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Biodiesel Use, Handling,
                                           and Fuel Quality
   A Publication of ATTRA - National Sustainable Agriculture Information Service • 1-800-346-9140 • www.attra.ncat.org

By Andrew Pressman                         This publication addresses questions that farmers and ranchers may have about using biodiesel in diesel
and Mike Morris                            engines. Biodiesel can be substituted for petroleum-based diesel fuel in virtually any standard unmodi-
NCAT Energy                                fied diesel engine. However, biodiesel has chemical properties that require somewhat different use and
Specialists                                handling. While most biodiesel users experience few if any problems, consumers can take precautions
September 2007                             to avoid potential problems associated with poor quality fuel.
© 2007 NCAT




Contents
Introduction .................... 1
Biodiesel, Ethanol,
Vegetable Oil: What’s
the Difference? ............... 2
Blending and
Storage .............................. 3
Issues and Concerns ..... 4




                                                                                                                                                Photos: Vern Grubinger
ASTM Standards ............. 6
The BQ-9000
Program ............................. 7
Warranty Issues .............. 8
Fuel Quality Testing ..... 9
Conclusion ....................... 9
References ...................... 10
                                           Introduction                                              • It functions as an excellent fuel
                                                                                                       lubricant and performs similarly
                                           Biodiesel is becoming widely available in                   to low-sulfur diesel with regards to
                                           most parts of the U.S. and can be substi-                   power, torque, and fuel consumption.
                                           tuted for petroleum-based diesel fuel (“pet-
                                           rodiesel”) in virtually any standard unmod-               • It can greatly reduce carbon emissions.
                                           ified diesel engine. Biodiesel offers many            For discussion of the environmental advan-
Funding for the development
                                           advantages over petroleum-based diesel:              tages of biodiesel, see the ATTRA publica-
of this publication was provided                                                                tion Biodiesel: the Sustainability Dimensions.
by the USDA Risk Management                     • It is made from domestically
Agency.
                                                  produced and renewable agricul-               To find retail biodiesel distributors in your
                                                  tural products, mainly vegetable oil          area, use NCAT’s Farm Energy Search Tool,
                                                  or animal fat.                                www.attra.ncat.org/farmenergysearchtool.
ATTRA—National Sustainable                                                                      Most biodiesel users pour it in the tank and
Agriculture Information Ser-                    • It is essentially non-toxic and bio-
vice is managed by the National
                                                  degradable.                                   experience few if any problems. Nonethe-
Center for Appropriate Technol-
ogy (NCAT) and is funded under
                                                                                                less, biodiesel has chemical properties that
a grant from the United States                  • It has a high flash point (over 300ºF)         can cause difficulties. For example:
Department of Agriculture’s
                                                  and is difficult to light on fi re with
Rural Business- Cooperative                                                                          • Biodiesel’s detergent or solvent
Service. Visit the NCAT Web site                  a match.
(www.ncat.org/agri.                                                                                    properties can clog your fuel fi lter
html) for more informa-
tion on our sustainable
                                                • It reduces emissions of many toxic                   as it cleans carbon deposits from
agriculture projects.                             air pollutants.                                      your engine.
• Compared to petrodiesel, biodie-             any plant oil or animal fat. Making biodie-
                                                   sel has somewhat worse cold-flow              sel is a chemical process. During this chem-
                                                   properties.                                  ical reaction, a thick gooey substance, glyc-
                                                 • Biodiesel degrades rubber and cer-           erin, is released from the oil molecules and
                                                   tain other materials, making it incom-       replaced with a comparatively thin and light
                                                   patible with some fuel lines, rubber         alcohol, usually methanol. For an expla-
                                                   gaskets, and other engine parts.             nation of how to make biodiesel, see the
                                            This article offers suggestions to help farm-       ATTRA publication Biodiesel: a Primer.
                                            ers and other consumers get the benefits of          Biodiesel is also very different from raw or
                                            biodiesel while avoiding performance and            “straight” vegetable oil (SVO). Almost any
                                            equipment problems.                                 vegetable oil will combust, to one degree or
                                                                                                another, in a diesel engine. So it’s possible
                                             Caution: If you are making your own fuel,          to run most diesel engines on SVO. But this
                                             using and storing large quantities of biodiesel,   is a somewhat risky process, mainly since
                                             or selling fuel commercially, you will need to     raw vegetable oil is too thick and viscous to
                                             take many safety, legal, and quality-related
                                             precautions beyond the ones described here.
                                                                                                run well in diesel engines.
                                                                                                Biodiesel will perform well in almost any
                                                                                                standard diesel engine without modifica-
                                            Biodiesel, Ethanol, Vegetable                       tions. On the other hand, to use SVO you
                                            Oil: What’s the Difference?                          will need to modify your engine. Conver-
                                                                                                sion kits are readily available for $300 to
                                            Biodiesel is a very different substance from
                                                                                                $1,500.(1) Generally, conversion means
                                            ethanol. Ethanol (or grain alcohol), the
                                                                                                installing a separate fuel tank, heater, and
Photo: www.biodieselcommunity.org




                                            familiar alcohol found in alcoholic bever-
                                                                                                fuel line, along with various switches and
                                            ages, is commonly blended with gasoline
                                                                                                controls. The idea is to thin the oil by heat-
                                            (not diesel fuel) and is made by fermenting
                                                                                                ing it, while taking precautions to keep cold,
                                            grains or other plants that contain sugar.
                                                                                                gooey vegetable oil out of your engine. You
                                            Fermentation is a biological process accom-
                                                                                                start and run the engine on standard diesel
                                            plished by yeasts and bacteria.
                                                                                                fuel or biodiesel. Once the engine is warm
                                            Biodiesel is essentially permanently thinned        and you’ve pre-heated the vegetable oil—
                                            plant or animal-based oil, with a viscosity         stored in a separate tank—you can switch to
                                            approximating that of standard #2 diesel            SVO. Several minutes before turning off the
                                            fuel. Biodiesel can be made from virtually          engine, you switch back to standard diesel
                                                                                                fuel or biodiesel, clearing all the SVO out of
                                                                                                your engine and fuel lines.
                                                                                                The U.S. Department of Energy, among
                                                                                                many other organizations, cautions that
                                                                                                SVO can reduce engine life and should not
                                                                                                be considered a fuel for long-term use.(2)
                                                                                                The use of SVO has been shown to cause
                                                                                                piston ring sticking, injector and combus-
                                                                                                tion chamber deposits, fuel system deposits,
                                                                                                reduced power, reduced fuel economy, and
                                                                                                increased exhaust emissions. Any of these
         Photo: Vern Grubinger




                                                                                                conditions can reduce engine life, increase
                                                                                                maintenance costs, or cause engine failure.
                                                                                                Modern diesel engines are also equipped
                                                                                                with catalytic converters, or fi lter traps, that
                                                                                                are not designed to handle SVO.
Page 2                              ATTRA                                                           Biodiesel Use, Handling, and Fuel Quality
Performance problems don’t necessarily           You should avoid adding biodiesel to cold
happen quickly. Certain engines seem to          petrodiesel, since this may cause crystals
tolerate SVO better than others, and some        to form. To prevent this from happening,
vehicles run trouble-free for years. On the      you can blend biodiesel with kerosene (also
other hand, many SVO users succeed ini-          called #1 diesel fuel) in a 50/50 mix before
tially, and are lulled into a false sense of     adding it to cold diesel fuel.(5) If crystals
security, only to run into serious problems      have already formed, the fuel will have to
later.(3)                                        be heated until they dissolve.
Despite the very real risk of engine dam-
age, SVO has certain advantages that may         Biodiesel Storage
make it worth considering for some farm-         Biodiesel can be stored in standard petroleum
ing situations and equipment, especially in      diesel storage tanks with some precautions:
older engines. Using SVO is in some ways             • Tanks that have previously been
simpler than making your own biodiesel.                used to store diesel fuel should be
Making biodiesel generally requires you                cleaned before use. As noted below,
to use methanol, a toxic chemical, and to              biodiesel is an excellent solvent and
dispose of glycerin, a waste product. By               will loosen deposits left by standard
contrast, SVO is generally only filtered               diesel fuel. Tanks should also be
before use, and there are few if any waste             free of water, since this encourages
products to deal with.                                 bacterial growth.
                                                     • Tanks may be made of aluminum,
Biodiesel Blends and                                   steel, Teflon, or fluorinated poly-
Blending                                               ethylene or polypropylene. Fiber-
                                                       glass is sometimes used, but should
Biodiesel in its pure (100 percent) form is
                                                       be approached with caution since
known as neat biodiesel or B100. It can be
                                                       some resins are not compatible with
readily blended with petroleum diesel in
                                                       biodiesel.(4)
any proportion. A B20 blend, for example,
is 20 percent by volume biodiesel and 80
percent petrodiesel.
Different blends serve different purposes.
Small amounts of biodiesel (B1-B2) add
                                                                                                 Photos: Vern Grubinger
lubrication to low-sulfur fuels. Blends in the
B20 to B50 range provide significant envi-
ronmental benefits with a low increase in
cost to consumers. Blending also reduces
the likelihood of the solvency, material
incompatibility, or cold weather problems
discussed below.
The simplest method is splash blending.
Biodiesel should always be poured on top
of petroleum diesel, since it is slightly
heavier. The two fuels will mix fairly well
as the biodiesel gradually sinks through
the lighter petrodiesel. Some form of agi-
tation is needed, though, to achieve highly
uniform fuel. Random samples of splash-
blended fuel being marketed as B20 have
been found to contain actual biodiesel
content ranging from B2 to B90.(4)
www.attra.ncat.org                                                                               ATTRA                    Page 3
• Both petrodiesel and biodiesel can           fuel tank before converting to biodiesel. An
                              cause metal parts to oxidize, so you         alternative is to switch to finer fi lters. Any-
                              should replace any parts made of             one using B100 should know how to change
                              brass, bronze, copper, lead, tin, or         the fuel fi lter and should carry a spare fuel
                              zinc with aluminum or steel.                 fi lter or two. Expect to change your fuel fi l-
                            • If biodiesel or blended fuels are            ter two or three times before all the deposits
                              stored beyond around six months,             are cleaned out of your engine. If you are
                              fuel stabilizers should be added.(6)         using a modest blend (B20 or lower), you
                              Old fuel will become acidic and              are less likely to notice fi lter clogging.
                              form sediments and varnish.
                            • Biodiesel and biodiesel blends               Issue #2: Reduced Power
                              should be stored at temperatures             On average, B100 has about eight per-
                              at least 15 degrees above the pour           cent less energy content (BTU per gallon)
                              point of the fuels.(7) The pour point        than #2 petrodiesel, while B20 has one to
                              is the temperature below which a             two percent less energy content.(8) If you
                              fuel will not pour.                          switch from standard diesel fuel to B100,



A
                                                                           you may notice a slight decrease in horse-
          nyone using       • Outdoor tanks should be located in
                                                                           power, torque, or fuel economy. At B20 or
          B100 should         cool shaded areas if possible.
                                                                           less, you probably won’t be able to tell the
          know how                                                         difference.
to change the fuel       Caution: If you are storing large amounts of
                         fuel, or selling it commercially, you will need   A cetane number is an indicator of diesel fuel
filter and should         to take many additional precautions and meet      quality, measuring the readiness of fuel to
carry a spare fuel       local laws and code requirements.                 ignite when injected into the engine. Biodie-
filter or two.                                                              sel’s cetane number is higher than that of
                                                                           standard diesel fuel, and this advantage may
                                                                           partly compensate for its lower BTU content.
                        Issue #1: Solvent Effects                           Because biodiesel ignites more readily in
                        and Filter Clogging                                diesel engines than petrodiesel, some author-
                                                                           ities recommend setting the injection timing
                        According to researchers at the University
                                                                           back by two to three degrees from top-dead
                        of Idaho, filter plugging is the most common
                                                                           center. This will sometimes cause the engine
                        problem experienced by biodiesel users.(4)
                                                                           to run quieter, although it may also slightly
                        Biodiesel has excellent solvent properties         reduce your power.(9)
                        and can be used as a cleaning agent and
                        paint remover. (It can remove the paint on         Issue #3: Cold Weather
                        the side of your car or tractor, if you splash
                        it around while fi lling the tank.) In fact, it
                                                                           Performance
                        can even dissolve concrete.(4)                     All diesel fuel, including petroleum-based
                                                                           fuel, begins to gel at cold temperatures.
                        Petroleum diesel often leaves a deposit in         The temperature at which a cloud of wax
                        the bottom of fuel lines, tanks, and deliv-        crystals forms in the fuel is known as the
                        ery systems. Biodiesel can loosen and dis-         cloud point. The cold filter plugging point
                        solve these sediments, as well as rust and         is the lowest temperature at which fuel can
                        other materials. This causes fuel fi lters to       be drawn through a metal screen fi lter.(10)
                        become clogged—sometimes in a matter of            The pour point is the temperature below
                        hours after switching to B100. Symptoms of         which a fuel will not pour.
                        fi lter clogging include a sudden power loss
                                                                           In general, biodiesel gels at somewhat higher
                        or engine shuddering.
                                                                           temperatures than conventional #2 diesel.
                        Older vehicles have more accumulated               When wax crystals begin to form in biodie-
                        deposits, and are especially prone to fi lter       sel, the entire fuel tends to cloud at the same
                        clogging. Ideally, you should clean an old         time. In contrast, petroleum diesel is made
Page 4      ATTRA                                                              Biodiesel Use, Handling, and Fuel Quality
up of many different compounds that gel at          since they will work on the petroleum-based
different temperatures. When some of these          portion of the fuel.
begin to crystallize, others remain liquid to a
much lower temperature.                             Issue #4: Softening Fuel Lines
The cloud point for standard #2 diesel fuel         Using a high-percentage biodiesel blend or
is around 5ºF. The cloud point for biodiesel        B100 can cause certain types of elastomers
depends on the feedstock and the amount             and natural rubber compounds to bubble,
of free fatty acids in the fuel. The cloud          bleed, soften, and degrade over time. Virtu-
point for soy diesel is around 32ºF (4),            ally all diesel vehicles made since the early
compared to cloud points around 20ºF for            1990s use components that are compatible
canola and 12ºF for rapeseed.(11) Biodie-           with B100.(4) But some older fuel hoses will
sel made from used cooking grease or ani-           need to be replaced.
mal fats will tend to cloud at higher tem-
peratures than biodiesel made from virgin           Equipment changes are rarely if ever
oils. Biodiesel from the most highly satu-          necessary with blends of B20 or lower.(8)
rated feedstocks may gel at temperatures as         Besides rubber, other vulnerable materials
high as 50-55ºF.                                    identified by the National Biodiesel Board
Low-percentage biodiesel blends generally           include polypropylene, polyvinyl, and Tygon.
have cold weather properties similar to pet-        Although there have been a few reports of
rodiesel. The cloud point of B20 may be             degraded injection pump seals, by far the most
3º-10ºF higher than #2 petrodiesel.(8)              common problem you are likely to encounter
                                                    is with rubber fuel lines. If you have an older
Simple cold weather precautions include             vehicle, you should inspect your fuel lines
using engine block or fuel filter heaters           frequently after you begin using biodiesel.
and parking vehicles in or near a build-
ing. Fuel additives can also inhibit crystal        The good news is that these problems are
growth and gelling in standard diesel fuel.         likely to appear gradually, if they appear
Anecdotal reports suggest that few if any           at all. Hoses will begin to soften and (even-
of these products work well on B100. They           tually) weep. You are unlikely to experience
may be effective on blended fuel, however,          a catastrophic failure.


  Case Study:                                vehicles, gradually expanding his usage   seemed as if he needed to change fil-
  Phil Foster Ranches                        as he became comfortable with the         ters more often than normal. “Maybe
                                             fuel’s performance. He also asked his     the fuel was a tad off ... We’ll probably
  Phil Foster began using biodiesel on his
                                             supplier lots of questions about test-    never know for sure.”
  organic vegetable farm near San Juan
                                             ing, standards, and feedstocks.
  Bautista, California in 2004. He saw the                                             Fuel economy may have decreased
  use of non-petroleum fuels as consis-      By 2006, biodiesel made up 81 percent     slightly, in the range of three to five
  tent with his philosophy as an organic     of the roughly 20,000 gallons of diesel   percent. There have also been a few
  vegetable farmer. He liked the idea that   fuel consumed annually by the farm’s      cold mornings (18º - 20 ºF) when the
  any fuel spills would be biodegradable     tractors, pickups, and delivery trucks.
                                                                                       vehicles running on B100 would not
  and far less toxic than standard diesel.   Most of the farm’s diesel vehicles are
                                                                                       start. Switching temporarily to B30 dur-
  He was attracted by the air quality        now running B100, although with some
                                                                                       ing cold weather has solved this prob-
  and health advantages for his family       of his older equipment Phil has been
  and his workers. And he liked the idea     reluctant to go above B30.                lem, and all vehicles have started fine
  of purchasing fuel made from agricul-                                                on B30.
                                             Overall, Phil comments that “After four
  tural products, preferably ones grown                                                Phil recently bought a new truck, which
                                             years of using biodiesel, we’ve had
  locally or regionally.                                                               he plans to run on B30 for the first six to
                                             very good results.” He did experience
  Phil didn’t have the time or inclination   some filter plugging when switching        twelve months - enough time for any
  to make his own fuel, so he began pur-     to biodiesel, and he now changes his      problems to show up. Once he’s confi-
  chasing biodiesel from a local retailer.   filters at every service. He also went     dent in the vehicle’s performance, he’ll
  Initially, he tried B100 in some of his    through a period recently where it        switch it over to B100.


www.attra.ncat.org                                                                                        ATTRA            Page 5
approved a standard specifically for biodie-
  Biodiesel-Compatible Fuel Lines                                       sel, ASTM D6751. This standard covers all
  The following fuel lines are claimed by their manufacturers to be     biodiesel fuels, regardless of feedstock or
  B100-compatible (14):                                                 processing method.
    • Goodyear part numbers 65148 thru 65153 & 65161 thru 65163 meet
      SAE specification J30R9.
                                                                        These legal requirements only apply to fuel
                                                                        that is sold. Home brewers, cooperatives,
    • Gates part number 4241G and 4241M for marine use.
                                                                        and farms making fuel for their own use are
    • Kuriyama part number A4143.
                                                                        not required to meet ASTM D6751.
    • NAPA fuel injection hose part H205.
    • McMaster-Carr Viton rubber tubing part number 5119K51             ASTM testing must be done by qualified
      (among many others).                                              laboratories and requires expensive equip-
    • Thomas Register listing of other Viton tubing suppliers.          ment. The standards are listed in the table
                                                                        on the following page.

                         Issue #5: Engine Oil Dilution
                                                                          Case Study:
                         and Fuel Oxidation                               The Minnesota Biodiesel Mandate
                         In blends higher than B20, unburned              In September 2005, Minnesota passed a
                         biodiesel can make its way past the piston       law requiring all diesel fuel to contain two
                         rings and into the oil pan.(8) This happens      percent biodiesel. Soon after the mandate
                         because biodiesel has a slightly higher vis-     went into effect, Minnesota truckers began
                         cosity and density than standard diesel.         to experience sporadic problems, includ-
                         Eventually, this fuel in the engine oil can      ing trucks breaking down on the road, hefty
                                                                          repair bills, and lost road time. The culprit
                         polymerize, causing oil sludge that coats        was clogged fuel filters and it soon became
                         metal surfaces and causes moving parts to        apparent that biodiesel was to blame.
                         stick.(4) If you are using biodiesel blends      Cold weather gelling was found to be the
                         higher than B20, you may need to change          main problem. In December 2005, the Min-




I
                         your engine oil more frequently.                 nesota Department of Commerce confirmed
     n 2001, ASTM                                                         that some biodiesel producers had shipped
     approved a                                                           biodiesel that did not meet ASTM D6751
                         Issue #6: Microbial Growth                       specification for free and total glycerin.(12)
     standard specif-    Water can sometimes drip through vents           “There’s no room for poor-quality biodie-
ically for biodiesel,    and collect at the bottom of fuel tanks.         sel in the marketplace,” said Steve Howell,
ASTM D6751.              Certain varieties of algae, yeast, and fungi     technical director with the National Biodiesel
                         can grow at the interface of the fuel and        Board. “Although investigations have indi-
                         water.(4) In order to prevent microbial          cated that other factors unrelated to biodie-
                                                                          sel may have led to at least some of the fil-
                         growth, you should drain any water from          ter-plugging reports in Minnesota, there’s
                         the bottom of your fuel tank on a regular        no question that off-specification biodiesel
                         basis. Certain biocides can also be added        can have a severe reaction in cold weather,
                         to control microbial growth, but the dead        even in low blends.”(13)
                         microbes may plug fi lters.                       All Minnesota biodiesel producers subse-
                                                                          quently had to prove that their fuel met
                                                                          ASTM specifications.(12) After imple-
                         ASTM Standards                                   menting additional quality measures,
                         The American Society for Testing and             the Department of Commerce reaffirmed
                         Materials (ASTM) is the industry organiza-       the ruling that diesel fuel was required to
                         tion that defines legal fuel standards: mini-     contain two percent biodiesel meeting
                         mum values that a fuel must meet to operate      ASTM D6751 specifications.
                         safely in a compression ignition engine.         Minnesota’s experience showed that even
                                                                          a low-percentage of off-spec biodiesel—
                         All diesel engines sold in the U.S. are man-     as low as two percent!—can cause perfor-
                         ufactured to meet ASTM D975, the legal           mance problems .
                         standard for petrodiesel. In 2001, ASTM

Page 6       ATTRA                                                         Biodiesel Use, Handling, and Fuel Quality
Table 1: ASTM Standards


 Property                               ASTM Method                     Limits                       Units

 Calcium & Magnesium,
                                        EN 14538                        5 max                        ppm (ug/g)
 combined
 Flash Point (closed cup)               D 93                            93 min                       Degrees C
 Alcohol Control
 1. Methanol Content                    EN 14110                        0.2 max                      % volume
 2. Flash Point                         D 93                            130 min                      Degrees C
 Water & Sediment                       D 2709                          0.05 max                     % volume
 Kinematic Viscosity, 40 C              D 445                           1.9 – 6.0                    mm2/sec
 Sulfated Ash                           D 874                           0.02 max                     % mass
 Sulfur
 S 15 Grade                             D 5453                          0.0015 max (15)              % mass (ppm)
 S 500 Grade                            D 5453                          0.05 max (500)               % mass (ppm)
 Copper Strip Corrosion                 D 130                           No. 3 max
 Cetane                                 D 613                           47 min
 Cloud Point                            D 2500                          Report                       Degrees C
 Carbon Residue 100% Sample             D 4530                          0.05 max                     % mass
 Acid Number                            D 664                           0.50 max                     mg KOH/g
 Free Glycerin                          D 6584                          0.020 max                    % mass
 Total Glycerin                         D 6584                          0.240 max                    % mass
 Phosphorus Content                     D 4951                          0.001 max                    % mass
 Distillation, T90 AET                  D 1160                          360 max                      Degrees C
 Sodium/Potassium, combined             EN 14538                        5 max                        ppm
 Oxidation Stability                    EN14112                         3 min                        hours
Adapted from The National Biodiesel Board, Specification For Biodiesel (B100) – ASTM D6751-07a.(15)




                                                                                    blending, shipping, distribution, and fuel
                            The BQ-9000 Program                                     management practices.
                            The National Biodiesel Board has insti-
                            tuted a cooperative and voluntary quality               Any biodiesel producer, marketer or
                            assurance program called BQ-9000. The                   distributor of biodiesel or biodiesel blends
                            program was developed to ensure a more                  in the U.S. or Canada is eligible for pro-
                            consistent quality for biodiesel being pro-             gram accreditation. Accredited manufactur-
                            duced, marketed, and used. While ASTM                   ers and certified marketers under this pro-
                            standards only cover fuel quality, BQ-9000              gram are listed on the BQ-9000 website,
                            encompasses storage, sampling, testing,                 www.bq-9000.com.


www.attra.ncat.org                                                                                           ATTRA      Page 7
It’s certainly true that bad quality biodie-
  Are You Sure Your Fuel Is Meeting ASTM Standards?                          sel can cause performance problems that
  A study released in November 2006 suggests that inconsistent fuel          are not the fault of the engine maker and
  quality continues to be a real issue for the US biodiesel industry—        so are not covered by the warranty. These
  despite the legal requirement that commercial fuel must meet ASTM          situations are no different from ones where
  standards.                                                                 a problem has been caused by bad quality
  Co-funded by the National Biodiesel Board (NBB) and the National
                                                                             petroleum diesel or gasoline.
  Renewable Energy Laboratory (NREL), the study randomly collected           Engine manufacturers would generally refer
  biodiesel samples from 32 fuel distributors around the country between     any customer with fuel-related problems to
  November 2005 and July 2006.
                                                                             the fuel supplier. According to the National
  Half of the samples failed to meet at least one of the ASTM D6751          Biodiesel Board, any reputable fuel supplier
  specifications, and some samples failed multiple standards. Thirty          (petrodiesel, biodiesel, or blend) should
  percent of the samples failed to meet the flash point standard, and         stand behind its product and cover any fuel
  one-third of the samples failed to meet the total glycerin standard.(18)
                                                                             quality problems that occur.(16)
                                                                             Biodiesel sold in the U.S. is subject to qual-
                                                                             ity requirements that are just as strict as
                          Will Biodiesel Void My                             those for standard diesel fuel. You are on
                          Warranty?                                          strong legal ground in using ASTM-compli-
                                                                             ant biodiesel fuel—just as you would be in
                          Many farms and ranches are discouraged
                                                                             using ASTM-compliant petroleum diesel.
                          from using biodiesel, especially in newer
                                                                             Unfortunately, though, your strong legal
                          vehicles, because of fears that they will
                                                                             position does not guarantee that you will be
                          “void their warranties.”
                                                                             free from warranty-related hassles. Some
                          It’s a good idea to check with your vehicle        equipment dealers are still poorly informed
                          manufacturer to see if they have an official        and will caution customers against using
                          policy on the use of biodiesel. Most major         biodiesel, since they (mistakenly) regard it
                          engine companies have formally stated that         as unregulated or unreliable.
                          biodiesel blends below 20 percent that meet
                          ASTM D6751 will not void their engine
                          warranties.                                         Caterpillar -
                                                                              Biodiesel Use Statement
                          The National Biodiesel Board has posted on          “Caterpillar neither approves nor prohibits use
                          its website several statements from engine          of biodiesel fuels. Caterpillar is not in a position
                          companies (www.biodiesel.org). John Deere,          to evaluate the many variations of biodiesel and
                          Caterpillar, and New Holland are among              the long term effects on performance, durabil-
                          the many companies that have adopted pol-           ity, or compliance to emissions standards for
                          icies supportive of biodiesel. Other compa-         Caterpillar products. The use of biodiesel fuel
                                                                              does not affect Caterpillar’s materials and work-
                          nies are in the process of developing guide-        manship. Failures that result from the use of any
                          lines for biodiesel.                                fuel are not Caterpillar factory defects. There-
                          A number of authorities state fl atly that           fore, the cost or repair would NOT be covered
                                                                              by a Caterpillar’s warranty.”(17)
                          the use of biodiesel does not, in itself, void
                          engine warranties. [See, for example, (1)           Caterpillar Commercial Diesel Engine Fluids
                          and (2)] Engine warranties typically cover          Recommendations
                          the “materials and workmanship” of the              SEBU6251-08 March 2004
                          engine, and say little or nothing about fuel.




Page 8       ATTRA                                                               Biodiesel Use, Handling, and Fuel Quality
How Can I Be Sure I’m
Getting Good Fuel?
It’s important to keep the issue of poor qual-




                                                                                                                        Photo: www.biodieselcommunity.org
ity, off-spec fuel in perspective: The vast
majority of biodiesel consumers experience
no fuel-related problems whatsoever. There
is also (unfortunately) off-spec gasoline and
diesel fuel in the marketplace too.
To reduce your chances of buying off-spec
biodiesel, get to know your dealer and ask
questions. How long have they been in busi-
                                                              pHLip test results, showing fuel quality problems.
ness? What feedstocks are used? What are
the cold weather characteristics of the fuel?
How frequently is the fuel tested for ASTM
compliance? Are your manufacturer and            While most of these are mainly of interest
marketer BQ-9000 accredited?                     to biodiesel fuel makers, some are within
                                                 the capability of technically minded fuel
Don’t assume that bigger companies are           consumers, too.
necessarily better. Many small producers
take pride in making excellent fuel, and         Conclusion
some large producers have been known to
make bad batches.                                Biodiesel users should take some basic pre-
                                                 cautions to avoid performance problems:
                                                      • Perform regular maintenance, check
Do-It-Yourself Fuel                                     fuel fi lters frequently, and change
Quality Testing                                         them as necessary.
You can mail a sample of fuel to a labora-            • Understand biodiesel’s cold weather
tory for comprehensive ASTM testing, but                properties and take appropriate
the price tag is likely to be a hefty $800              precautions.
to $1,000 or more. Fortunately, there are
some inexpensive alternatives for consum-             • Be aware of biodiesel’s incompat-
ers and fuel makers.                                    ibility with certain materials and
                                                        replace any incompatible parts,
Dr. Randall von Wedel has developed a sim-              especially rubber fuel lines.
ple testing kit called the pHLip (pronounced          • Regularly drain water from the
“fl ip”) Test. You fi ll a vial with B100 to              bottom of fuel tanks, to prevent
the indicated level, then fl ip the sample 10            microbial growth.
times and wait 10 minutes for the fuel to
float to the top. Through visual inspection            • Use stored biodiesel within about
you can identify a variety of fuel quality              six months.
problems, including old, poorly washed, or            • Make sure that fuel meets ASTM
oxidized fuel. The kits are NOT a substitute            D6751.
for ASTM testing and standards, but cost              • Incorporate biodiesel into farming
only around $5 per test and allow quick in-             operations gradually. Start slowly
the-field testing. For more information, visit           and expand your use of the fuel as
www.phliptest.com.                                      you gain confidence.
Several simple fuel quality tests are also            • Make sure your biodiesel comes
described on the Journey to Forever site, at            from a reputable source. Get to
http://journeytoforever.org/biodiesel_vehicle.          know your fuel provider and ask
html. These include the “wash test,” “repro-            questions about feedstocks and
cessing test,” “methanol test,” and others.             quality testing.
www.attra.ncat.org                                                                                      ATTRA      Page 9
References                                               10. Anon. No Date. Background. National Biodiesel
                                                                Board. Retrieved May 10, 2007. www.biodie-
1. Pahl, Greg. 2005. Biodiesel: Growing a New                   sel.org/pdf _ files/fuelfactsheets/Cold%20Flow.pdf
        Energy Economy. White River Junction, VT:        11. Brown, Jack and Jim Davis. January 31, 2007.
        Chelsea Green Publishing Company.                       “Agronomics of Oil Seed Crops in the Pacific
2. Clean Cities. 2006. “Straight Vegetable Oil as a             Northwest.” Biodiesel in the Pacific Northwest
       Diesel Fuel?” Washington, DC: U.S. Depart-               Biodiesel Workshop Course. National Biodiesel
       ment of Energy. Retrieved May 9, 2007.                   Program, University of Idaho.
       www.eere.energy.gov/cleancities                   12. Zeman, Nicholas. 2006. “Remember December.”
                                                                Biodiesel Magazine, October. Retrieved May
3. Engine Manufacturers Association. 2006.
                                                                11, 2007. www.biodieselmagazine.com/
       “Use of Raw Vegetable Oil or Animal Fats                 article-print.jsp?article_id=1180
       in Diesel Engines.” Chicago, IL: Engine
       Manufacturers Association.                        13. Barrett, Rick. 2006. “Minnesota Aims to Get
                                                                Biodiesel Back In Gear.” Milwaukee Journal
4. Van Gerpen, Jon. “Biodiesel Use and Consumption.”            Sentinel, February 1. Retrieved May 11, 2007.
       Montana Oilseed and Biodiesel Workshop.                  http://findarticles.com/p/articles/mi_qn4196/is_
       Great Falls, MT: Montana Farmers Union and               20060201/ai_n16036216/print
       Montana Grain Growers Association,
                                                         14. Anon. No date. “Solvency Effects.” Piedmont Bio-
       February 15, 2007.
                                                                fuels. Retrieved May 14, 2007. http://biofuels.
5. Ryan, David. 2004. “Biodiesel—A Primer.”                     coop/general-information/solvency-effects
       Butte, MT: National Center for Appropriate        15. Anon. 2007. Specification For Biodiesel (B100).
       Technology.                                              ASTM D6751-07a. National Biodiesel Board.
6. Anon. 2006. Fuel Quality and Performance Guide.              Retrieved June 9, 2007. www.biodiesel.org/
       National Biodiesel Board. Retrieved May 11,              pdf-files/fuelfactsheets/BDSpec.pdf
       2007. www.biodiesel.org/pdf _ files/Fuel           16. Anon. No Date. “Biodiesel Standards and Warran-
       QualityandPerformanceGuide.pdf                           ties.” National Biodiesel Board. Retrieved May
7. Tyson, K. Shaine. 2001. Biodiesel Handling and               14, 2007. www.biodiesel.org/resources/
                                                                fuelfactsheets/standards-and-warranties.shtm
       Use Guidelines. Golden, CO: National Renew-
       able Energy Laboratory.                           17. Freckmann, Chad. 2006. “Biodiesel: A Renew-
                                                                able, Premium Fuel to Meet Today’s and
8. Anon. 2005. “Use of Biodiesel Blends above                   Tomorrow’s Energy Needs in a Clean and
       20% Biodiesel.” National Biodiesel Board.                Sustainable Manner.” Kilarnock, VA: Hampton
       Retrieved May 14, 2007. www.biodiesel.org/               Clean Cities Coalition. Retrieved May 9, 2007.
       pdf _ files/Biodiesel_Blends_Above%20_20_                 www.hrccc.org/presentations/BlueRidge
       Final.pdf                                                CleanFuels-Biodieseloverview.pdf
9. Pelly, Mike. 2003. “Mike Pelly’s Biodiesel Method.”   18. Anon. January 2007. “Biodiesel tests reveal off-spec
        Journey to Forever. Retrieved June 5, 2007.             fuel in U.S. market.” Biodiesel Magazine. www.
        www.journeytoforever.org/biodiesel_mike.html            biodieselmagazine.com/article.jsp?article_id=1345




Page 10    ATTRA                                                         Biodiesel Use, Handling, and Fuel Quality
Notes




www.attra.ncat.org   ATTRA   Page 11
Biodiesel Use, Handling, and Fuel Quality
                  By Andrew Pressman and Mike Morris
                  NCAT Energy Specialists
                  © 2007 NCAT
                  This publication is available on the Web at:
                  www.attra.ncat.org/attra-pub/biodiesel_use.html
                  or
                  www.attra.ncat.org/attra-pub/PDF/biodiesel_use.pdf
                  IP315
                  Slot 314
                  Version 102407


Page 12   ATTRA

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Biodiesel Use, Handling, and Fuel Quality

  • 1. Biodiesel Use, Handling, and Fuel Quality A Publication of ATTRA - National Sustainable Agriculture Information Service • 1-800-346-9140 • www.attra.ncat.org By Andrew Pressman This publication addresses questions that farmers and ranchers may have about using biodiesel in diesel and Mike Morris engines. Biodiesel can be substituted for petroleum-based diesel fuel in virtually any standard unmodi- NCAT Energy fied diesel engine. However, biodiesel has chemical properties that require somewhat different use and Specialists handling. While most biodiesel users experience few if any problems, consumers can take precautions September 2007 to avoid potential problems associated with poor quality fuel. © 2007 NCAT Contents Introduction .................... 1 Biodiesel, Ethanol, Vegetable Oil: What’s the Difference? ............... 2 Blending and Storage .............................. 3 Issues and Concerns ..... 4 Photos: Vern Grubinger ASTM Standards ............. 6 The BQ-9000 Program ............................. 7 Warranty Issues .............. 8 Fuel Quality Testing ..... 9 Conclusion ....................... 9 References ...................... 10 Introduction • It functions as an excellent fuel lubricant and performs similarly Biodiesel is becoming widely available in to low-sulfur diesel with regards to most parts of the U.S. and can be substi- power, torque, and fuel consumption. tuted for petroleum-based diesel fuel (“pet- rodiesel”) in virtually any standard unmod- • It can greatly reduce carbon emissions. ified diesel engine. Biodiesel offers many For discussion of the environmental advan- Funding for the development advantages over petroleum-based diesel: tages of biodiesel, see the ATTRA publica- of this publication was provided tion Biodiesel: the Sustainability Dimensions. by the USDA Risk Management • It is made from domestically Agency. produced and renewable agricul- To find retail biodiesel distributors in your tural products, mainly vegetable oil area, use NCAT’s Farm Energy Search Tool, or animal fat. www.attra.ncat.org/farmenergysearchtool. ATTRA—National Sustainable Most biodiesel users pour it in the tank and Agriculture Information Ser- • It is essentially non-toxic and bio- vice is managed by the National degradable. experience few if any problems. Nonethe- Center for Appropriate Technol- ogy (NCAT) and is funded under less, biodiesel has chemical properties that a grant from the United States • It has a high flash point (over 300ºF) can cause difficulties. For example: Department of Agriculture’s and is difficult to light on fi re with Rural Business- Cooperative • Biodiesel’s detergent or solvent Service. Visit the NCAT Web site a match. (www.ncat.org/agri. properties can clog your fuel fi lter html) for more informa- tion on our sustainable • It reduces emissions of many toxic as it cleans carbon deposits from agriculture projects. air pollutants. your engine.
  • 2. • Compared to petrodiesel, biodie- any plant oil or animal fat. Making biodie- sel has somewhat worse cold-flow sel is a chemical process. During this chem- properties. ical reaction, a thick gooey substance, glyc- • Biodiesel degrades rubber and cer- erin, is released from the oil molecules and tain other materials, making it incom- replaced with a comparatively thin and light patible with some fuel lines, rubber alcohol, usually methanol. For an expla- gaskets, and other engine parts. nation of how to make biodiesel, see the This article offers suggestions to help farm- ATTRA publication Biodiesel: a Primer. ers and other consumers get the benefits of Biodiesel is also very different from raw or biodiesel while avoiding performance and “straight” vegetable oil (SVO). Almost any equipment problems. vegetable oil will combust, to one degree or another, in a diesel engine. So it’s possible Caution: If you are making your own fuel, to run most diesel engines on SVO. But this using and storing large quantities of biodiesel, is a somewhat risky process, mainly since or selling fuel commercially, you will need to raw vegetable oil is too thick and viscous to take many safety, legal, and quality-related precautions beyond the ones described here. run well in diesel engines. Biodiesel will perform well in almost any standard diesel engine without modifica- Biodiesel, Ethanol, Vegetable tions. On the other hand, to use SVO you Oil: What’s the Difference? will need to modify your engine. Conver- sion kits are readily available for $300 to Biodiesel is a very different substance from $1,500.(1) Generally, conversion means ethanol. Ethanol (or grain alcohol), the installing a separate fuel tank, heater, and Photo: www.biodieselcommunity.org familiar alcohol found in alcoholic bever- fuel line, along with various switches and ages, is commonly blended with gasoline controls. The idea is to thin the oil by heat- (not diesel fuel) and is made by fermenting ing it, while taking precautions to keep cold, grains or other plants that contain sugar. gooey vegetable oil out of your engine. You Fermentation is a biological process accom- start and run the engine on standard diesel plished by yeasts and bacteria. fuel or biodiesel. Once the engine is warm Biodiesel is essentially permanently thinned and you’ve pre-heated the vegetable oil— plant or animal-based oil, with a viscosity stored in a separate tank—you can switch to approximating that of standard #2 diesel SVO. Several minutes before turning off the fuel. Biodiesel can be made from virtually engine, you switch back to standard diesel fuel or biodiesel, clearing all the SVO out of your engine and fuel lines. The U.S. Department of Energy, among many other organizations, cautions that SVO can reduce engine life and should not be considered a fuel for long-term use.(2) The use of SVO has been shown to cause piston ring sticking, injector and combus- tion chamber deposits, fuel system deposits, reduced power, reduced fuel economy, and increased exhaust emissions. Any of these Photo: Vern Grubinger conditions can reduce engine life, increase maintenance costs, or cause engine failure. Modern diesel engines are also equipped with catalytic converters, or fi lter traps, that are not designed to handle SVO. Page 2 ATTRA Biodiesel Use, Handling, and Fuel Quality
  • 3. Performance problems don’t necessarily You should avoid adding biodiesel to cold happen quickly. Certain engines seem to petrodiesel, since this may cause crystals tolerate SVO better than others, and some to form. To prevent this from happening, vehicles run trouble-free for years. On the you can blend biodiesel with kerosene (also other hand, many SVO users succeed ini- called #1 diesel fuel) in a 50/50 mix before tially, and are lulled into a false sense of adding it to cold diesel fuel.(5) If crystals security, only to run into serious problems have already formed, the fuel will have to later.(3) be heated until they dissolve. Despite the very real risk of engine dam- age, SVO has certain advantages that may Biodiesel Storage make it worth considering for some farm- Biodiesel can be stored in standard petroleum ing situations and equipment, especially in diesel storage tanks with some precautions: older engines. Using SVO is in some ways • Tanks that have previously been simpler than making your own biodiesel. used to store diesel fuel should be Making biodiesel generally requires you cleaned before use. As noted below, to use methanol, a toxic chemical, and to biodiesel is an excellent solvent and dispose of glycerin, a waste product. By will loosen deposits left by standard contrast, SVO is generally only filtered diesel fuel. Tanks should also be before use, and there are few if any waste free of water, since this encourages products to deal with. bacterial growth. • Tanks may be made of aluminum, Biodiesel Blends and steel, Teflon, or fluorinated poly- Blending ethylene or polypropylene. Fiber- glass is sometimes used, but should Biodiesel in its pure (100 percent) form is be approached with caution since known as neat biodiesel or B100. It can be some resins are not compatible with readily blended with petroleum diesel in biodiesel.(4) any proportion. A B20 blend, for example, is 20 percent by volume biodiesel and 80 percent petrodiesel. Different blends serve different purposes. Small amounts of biodiesel (B1-B2) add Photos: Vern Grubinger lubrication to low-sulfur fuels. Blends in the B20 to B50 range provide significant envi- ronmental benefits with a low increase in cost to consumers. Blending also reduces the likelihood of the solvency, material incompatibility, or cold weather problems discussed below. The simplest method is splash blending. Biodiesel should always be poured on top of petroleum diesel, since it is slightly heavier. The two fuels will mix fairly well as the biodiesel gradually sinks through the lighter petrodiesel. Some form of agi- tation is needed, though, to achieve highly uniform fuel. Random samples of splash- blended fuel being marketed as B20 have been found to contain actual biodiesel content ranging from B2 to B90.(4) www.attra.ncat.org ATTRA Page 3
  • 4. • Both petrodiesel and biodiesel can fuel tank before converting to biodiesel. An cause metal parts to oxidize, so you alternative is to switch to finer fi lters. Any- should replace any parts made of one using B100 should know how to change brass, bronze, copper, lead, tin, or the fuel fi lter and should carry a spare fuel zinc with aluminum or steel. fi lter or two. Expect to change your fuel fi l- • If biodiesel or blended fuels are ter two or three times before all the deposits stored beyond around six months, are cleaned out of your engine. If you are fuel stabilizers should be added.(6) using a modest blend (B20 or lower), you Old fuel will become acidic and are less likely to notice fi lter clogging. form sediments and varnish. • Biodiesel and biodiesel blends Issue #2: Reduced Power should be stored at temperatures On average, B100 has about eight per- at least 15 degrees above the pour cent less energy content (BTU per gallon) point of the fuels.(7) The pour point than #2 petrodiesel, while B20 has one to is the temperature below which a two percent less energy content.(8) If you fuel will not pour. switch from standard diesel fuel to B100, A you may notice a slight decrease in horse- nyone using • Outdoor tanks should be located in power, torque, or fuel economy. At B20 or B100 should cool shaded areas if possible. less, you probably won’t be able to tell the know how difference. to change the fuel Caution: If you are storing large amounts of fuel, or selling it commercially, you will need A cetane number is an indicator of diesel fuel filter and should to take many additional precautions and meet quality, measuring the readiness of fuel to carry a spare fuel local laws and code requirements. ignite when injected into the engine. Biodie- filter or two. sel’s cetane number is higher than that of standard diesel fuel, and this advantage may partly compensate for its lower BTU content. Issue #1: Solvent Effects Because biodiesel ignites more readily in and Filter Clogging diesel engines than petrodiesel, some author- ities recommend setting the injection timing According to researchers at the University back by two to three degrees from top-dead of Idaho, filter plugging is the most common center. This will sometimes cause the engine problem experienced by biodiesel users.(4) to run quieter, although it may also slightly Biodiesel has excellent solvent properties reduce your power.(9) and can be used as a cleaning agent and paint remover. (It can remove the paint on Issue #3: Cold Weather the side of your car or tractor, if you splash it around while fi lling the tank.) In fact, it Performance can even dissolve concrete.(4) All diesel fuel, including petroleum-based fuel, begins to gel at cold temperatures. Petroleum diesel often leaves a deposit in The temperature at which a cloud of wax the bottom of fuel lines, tanks, and deliv- crystals forms in the fuel is known as the ery systems. Biodiesel can loosen and dis- cloud point. The cold filter plugging point solve these sediments, as well as rust and is the lowest temperature at which fuel can other materials. This causes fuel fi lters to be drawn through a metal screen fi lter.(10) become clogged—sometimes in a matter of The pour point is the temperature below hours after switching to B100. Symptoms of which a fuel will not pour. fi lter clogging include a sudden power loss In general, biodiesel gels at somewhat higher or engine shuddering. temperatures than conventional #2 diesel. Older vehicles have more accumulated When wax crystals begin to form in biodie- deposits, and are especially prone to fi lter sel, the entire fuel tends to cloud at the same clogging. Ideally, you should clean an old time. In contrast, petroleum diesel is made Page 4 ATTRA Biodiesel Use, Handling, and Fuel Quality
  • 5. up of many different compounds that gel at since they will work on the petroleum-based different temperatures. When some of these portion of the fuel. begin to crystallize, others remain liquid to a much lower temperature. Issue #4: Softening Fuel Lines The cloud point for standard #2 diesel fuel Using a high-percentage biodiesel blend or is around 5ºF. The cloud point for biodiesel B100 can cause certain types of elastomers depends on the feedstock and the amount and natural rubber compounds to bubble, of free fatty acids in the fuel. The cloud bleed, soften, and degrade over time. Virtu- point for soy diesel is around 32ºF (4), ally all diesel vehicles made since the early compared to cloud points around 20ºF for 1990s use components that are compatible canola and 12ºF for rapeseed.(11) Biodie- with B100.(4) But some older fuel hoses will sel made from used cooking grease or ani- need to be replaced. mal fats will tend to cloud at higher tem- peratures than biodiesel made from virgin Equipment changes are rarely if ever oils. Biodiesel from the most highly satu- necessary with blends of B20 or lower.(8) rated feedstocks may gel at temperatures as Besides rubber, other vulnerable materials high as 50-55ºF. identified by the National Biodiesel Board Low-percentage biodiesel blends generally include polypropylene, polyvinyl, and Tygon. have cold weather properties similar to pet- Although there have been a few reports of rodiesel. The cloud point of B20 may be degraded injection pump seals, by far the most 3º-10ºF higher than #2 petrodiesel.(8) common problem you are likely to encounter is with rubber fuel lines. If you have an older Simple cold weather precautions include vehicle, you should inspect your fuel lines using engine block or fuel filter heaters frequently after you begin using biodiesel. and parking vehicles in or near a build- ing. Fuel additives can also inhibit crystal The good news is that these problems are growth and gelling in standard diesel fuel. likely to appear gradually, if they appear Anecdotal reports suggest that few if any at all. Hoses will begin to soften and (even- of these products work well on B100. They tually) weep. You are unlikely to experience may be effective on blended fuel, however, a catastrophic failure. Case Study: vehicles, gradually expanding his usage seemed as if he needed to change fil- Phil Foster Ranches as he became comfortable with the ters more often than normal. “Maybe fuel’s performance. He also asked his the fuel was a tad off ... We’ll probably Phil Foster began using biodiesel on his supplier lots of questions about test- never know for sure.” organic vegetable farm near San Juan ing, standards, and feedstocks. Bautista, California in 2004. He saw the Fuel economy may have decreased use of non-petroleum fuels as consis- By 2006, biodiesel made up 81 percent slightly, in the range of three to five tent with his philosophy as an organic of the roughly 20,000 gallons of diesel percent. There have also been a few vegetable farmer. He liked the idea that fuel consumed annually by the farm’s cold mornings (18º - 20 ºF) when the any fuel spills would be biodegradable tractors, pickups, and delivery trucks. vehicles running on B100 would not and far less toxic than standard diesel. Most of the farm’s diesel vehicles are start. Switching temporarily to B30 dur- He was attracted by the air quality now running B100, although with some ing cold weather has solved this prob- and health advantages for his family of his older equipment Phil has been and his workers. And he liked the idea reluctant to go above B30. lem, and all vehicles have started fine of purchasing fuel made from agricul- on B30. Overall, Phil comments that “After four tural products, preferably ones grown Phil recently bought a new truck, which years of using biodiesel, we’ve had locally or regionally. he plans to run on B30 for the first six to very good results.” He did experience Phil didn’t have the time or inclination some filter plugging when switching twelve months - enough time for any to make his own fuel, so he began pur- to biodiesel, and he now changes his problems to show up. Once he’s confi- chasing biodiesel from a local retailer. filters at every service. He also went dent in the vehicle’s performance, he’ll Initially, he tried B100 in some of his through a period recently where it switch it over to B100. www.attra.ncat.org ATTRA Page 5
  • 6. approved a standard specifically for biodie- Biodiesel-Compatible Fuel Lines sel, ASTM D6751. This standard covers all The following fuel lines are claimed by their manufacturers to be biodiesel fuels, regardless of feedstock or B100-compatible (14): processing method. • Goodyear part numbers 65148 thru 65153 & 65161 thru 65163 meet SAE specification J30R9. These legal requirements only apply to fuel that is sold. Home brewers, cooperatives, • Gates part number 4241G and 4241M for marine use. and farms making fuel for their own use are • Kuriyama part number A4143. not required to meet ASTM D6751. • NAPA fuel injection hose part H205. • McMaster-Carr Viton rubber tubing part number 5119K51 ASTM testing must be done by qualified (among many others). laboratories and requires expensive equip- • Thomas Register listing of other Viton tubing suppliers. ment. The standards are listed in the table on the following page. Issue #5: Engine Oil Dilution Case Study: and Fuel Oxidation The Minnesota Biodiesel Mandate In blends higher than B20, unburned In September 2005, Minnesota passed a biodiesel can make its way past the piston law requiring all diesel fuel to contain two rings and into the oil pan.(8) This happens percent biodiesel. Soon after the mandate because biodiesel has a slightly higher vis- went into effect, Minnesota truckers began cosity and density than standard diesel. to experience sporadic problems, includ- Eventually, this fuel in the engine oil can ing trucks breaking down on the road, hefty repair bills, and lost road time. The culprit polymerize, causing oil sludge that coats was clogged fuel filters and it soon became metal surfaces and causes moving parts to apparent that biodiesel was to blame. stick.(4) If you are using biodiesel blends Cold weather gelling was found to be the higher than B20, you may need to change main problem. In December 2005, the Min- I your engine oil more frequently. nesota Department of Commerce confirmed n 2001, ASTM that some biodiesel producers had shipped approved a biodiesel that did not meet ASTM D6751 Issue #6: Microbial Growth specification for free and total glycerin.(12) standard specif- Water can sometimes drip through vents “There’s no room for poor-quality biodie- ically for biodiesel, and collect at the bottom of fuel tanks. sel in the marketplace,” said Steve Howell, ASTM D6751. Certain varieties of algae, yeast, and fungi technical director with the National Biodiesel can grow at the interface of the fuel and Board. “Although investigations have indi- water.(4) In order to prevent microbial cated that other factors unrelated to biodie- sel may have led to at least some of the fil- growth, you should drain any water from ter-plugging reports in Minnesota, there’s the bottom of your fuel tank on a regular no question that off-specification biodiesel basis. Certain biocides can also be added can have a severe reaction in cold weather, to control microbial growth, but the dead even in low blends.”(13) microbes may plug fi lters. All Minnesota biodiesel producers subse- quently had to prove that their fuel met ASTM specifications.(12) After imple- ASTM Standards menting additional quality measures, The American Society for Testing and the Department of Commerce reaffirmed Materials (ASTM) is the industry organiza- the ruling that diesel fuel was required to tion that defines legal fuel standards: mini- contain two percent biodiesel meeting mum values that a fuel must meet to operate ASTM D6751 specifications. safely in a compression ignition engine. Minnesota’s experience showed that even a low-percentage of off-spec biodiesel— All diesel engines sold in the U.S. are man- as low as two percent!—can cause perfor- ufactured to meet ASTM D975, the legal mance problems . standard for petrodiesel. In 2001, ASTM Page 6 ATTRA Biodiesel Use, Handling, and Fuel Quality
  • 7. Table 1: ASTM Standards Property ASTM Method Limits Units Calcium & Magnesium, EN 14538 5 max ppm (ug/g) combined Flash Point (closed cup) D 93 93 min Degrees C Alcohol Control 1. Methanol Content EN 14110 0.2 max % volume 2. Flash Point D 93 130 min Degrees C Water & Sediment D 2709 0.05 max % volume Kinematic Viscosity, 40 C D 445 1.9 – 6.0 mm2/sec Sulfated Ash D 874 0.02 max % mass Sulfur S 15 Grade D 5453 0.0015 max (15) % mass (ppm) S 500 Grade D 5453 0.05 max (500) % mass (ppm) Copper Strip Corrosion D 130 No. 3 max Cetane D 613 47 min Cloud Point D 2500 Report Degrees C Carbon Residue 100% Sample D 4530 0.05 max % mass Acid Number D 664 0.50 max mg KOH/g Free Glycerin D 6584 0.020 max % mass Total Glycerin D 6584 0.240 max % mass Phosphorus Content D 4951 0.001 max % mass Distillation, T90 AET D 1160 360 max Degrees C Sodium/Potassium, combined EN 14538 5 max ppm Oxidation Stability EN14112 3 min hours Adapted from The National Biodiesel Board, Specification For Biodiesel (B100) – ASTM D6751-07a.(15) blending, shipping, distribution, and fuel The BQ-9000 Program management practices. The National Biodiesel Board has insti- tuted a cooperative and voluntary quality Any biodiesel producer, marketer or assurance program called BQ-9000. The distributor of biodiesel or biodiesel blends program was developed to ensure a more in the U.S. or Canada is eligible for pro- consistent quality for biodiesel being pro- gram accreditation. Accredited manufactur- duced, marketed, and used. While ASTM ers and certified marketers under this pro- standards only cover fuel quality, BQ-9000 gram are listed on the BQ-9000 website, encompasses storage, sampling, testing, www.bq-9000.com. www.attra.ncat.org ATTRA Page 7
  • 8. It’s certainly true that bad quality biodie- Are You Sure Your Fuel Is Meeting ASTM Standards? sel can cause performance problems that A study released in November 2006 suggests that inconsistent fuel are not the fault of the engine maker and quality continues to be a real issue for the US biodiesel industry— so are not covered by the warranty. These despite the legal requirement that commercial fuel must meet ASTM situations are no different from ones where standards. a problem has been caused by bad quality Co-funded by the National Biodiesel Board (NBB) and the National petroleum diesel or gasoline. Renewable Energy Laboratory (NREL), the study randomly collected Engine manufacturers would generally refer biodiesel samples from 32 fuel distributors around the country between any customer with fuel-related problems to November 2005 and July 2006. the fuel supplier. According to the National Half of the samples failed to meet at least one of the ASTM D6751 Biodiesel Board, any reputable fuel supplier specifications, and some samples failed multiple standards. Thirty (petrodiesel, biodiesel, or blend) should percent of the samples failed to meet the flash point standard, and stand behind its product and cover any fuel one-third of the samples failed to meet the total glycerin standard.(18) quality problems that occur.(16) Biodiesel sold in the U.S. is subject to qual- ity requirements that are just as strict as Will Biodiesel Void My those for standard diesel fuel. You are on Warranty? strong legal ground in using ASTM-compli- ant biodiesel fuel—just as you would be in Many farms and ranches are discouraged using ASTM-compliant petroleum diesel. from using biodiesel, especially in newer Unfortunately, though, your strong legal vehicles, because of fears that they will position does not guarantee that you will be “void their warranties.” free from warranty-related hassles. Some It’s a good idea to check with your vehicle equipment dealers are still poorly informed manufacturer to see if they have an official and will caution customers against using policy on the use of biodiesel. Most major biodiesel, since they (mistakenly) regard it engine companies have formally stated that as unregulated or unreliable. biodiesel blends below 20 percent that meet ASTM D6751 will not void their engine warranties. Caterpillar - Biodiesel Use Statement The National Biodiesel Board has posted on “Caterpillar neither approves nor prohibits use its website several statements from engine of biodiesel fuels. Caterpillar is not in a position companies (www.biodiesel.org). John Deere, to evaluate the many variations of biodiesel and Caterpillar, and New Holland are among the long term effects on performance, durabil- the many companies that have adopted pol- ity, or compliance to emissions standards for icies supportive of biodiesel. Other compa- Caterpillar products. The use of biodiesel fuel does not affect Caterpillar’s materials and work- nies are in the process of developing guide- manship. Failures that result from the use of any lines for biodiesel. fuel are not Caterpillar factory defects. There- A number of authorities state fl atly that fore, the cost or repair would NOT be covered by a Caterpillar’s warranty.”(17) the use of biodiesel does not, in itself, void engine warranties. [See, for example, (1) Caterpillar Commercial Diesel Engine Fluids and (2)] Engine warranties typically cover Recommendations the “materials and workmanship” of the SEBU6251-08 March 2004 engine, and say little or nothing about fuel. Page 8 ATTRA Biodiesel Use, Handling, and Fuel Quality
  • 9. How Can I Be Sure I’m Getting Good Fuel? It’s important to keep the issue of poor qual- Photo: www.biodieselcommunity.org ity, off-spec fuel in perspective: The vast majority of biodiesel consumers experience no fuel-related problems whatsoever. There is also (unfortunately) off-spec gasoline and diesel fuel in the marketplace too. To reduce your chances of buying off-spec biodiesel, get to know your dealer and ask questions. How long have they been in busi- pHLip test results, showing fuel quality problems. ness? What feedstocks are used? What are the cold weather characteristics of the fuel? How frequently is the fuel tested for ASTM compliance? Are your manufacturer and While most of these are mainly of interest marketer BQ-9000 accredited? to biodiesel fuel makers, some are within the capability of technically minded fuel Don’t assume that bigger companies are consumers, too. necessarily better. Many small producers take pride in making excellent fuel, and Conclusion some large producers have been known to make bad batches. Biodiesel users should take some basic pre- cautions to avoid performance problems: • Perform regular maintenance, check Do-It-Yourself Fuel fuel fi lters frequently, and change Quality Testing them as necessary. You can mail a sample of fuel to a labora- • Understand biodiesel’s cold weather tory for comprehensive ASTM testing, but properties and take appropriate the price tag is likely to be a hefty $800 precautions. to $1,000 or more. Fortunately, there are some inexpensive alternatives for consum- • Be aware of biodiesel’s incompat- ers and fuel makers. ibility with certain materials and replace any incompatible parts, Dr. Randall von Wedel has developed a sim- especially rubber fuel lines. ple testing kit called the pHLip (pronounced • Regularly drain water from the “fl ip”) Test. You fi ll a vial with B100 to bottom of fuel tanks, to prevent the indicated level, then fl ip the sample 10 microbial growth. times and wait 10 minutes for the fuel to float to the top. Through visual inspection • Use stored biodiesel within about you can identify a variety of fuel quality six months. problems, including old, poorly washed, or • Make sure that fuel meets ASTM oxidized fuel. The kits are NOT a substitute D6751. for ASTM testing and standards, but cost • Incorporate biodiesel into farming only around $5 per test and allow quick in- operations gradually. Start slowly the-field testing. For more information, visit and expand your use of the fuel as www.phliptest.com. you gain confidence. Several simple fuel quality tests are also • Make sure your biodiesel comes described on the Journey to Forever site, at from a reputable source. Get to http://journeytoforever.org/biodiesel_vehicle. know your fuel provider and ask html. These include the “wash test,” “repro- questions about feedstocks and cessing test,” “methanol test,” and others. quality testing. www.attra.ncat.org ATTRA Page 9
  • 10. References 10. Anon. No Date. Background. National Biodiesel Board. Retrieved May 10, 2007. www.biodie- 1. Pahl, Greg. 2005. Biodiesel: Growing a New sel.org/pdf _ files/fuelfactsheets/Cold%20Flow.pdf Energy Economy. White River Junction, VT: 11. Brown, Jack and Jim Davis. January 31, 2007. Chelsea Green Publishing Company. “Agronomics of Oil Seed Crops in the Pacific 2. Clean Cities. 2006. “Straight Vegetable Oil as a Northwest.” Biodiesel in the Pacific Northwest Diesel Fuel?” Washington, DC: U.S. Depart- Biodiesel Workshop Course. National Biodiesel ment of Energy. Retrieved May 9, 2007. Program, University of Idaho. www.eere.energy.gov/cleancities 12. Zeman, Nicholas. 2006. “Remember December.” Biodiesel Magazine, October. Retrieved May 3. Engine Manufacturers Association. 2006. 11, 2007. www.biodieselmagazine.com/ “Use of Raw Vegetable Oil or Animal Fats article-print.jsp?article_id=1180 in Diesel Engines.” Chicago, IL: Engine Manufacturers Association. 13. Barrett, Rick. 2006. “Minnesota Aims to Get Biodiesel Back In Gear.” Milwaukee Journal 4. Van Gerpen, Jon. “Biodiesel Use and Consumption.” Sentinel, February 1. Retrieved May 11, 2007. Montana Oilseed and Biodiesel Workshop. http://findarticles.com/p/articles/mi_qn4196/is_ Great Falls, MT: Montana Farmers Union and 20060201/ai_n16036216/print Montana Grain Growers Association, 14. Anon. No date. “Solvency Effects.” Piedmont Bio- February 15, 2007. fuels. Retrieved May 14, 2007. http://biofuels. 5. Ryan, David. 2004. “Biodiesel—A Primer.” coop/general-information/solvency-effects Butte, MT: National Center for Appropriate 15. Anon. 2007. Specification For Biodiesel (B100). Technology. ASTM D6751-07a. National Biodiesel Board. 6. Anon. 2006. Fuel Quality and Performance Guide. Retrieved June 9, 2007. www.biodiesel.org/ National Biodiesel Board. Retrieved May 11, pdf-files/fuelfactsheets/BDSpec.pdf 2007. www.biodiesel.org/pdf _ files/Fuel 16. Anon. No Date. “Biodiesel Standards and Warran- QualityandPerformanceGuide.pdf ties.” National Biodiesel Board. Retrieved May 7. Tyson, K. Shaine. 2001. Biodiesel Handling and 14, 2007. www.biodiesel.org/resources/ fuelfactsheets/standards-and-warranties.shtm Use Guidelines. Golden, CO: National Renew- able Energy Laboratory. 17. Freckmann, Chad. 2006. “Biodiesel: A Renew- able, Premium Fuel to Meet Today’s and 8. Anon. 2005. “Use of Biodiesel Blends above Tomorrow’s Energy Needs in a Clean and 20% Biodiesel.” National Biodiesel Board. Sustainable Manner.” Kilarnock, VA: Hampton Retrieved May 14, 2007. www.biodiesel.org/ Clean Cities Coalition. Retrieved May 9, 2007. pdf _ files/Biodiesel_Blends_Above%20_20_ www.hrccc.org/presentations/BlueRidge Final.pdf CleanFuels-Biodieseloverview.pdf 9. Pelly, Mike. 2003. “Mike Pelly’s Biodiesel Method.” 18. Anon. January 2007. “Biodiesel tests reveal off-spec Journey to Forever. Retrieved June 5, 2007. fuel in U.S. market.” Biodiesel Magazine. www. www.journeytoforever.org/biodiesel_mike.html biodieselmagazine.com/article.jsp?article_id=1345 Page 10 ATTRA Biodiesel Use, Handling, and Fuel Quality
  • 11. Notes www.attra.ncat.org ATTRA Page 11
  • 12. Biodiesel Use, Handling, and Fuel Quality By Andrew Pressman and Mike Morris NCAT Energy Specialists © 2007 NCAT This publication is available on the Web at: www.attra.ncat.org/attra-pub/biodiesel_use.html or www.attra.ncat.org/attra-pub/PDF/biodiesel_use.pdf IP315 Slot 314 Version 102407 Page 12 ATTRA