KK Sahu sir
 
Intermolecular Forces
Intermolecular ForcesIntermolecular Forces
Intermolecular Forces
 
Molecular Polarity and Dipole-Dipole Forces
Molecular Polarity and Dipole-Dipole ForcesMolecular Polarity and Dipole-Dipole Forces
Molecular Polarity and Dipole-Dipole Forces
 
Binding forces SB
Binding forces SBBinding forces SB
Binding forces SB
 
Water’s life supporting properties
Water’s life supporting propertiesWater’s life supporting properties
Water’s life supporting properties
 
Intermolecular Forces in Hydrogen Bonding - Pooja N
Intermolecular Forces in Hydrogen Bonding - Pooja NIntermolecular Forces in Hydrogen Bonding - Pooja N
Intermolecular Forces in Hydrogen Bonding - Pooja N
 

Ähnlich wie Intermolecular forces of attraction

Intermolecular attractions are attractions betwee.pdf
                     Intermolecular attractions are attractions betwee.pdf                     Intermolecular attractions are attractions betwee.pdf
Intermolecular attractions are attractions betwee.pdf
annaelctronics
 
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
Rai University
 
Structure of matter (STAR review)
Structure of matter (STAR review)Structure of matter (STAR review)
Structure of matter (STAR review)
MrsKendall
 
Chapters 2&3
Chapters 2&3Chapters 2&3
Chapters 2&3
ktanaka2
 
Types of bonding in solids
Types of bonding in solidsTypes of bonding in solids
Types of bonding in solids
Mandar Jagtap
 
Describe the intramecular and intermolecular forces of water mole.pdf
Describe the intramecular and intermolecular forces of water mole.pdfDescribe the intramecular and intermolecular forces of water mole.pdf
Describe the intramecular and intermolecular forces of water mole.pdf
arihanthtoysandgifts
 
Investigation Of The Thermal Decomposition Of Copper...
 Investigation Of The Thermal Decomposition Of Copper... Investigation Of The Thermal Decomposition Of Copper...
Investigation Of The Thermal Decomposition Of Copper...
Alexis Naranjo
 

Ähnlich wie Intermolecular forces of attraction (20)

Intermolecular attractions are attractions betwee.pdf
                     Intermolecular attractions are attractions betwee.pdf                     Intermolecular attractions are attractions betwee.pdf
Intermolecular attractions are attractions betwee.pdf
 
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
B.sc(microbiology, biotechnology and biochemistry) ii inorganic chemistry uni...
 
Applied science./cosmetic dentistry course by Indian dental academy
Applied science./cosmetic dentistry course by Indian dental academyApplied science./cosmetic dentistry course by Indian dental academy
Applied science./cosmetic dentistry course by Indian dental academy
 
Structure of matter/cosmetic dentistry course by Indian dental academy
Structure of matter/cosmetic dentistry course by Indian dental academyStructure of matter/cosmetic dentistry course by Indian dental academy
Structure of matter/cosmetic dentistry course by Indian dental academy
 
Thermal 3.1
Thermal 3.1Thermal 3.1
Thermal 3.1
 
Thermal 3.1
Thermal 3.1Thermal 3.1
Thermal 3.1
 
Structure of matter (STAR review)
Structure of matter (STAR review)Structure of matter (STAR review)
Structure of matter (STAR review)
 
Structure of matter/certified fixed orthodontic courses by Indian dental acad...
Structure of matter/certified fixed orthodontic courses by Indian dental acad...Structure of matter/certified fixed orthodontic courses by Indian dental acad...
Structure of matter/certified fixed orthodontic courses by Indian dental acad...
 
Chapters 2&3
Chapters 2&3Chapters 2&3
Chapters 2&3
 
Types of bonding in solids
Types of bonding in solidsTypes of bonding in solids
Types of bonding in solids
 
Describe the intramecular and intermolecular forces of water mole.pdf
Describe the intramecular and intermolecular forces of water mole.pdfDescribe the intramecular and intermolecular forces of water mole.pdf
Describe the intramecular and intermolecular forces of water mole.pdf
 
Chemical bonding by Saliha Rais
Chemical bonding by Saliha RaisChemical bonding by Saliha Rais
Chemical bonding by Saliha Rais
 
Formation of Light Elements.
Formation of Light Elements.Formation of Light Elements.
Formation of Light Elements.
 
Chemical bonding
Chemical bondingChemical bonding
Chemical bonding
 
State of matter
State of matterState of matter
State of matter
 
Grade 10 matter and materials
Grade 10 matter and materials Grade 10 matter and materials
Grade 10 matter and materials
 
Chapter 8 Covalent Bonds
Chapter 8 Covalent BondsChapter 8 Covalent Bonds
Chapter 8 Covalent Bonds
 
Investigation Of The Thermal Decomposition Of Copper...
 Investigation Of The Thermal Decomposition Of Copper... Investigation Of The Thermal Decomposition Of Copper...
Investigation Of The Thermal Decomposition Of Copper...
 
Chemistry
ChemistryChemistry
Chemistry
 
Advchemchapt10 101015122937-phpapp01
Advchemchapt10 101015122937-phpapp01Advchemchapt10 101015122937-phpapp01
Advchemchapt10 101015122937-phpapp01
 

Mehr von Gareth Ng

Atoms elements
Atoms elementsAtoms elements
Atoms elements
Gareth Ng
 
Velocity and acceleration big idea_student_copy
Velocity and acceleration big idea_student_copyVelocity and acceleration big idea_student_copy
Velocity and acceleration big idea_student_copy
Gareth Ng
 

Mehr von Gareth Ng (11)

refraction
refractionrefraction
refraction
 
Atoms elements
Atoms elementsAtoms elements
Atoms elements
 
Forces
ForcesForces
Forces
 
Velocity and acceleration big idea_student_copy
Velocity and acceleration big idea_student_copyVelocity and acceleration big idea_student_copy
Velocity and acceleration big idea_student_copy
 
Chem separation techniques
Chem separation techniquesChem separation techniques
Chem separation techniques
 
Separation techniques student_checklist
Separation techniques student_checklistSeparation techniques student_checklist
Separation techniques student_checklist
 
Acids and bases
Acids and basesAcids and bases
Acids and bases
 
Ions and bonding student copy
Ions and bonding student copyIons and bonding student copy
Ions and bonding student copy
 
Velocity and acceleration
Velocity and accelerationVelocity and acceleration
Velocity and acceleration
 
Chemical equations
Chemical equationsChemical equations
Chemical equations
 
Ions and bonding
Ions and bonding Ions and bonding
Ions and bonding
 

Kürzlich hochgeladen

Finding Java's Hidden Performance Traps @ DevoxxUK 2024
Finding Java's Hidden Performance Traps @ DevoxxUK 2024Finding Java's Hidden Performance Traps @ DevoxxUK 2024
Finding Java's Hidden Performance Traps @ DevoxxUK 2024
Victor Rentea
 
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers:  A Deep Dive into Serverless Spatial Data and FMECloud Frontiers:  A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Safe Software
 
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers:  A Deep Dive into Serverless Spatial Data and FMECloud Frontiers:  A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Safe Software
 

Kürzlich hochgeladen (20)

Apidays New York 2024 - The value of a flexible API Management solution for O...
Apidays New York 2024 - The value of a flexible API Management solution for O...Apidays New York 2024 - The value of a flexible API Management solution for O...
Apidays New York 2024 - The value of a flexible API Management solution for O...
 
MINDCTI Revenue Release Quarter One 2024
MINDCTI Revenue Release Quarter One 2024MINDCTI Revenue Release Quarter One 2024
MINDCTI Revenue Release Quarter One 2024
 
Finding Java's Hidden Performance Traps @ DevoxxUK 2024
Finding Java's Hidden Performance Traps @ DevoxxUK 2024Finding Java's Hidden Performance Traps @ DevoxxUK 2024
Finding Java's Hidden Performance Traps @ DevoxxUK 2024
 
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers:  A Deep Dive into Serverless Spatial Data and FMECloud Frontiers:  A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
 
Web Form Automation for Bonterra Impact Management (fka Social Solutions Apri...
Web Form Automation for Bonterra Impact Management (fka Social Solutions Apri...Web Form Automation for Bonterra Impact Management (fka Social Solutions Apri...
Web Form Automation for Bonterra Impact Management (fka Social Solutions Apri...
 
Navigating the Deluge_ Dubai Floods and the Resilience of Dubai International...
Navigating the Deluge_ Dubai Floods and the Resilience of Dubai International...Navigating the Deluge_ Dubai Floods and the Resilience of Dubai International...
Navigating the Deluge_ Dubai Floods and the Resilience of Dubai International...
 
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
 
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, AdobeApidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
 
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers:  A Deep Dive into Serverless Spatial Data and FMECloud Frontiers:  A Deep Dive into Serverless Spatial Data and FME
Cloud Frontiers: A Deep Dive into Serverless Spatial Data and FME
 
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot ModelMcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
 
Artificial Intelligence Chap.5 : Uncertainty
Artificial Intelligence Chap.5 : UncertaintyArtificial Intelligence Chap.5 : Uncertainty
Artificial Intelligence Chap.5 : Uncertainty
 
DBX First Quarter 2024 Investor Presentation
DBX First Quarter 2024 Investor PresentationDBX First Quarter 2024 Investor Presentation
DBX First Quarter 2024 Investor Presentation
 
Apidays New York 2024 - Accelerating FinTech Innovation by Vasa Krishnan, Fin...
Apidays New York 2024 - Accelerating FinTech Innovation by Vasa Krishnan, Fin...Apidays New York 2024 - Accelerating FinTech Innovation by Vasa Krishnan, Fin...
Apidays New York 2024 - Accelerating FinTech Innovation by Vasa Krishnan, Fin...
 
How to Troubleshoot Apps for the Modern Connected Worker
How to Troubleshoot Apps for the Modern Connected WorkerHow to Troubleshoot Apps for the Modern Connected Worker
How to Troubleshoot Apps for the Modern Connected Worker
 
Connector Corner: Accelerate revenue generation using UiPath API-centric busi...
Connector Corner: Accelerate revenue generation using UiPath API-centric busi...Connector Corner: Accelerate revenue generation using UiPath API-centric busi...
Connector Corner: Accelerate revenue generation using UiPath API-centric busi...
 
Strategies for Landing an Oracle DBA Job as a Fresher
Strategies for Landing an Oracle DBA Job as a FresherStrategies for Landing an Oracle DBA Job as a Fresher
Strategies for Landing an Oracle DBA Job as a Fresher
 
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemkeProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
 
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
 
Elevate Developer Efficiency & build GenAI Application with Amazon Q​
Elevate Developer Efficiency & build GenAI Application with Amazon Q​Elevate Developer Efficiency & build GenAI Application with Amazon Q​
Elevate Developer Efficiency & build GenAI Application with Amazon Q​
 
AWS Community Day CPH - Three problems of Terraform
AWS Community Day CPH - Three problems of TerraformAWS Community Day CPH - Three problems of Terraform
AWS Community Day CPH - Three problems of Terraform
 

Intermolecular forces of attraction

  • 1. BIG AND SMALL – COVALENT MOLECULES When 2 or moreatoms are covalently bonded to form molecules, they move as one and the molecule is considered one unit all by itself. The energy of a typical single covalent bond is ~80 kilocalories per mole (kcal/mol). However, this bond energy can vary from ~50 kcal/mol to ~110 kcal/mol depending on the elements involved. Once formed, covalent bonds rarely break spontaneously. This is due to simple energetic considerations; the thermal energy of a molecule at room temperature (298 K) is only ~0.6 kcal/mol, much lower than the energy required to break a covalent bond. Molecules come in different sizes depending on the extensiveness of the number of covalent bonds formed per atom. A molecule formed completely of carbon would have a very large size, while that formed of hydrogen and oxygen has a formula of just H2O. The smallest level is the diatomic molecule which is the elemental form of group 7 atoms as they just need to form just one covalent bond to attain octet electronic configuration. Very large molecules are called macro-molecules and they can contain over 1000 atoms and more. Look at how many water molecules can fit in the space of ONE diamond molecule. There is very little intermolecular forces for diamond or for the sand on the seashore, because one molecule is so big… but it is very significant for simple covalent compounds!  Temporary dipoles An molecule has an electron cloud combining the electrons from the atoms that make up the molecule As electrons are very mobile, the majority of them may move to one end of the cloud at an instant, and cause a temporary negative charge to form at that end.
  • 2. While at the other end which has very few electrons, a slightly positive charge will be the result. This is very temporary and electrons move very very fast and… the polarity may be reversed very quickly The uneven distribution of electrons can occur in atoms of noble gases even, such as helium! Because the end are slightly charged, consider what happens here The positive end repels electrons from a nearby molecule to the opposite end and induces a temporary dipole to form on it! And even if the electrons move to the other end, the attraction is still maintained! And this doesn’t just occur between 2 molecules, remember the image of water molecules all bunched up earlier? A large number of molecules can be held together by intermolecular forces  Molecular size and strength of van der waal forces Let us look at the boiling point of the noble gases helium -269°C neon -246°C argon -186°C krypton -152°C xenon -108°C radon -62°C
  • 3. boiling point increase  means stronger intermolecular attraction down group strong intermolecular forces  because down the group, the number of electrons increase, and the size of the atom becomes bigger. More electrons  means that the temporary dipoles are stronger Larger size of atom  more surface area to interact with other molecules Melting and boiling points Melting and boiling points represent the temperature at which a change of state occurs. Heat, once absorbed as energy, contributes to the overall internal energy of the object. One form of this internal energy is kinetic energy; the particles begin to move faster, resulting in a greater kinetic energy. This more vigorous motion of particles is reflected by a temperature increase. The reverse logic applies as well. Energy, once released as heat, results in a decrease in the overall internal energy of the object. 1) At temperatures lower than its melting point if a solid is heated, its KE increases 2) Just at the melting point, heat supplied is used to overcome the attractive forces between particles, therefore temperature remains the same. 3) After melting is completed, the additional heat increases the KE of the particles.
  • 4. From the graph above, explain what the state of matter which the compound being heated is in between time D and E. It is in both liquid and gaseous phase It is only after point E that all of the compound has been converted to gaseous state Flat line indicate that temperature is constant As the compound is melting between point D and E. energy supplied is used to break bonds only Additional stuff The big energy change when water freezes is in the potential energy of interactions between the water molecules. In the ice, the molecules arrange to touch in a way that lowers this energy. In the liquid, the arrangement is less regular and the energy is not lowered as much. Freezing is a change in the ordering, or structure of the molecules. An ice crystal has less spatial symmetry (specific crystal axes are defined in space) than water (every direction is as good as every other direction). There is an energy associated with this transition -- 80 calories per gram of ice are needed to melt ice at 0C at ordinary pressure, and 80 calories per gram of water are given off during the freezing process. http://van.physics.illinois.edu/qa/listing.php?id=1730