EN - Presentation Water treatment for the Downstream Oil & Gas industry - Degremont Industry

WATER FOR THE DOWNSTREAM
REFINING & PETROCHEMICAL
INDUSTRY

JUNE 2013

SUMMARY

Degrémont Industry Introduction

Challenges facing the Refining & Petrochemical Industry
Technological and Services Solutions
Mobile Water Solutions
Benefits for the Refining & Petrochemical Industry
References & Customer Testimonies

2

Refining & Petrochem Industry

PRESENT ON A GLOBAL AND LOCAL SCALE,
BENEFITING FROM BOTH WORLDS

WATER AND WASTE

WATER

WATER & WASTEWATER
FOR INDUSTRY
Including

Ameriwater

Anderson

Ozonia

3

Infilco

Purite


Ondeo IS
WPT

DEGRÉMONT INDUSTRY, YOUR PARTNER IN
WATER MANAGEMENT FOR INDUSTRY
Our Offer
Process design
& Engineering
•
•
•
•
•

Pilots
Feasibility Studies (BDP, FEED)
Process Design
Engineering & Procurement
Construction & Installation

Services
•
•
•
•
•

Audit
Technical Assistance
Operation & Maintenance
Mobile Treatment Solutions
Off-site Effluent Treatment

Key Figures
347 M€

worldwide turnover for
industrial customers

Market presence since 1947
1,100 employees
1,800 process water production
plants built

•
•
•
•

Design
Manufacture
Supply
After Sales Services

Equipment

4

•
•
•
•
•

BOT

Finance
Construction
Operation
Maintenance
Transfer

2,200

wastewater treatment plants

built

200

current operation and services
contracts

5,000

industrial sites equipped with
water systems

> 50M m³

per year capacity of
mobile water treatment units


RESEARCH & INNOVATION
A HISTORICAL PRODUCT
ORIENTATION:

KEY FIGURES:
74 M€ devoted to R&D
400 Experts and Researchers
120 Research Partners
17 R&D Centers (USA,
France, UK, Spain & China)
 70 R&D Programs
 More than 700 Technical
Assistance Missions per Year





 A Policy of Patented
Proprietary Products
• In House Developments
• Acquisition and Management of
Licenses
• Products between Innovation
and Optimisation

 An applied R&D
 Pilot Plants all over the World
 An ISO 14001 certified R&D

5


GLOBAL PRESENCE
Richmond, VA

United Kingdom

Benelux
Italy
Russia

Toronto, Canada

India
Dayton, OH
Salt Lake City, UT
Mexico

France
Beijing, China
Spain

Shanghai, China

Houston, TX

United Arab Emirates

Arlington, TX
Qatar

Malaysia

Columbia, SC

Indonesia

Chile
South Africa
Argentina

Australia
Brazil

6


70 YEARS OF EXPERIENCE WITH ALL
INDUSTRIAL SECTORS

7


EHSQ, A PRIORITY AT THE HEART OF OUR
ACTIVITIES
A continuous improvement approach certified ISO 18001,
MASE, VCA, ISO 14000, ISO 9001, OHSAS
High-performance safety indicators
A proactive management system including:
 Site audits,
 Procedures and training adapted to our activities and site
specifications,
 Monitoring,
 Evaluation and continuous improvement,
 Targeted and efficient communication,
 Crisis management protocols

PLAN

8

PERFORM


MONITOR

ENVIRONMENTAL, SOCIAL AND GOVERNANCE
A TRUE GLOBAL COMMITMENT

9


MEMBER OF 4 FLAGSHIP STOCK MARKET
SUSTAINABILITY INDEXES
2009
2009

10

2010
2010

2011
2011


2012
2012

SUMMARY

Degrémont Industry Presentation


11


REFINING & PETROCHEM INDUSTRY

Downstream

Upstream

Exploration
• Drilling of exploration
wells
•
•
•

• Operating the
production wells
• Oil & Gas processing

Process water for production
Treatment of Produced Water (oil separation,
reinjection)
Water reuse or discharge

Production continuity

12

Production

Protecting the environment

Refinery

Petrochemical

• Processing of crude oil
• Refining

• Fabrication of base
chemicals and plastics

•
•

Cooling water and
Utility water
Wastewater

Cost optimisation


•
•

Water reuse, recycle
or discharge
Sludge

Reliability & Safety

CHALLENGES FACING THE DOWNSTREAM
REFINING & PETROCHEMICAL INDUSTRY
Increasing pressure to optimise costs,
minimize water usage while cutting back on
investments
More and more stringent environmental
regulations

To achieve performance objectives, several
challenges need to be addressed:
 Integration of state of the art water
technologies in order to meet environmental
and local constraints (space, discharge and
water resources)
 Requirement for robust installations
following industry specific standards
 Reliable solutions to ensure a flawless
operation
13


MARKET TRENDS
Existing plants

Grassroot

Revamping and/or upgrading
older water & wastewater
treatment plants (>30 years) to
meet new legislation or to give a
second life
 increased treatment
efficiencies, reuse systems

Grassroot water &
wastewater treatment
plants for new industrial
sites
 high efficient, state of
the art, treatment
plants

Contaminated groundwater
treatment plants with reuse

Effluent reuse, and Zero
Liquid Discharge (ZLD)
policy on new plants

Operation and
maintenance
Increasing demand of
customers to support them in
the day to day operations of
their water treatment
systems

14

Mobile water
treatment
Assist clients for ageing
installation to continue
production while repairing
or revamping their water
treatment systems


SUMMARY



15


WATER FOR THE DOWNSTREAM INDUSTRY

16


OUR AREAS OF EXPERTISE
Sludge &
By-products

Water source

Process Water

Wastewater

• Boreholes, groundwater or
surface water intakes

• Physical-chemical treatment,
clarification, filtration

• Flow separation

• Sea water

• Membrane technologies (UF
– NF – RO)

• Physical-chemical
treatments, clarification,
filtration

• Corrosion and biological
control

• Aerobic and anaerobic
biological treatments

• Sludge disposal

• Decarbonation

• Biological systems

• By-products recovery

• Ion exchange

• Membrane technologies

• Oil recovery

• Disinfection systems

• Wastewater reuse or Zero
Liquid Discharge (ZLD)

• Alternative or emergency
supplies

• Reduction of sludge
volume
• In-situ treatment:
digestion, dewatering,
drying and incineration

• Groundwater remediation

(Ozone,UV)

• Electrodeionization

• Network management

• Recycling
• Network management

17


TECHNOLOGICAL SOLUTIONS
FOCUS
PROCESS WATER

WASTE WATER
WASTEWATER

RECYCLING

PRETREATMENT

TREATMENT

PHYSICO-CHEMICAL

Densadeg™

Aquadaf™

Softening & physical chemical
treatment combined in a
single compact unit

High velocity flotation with a
simplified engineered
integration

DEMIN & DESALINATION

DCI™ & DGF

Membrane
Bioreactor

Combined clarification and oil Remove carbon and nitrogen
removal with an integrated using a very compact solution
system

SLUDGE

Tertiary Densadeg™

RO systems

Combined clarification and
thickening functions in a
single compact unit

Recycling of treated
wastewater as feed water to
the demineralisation plant

ADVANCED BIOLOGICAL

Fractal™ Ion
Exchanger

NF- RO Systems

Nitrogen blanketed
decanter centrifuges

Sludge Dewatering

Oxyblue™

Biofor™

Compact design and
optimised regeneration for ion
exchange

Integrated and optimised
system with latest available
membranes

Sludge dewatering

Improved safety in dewatered
sludge drying while reducing
energy costs (thermal/solar)

Boost elimination of nonbiodegradable COD and
persistent micro-pollution

Compact biological treatment
and filtration system

And more available

18

And more available


And more available

INNOVATIVE SERVICES
“A LA CARTE”

Mobile treatment
services
Flexible solution to help you
save cost and secure
production

Spare parts and
associated services
Off-site effluent
treatment service

Wide range of spare parts and
associated services for an
efficient maintenance

Resins, membranes &
associated services
Global solution for your resins
and membranes

19

CoolSure, SteamSure,
UpSure
Optimise and protect
your water production, cooling
& steam production systems


SUMMARY



20


MOBILE SOLUTIONS
FLEXIBLE AND COST EFFECTIVE

EMERGENCY

 Ensuring
the continuity of your
production

21

SOLUTIONS

SCHEDULED
OPERATIONS

 Planning
your water
requirements


LONG TERM
RENTAL

 Producing
water with no capital
investment

A WORLDWIDE MOBILE SERVICE
Presence on 5 continents
A dedicated expert team to ensure our mobile operations meet
your expectations and production needs
Ensuring your needs for both process water and wastewater

Flexible services:
 The RIGHT SOLUTION

 At the RIGHT TIME
 In the RIGHT PLACE
 At the RIGHT PRICE
22


SUMMARY



23


BENEFITS: A COMPLETE OFFER

Leading edge
technologies to ensure
risk management and
the ongoing quest for
streamlined operating
costs throughout the
water cycle

Integrator of state of
the art solutions to
specific problems:
variable water resource
levels or shortages,
reinforced discharge
threshold, specific
pollutants requiring
treatment, etc.

Compliance with and
anticipation of current and
future environmental
regulations

Continuous improvement of the industrial water management
24


SUMMARY



25


MORE THAN 250 REFERENCES WORLDWIDE...

26


… WITH ALL THE MAJOR PLAYERS

27


Needs

 Small footprint available for new
wastewater treatment plant
 Construction in an operating refinery and
wastewater treatment plant
 Strict standards on odour emissions

Solutions
 Engineering & Procurement contract
 Sludge and odour treatment

Benefits
 The solution proposed by Degrémont
Industry allowed the client to be under
the new discharge limitations

28

-

Revamp & Upgrade Project

 Meeting new & more stringent discharge
consent

-

DCI primary oil removal
(3*270m3/h)
DAF treatment (2*340m3/h)
Biological treatment (2*340m3/h)

Capacity
800 m3/h


Type of contract
EP

Our solution

BP HORST
GELSENKIRCHEN, GERMANY

Needs

Solutions
 EPC contract for revamping existing and
operating wastewater plant
 Revamping biological activated treatment
by Membrane Bioreactors (MBR) using
Zenon membranes

Benefits
 One of the first MBR systems in a
petrochemical complex
 The largest MBR plant operational since
2007

29

-

Revamp & Upgrade Project

 Meeting new & more stringent discharge
consent : TSS < 1 mg/l

MBR wastewater treatment plant
upgrade to implement
nitrification and denitrification
with submerged ultrafiltration
membranes

Capacity
2,000 m3/h


Type of contract
EPC

Our solution

SYNDIAL PETROCHEMICALS
PORTO MARGHERA, ITALY

 Groundwater remediation for two sites:
• Gela (Sicily)
• Priolo (Sicily)
 Strict sea water discharge standards for
RO reject

Solutions
 Arsenic removal
 BTEX removal
 Water recycling

Benefits


70% recycled water

Contaminated groundwater

Needs

-

CPI, Densadeg lamellar clarifier
GFH filtration for arsenic removal
MBR treatment for COD and
nitrogen removal
Reverse Osmosis

Capacity
300

m3/h

(Gela), 600

Raffineria
di Gela

30


Type of contract
EPC
(Priolo)

m3/h

Our solution

SYNDIAL GELA & PRIOLO REFINERIES
SICILY, ITALY

Needs

 Reduce operational costs
 Reduce energy consumption

Solutions
 Leak repairs, water recycling,
automation, water and wastewater
plants optimised for maximum
performance

Benefits
 20 year customized contract
 Complete water management
 Full responsibilities for operating and
maintaining systems for the feed water 2
demineralisation systems, 7 cooling
systems and the effluent treatment

31

-

Operations & Maintenance

 Reduce discharge to environment by 5
million liters/day

-

Pre-treatment with an API
Induced Air Flotation and an Activated Sludge
Oily sludges thickened before dewatering in a
centrifuge
Demineralisation unit with cationic, anionic
resins and mixed bed

Capacity
850 m3/h


Type of contract
O&M

Our solution

INEOS
GRANGEMOUTH, UK

 Revamping existing effluent treatment
plant
 New requirements for Nitrogen

Solutions
 3 years operation contract after the
commissioning of the new effluent
treatment plant

Benefits
 Turn key supply of a new effluent
treatment plant in a running system

32

Revamping and upgrade project

Needs
-

Dissolved Air Flotation

-

Biological treatment with
nitrogen removal

Capacity
2 x 240 m3/h


Type of contract
EPC + O&M

Our solution

INEOS
LAVERA, FRANCE

Needs

Solutions
 Stacked horizontal sand filters: 4 x 160
m3/h
 Demineralisation: 3 x 180 m3/h
 Rental of a mobile unit for at least 6
months during the construction and a 3year service contract after the
provisional acceptance

Benefits
 Replacement of 6 demineralization lines
by 3 new lines of ion exchange
demineralization and pressure sand filter

33

-

Expansion - upgrade project

 Compact construction required with
restrictions on hydraulic profile from
existing carbonate removal plant
 Installation inside a running plant

2 x 2 Stacked horizontal sand
filters for 4 x 160 m3/h

-

2 (+1) ion exchange lines (SAC,
CO2, WBA/SBA) for 3 x 180 m3/h

Capacity

Type of contract
EP

4 x 160 m3/h + 3 x 180 m3/h


Our solution

TOTAL PETROCHEMICALS
GONFREVILLE, FRANCE

 New grassroot refinery
 Stringent effluent specification
 Polypropylene production has to be
treated in a centralized water treatment
plant to meet the requirement for
discharges

Solutions
 Part of the water has been further
treated in order to re use this water in
the plant

Benefits


34

Supply of robust processes

Grassroot construction

Needs

-

Catalitic Sulphide oxydation
DCI primary oil removal
DAF treatment
Biological treatment
Densadeg lamellar clarification
Sludge treatment

Capacity
1,000 m3/h


Type of contract
EP

Our solution

PETROCHINA REFINERY
GUANGXI , CHINA

Needs

Solutions
 One standard treatment line, one tertiary
treatment line
 One third treatment line: ozonation unit,
biological filtering system, ultrafiltration
stage, reverse osmosis unit, sludge
treatment facility
 This treatment line also receive treated
rainwater

Benefits

-

Ozonation unit

-

Wastewater treatment plant

 The wastewater plant has to treat
industrial effluent from the refinery and
a third of the wastewater, to be reused
for cooling, saving the region's water
resources

Biological filtering system

-

Ultrafiltration stage

-

Reverse osmosis unit

-

Sludge treatment facility

Capacity
1,115 m3/h

 Largest ozonation unit ever installed in
China (200 kg/h)
 Technical solution meeting the economic
and environmental issues.

35


Type of contract
EPC, O&M, Mobile units

Our solution

PETROCHINA REFINERY
CHENGDU, CHINA

SCIP
SHANGHAI, CHINA
Needs

-

 Industrial and process water production
plants
 Collective waste water treatment plant
 Construction and operation of all plants
for multi-chemical customers

Benefits
 Monitoring and buffering facilities for
each connected client (15)
 Operations & Maintenance over a 25
year period

36

Biological treatment (N/DN)

-


Solutions

Buffering

-

 Centralized wastewater treatment plant,
treating the effluent of a large quantity
of petrochemical & chemical clients

Tertiary DAF flotation

-

Sludge treatment

-

A common homogenization tank

Capacity
3 x 400 m3/h


Type of contract
EPC, O&M, Mobile units

Our solution

INDUSTRIAL PARK

Needs

-

Solution
 BOT followed by an O&M contract with plant
availability of 98 %

Benefits
 Conservation of the water resources
while meeting the industrial and
agricultural needs of a dry land area
where water availability is low

37

DAF treatment

-


 Recycle industrial waste water to
produce cooling tower make up

Catalitic Sulphide oxydation

-

 Approach a Zero Liquid Discharge policy

Biological treatment

-

Seawater desalination - 600 m3/h

Type of contract
360 m3/h + desal. 600 m3/h BOT & O&M
Capacity


Our solution

PEMEX REFINERY
SALINA CRUZ - MEXICO

Needs

-

 Production of boiler feed water from
surface water and recycled refinery
wastewater



UF/RO/MB plant to produce boiler feed
water

Benefits
 Upgrade of facilities for refinery
wastewater treatment and reuse

38

Upgrade Project

Solution

-

Flotation of river water
sand filtration of treated wastewater
and effluent from river water flotation
Activated carbon filtration
UF/RO/MB plant to produce boiler feed
water

Capacity
900 m3/h


Type of contract
EPC

Our solution

PETROBRAS REVAP
SÃO PAULO, BRAZIL

Needs

Solutions
 Short term rental of deionization trailers
 Medium Term – Supply of mobile units
Outsourcing System with Deionization
trailers for polish
 Long Term – The client preferred our
solution and has yet to begin repairs on
their own system

Benefits
 Able to address the short, medium and
long term needs of customer
 Contract renewed annually
 High asset utilization

39

-

MobilePRO Outsourcing

 Needed immediate solution to maintain
operations and medium term solution to
be able to repair deionization system

Mobile units: Reverse Osmosis
and associated pretreatment

-

Mobile units: Deionization Trailers

Capacity
40 m³/h


Type of contract
Mobile units Outsourcing

Our solution

EXXON
KEMMERER, WY - USA

Needs
-

Solutions
 Mobile unit design, build, own operate
system
 Customer pays fixed fee plus variable
rate for production of process water

Benefits
 Original needs satisfied (10 year contract
being renewed and recently extended
again with an expanded scope)
 Customer can focus on financial and
human resources and on core business
 Customer assured of supply of process
water backed up with our mobile assets

40

Mobile units rental

 Customer wanted an economical
alternative to the financial investment
and operation of a process water plant

Clarification
Filtration
Ion Exchange
Reverse Osmosis

Capacity
900 m³/h


Type of contract
DBO - O&M, mobile units

Our solution

VALERO
NEW ORLEANS, LA - USA

Needs
-

 To produce, with no capital investment
and in just a few weeks, 100 m³/h of 0.2
µS/cm demineralised water to feed the
boiler

 Long-term rental mobile installation

Benefits
 A complete demineralisation chain set up
in 5 weeks, with sand filtration, reverse
osmosis and resin demineralisation, in
the form of a leasing agreement

41

Long-term rental

Solution

-

Pre-treatment with multimedia
filtration
2 mobile reverse osmosis units
1 mobile FractalO ion exchange
unit

Capacity
100 m³/h


Type of contract

Long-term rental mobile
installation

Our solution

SASOL REFINERY
SOUTH AFRICA

 Industrial effluent treatment plant
 High effluent standards with regard to
TSS and COD
 Engineering & construction in a relatively
short time

Solution
 Response to the strict client engineering
standards

Benefits
 Quick response to the client’s needs and
respect of the high effluent standards

42

Grassroot + Expansion project

Needs

-

Carbonaceous aeration 2 x 200 m3/h
Degassing & Clarification
Densadeg lamellar clarification
Aerobic sludge digestion and
dewatering

Capacity
600 m3/h


Type of contract
EP

Our solution

OPTIMAL - KERTEH REFINERY
MALAYSIA

Needs

Solution
 This project involves wastewater
treatment plant consisting of an API
separator followed by two 50% lines with
DAF flotation units and four 33%
biological aerated flooded filters (Biofor)

Benefits
 Basic design

-


 Efficient treatment of low polluted water
from a crude oil transport pipeline
 Plant installed in a location with extreme
climatic changes

API separator
2 x 50% DAF flotation
4 x 33% Biofor (biological aerated
flooded filters) biological treatment for
the treatment of produced water and
rainwater

Capacity
140 m3/h

 Detailed Design
 Procurement of equipment
 Commissioning & Start-up
 Staff training

43


Type of contract
EP

Our solution

CASPIAN PIPELINE CONSORTIUM
(CPC)
NOVOROSSIYSK, RUSSIA

CUSTOMER TESTIMONIES

44


EN - Presentation Water treatment for the Downstream Oil & Gas industry - Degremont Industry

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