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Lecture VII.
Applications
Electrostatic Imaging and Xerographic materials
Organic Light-emitting diodes ) OLEDS and Active
Matrix OLEDS (AMOLEDS) for Display and Lighting
Solar Cells
Field-effect transistors
Batteries
Photo-detectors
Luminescence for Land-mine Sniffing
Lasers
Switches
E-Ink
Inorganic Vs. Organic
Material Properties
Limitations At Early Stage
 Organic materials have often proved to be
unstable.
 Making reliable electrical contacts to organic
thin films is difficult.
 When exposed to air, water, or ultraviolet light,
their electronic properties can degrade rapidly.
 The low carrier mobilities characteristic of
organic materials obviates their use in high-
frequency (greater than 10 MHz) applications.
These shortcomings are compounded by the difficulty of
both purifying and doping the materials.
Electrostatic Imaging
Chester Carlson
History of Xerography
The first xerographic image
10-22-1938, Astoria, NY.
slide #2
History of Xerography
1906: Haloid Corp.
founded
1900 1910 1920 1930 1940 1950
1938: 1st
xerographic image
1949: 1st copier -
Model A
1950 1960 1970 1980 1990 2000
1959: Xerox 914, 1st plain paper
automatic copier - 7 1/2
copies/min
1964: LDX (long distance
xerography) - 1st fax
1973: Xerox 6500 -
1st color copier
1977: Xerox 9700 -
1st laser printer
1988: Xerox 5090 -
135 copies/min
1997: Docutech digital printer
(180 copies/min)
1997: Docucolor 70 - 70
color prints/min
Today Xerox has 91,400 employees (50,200 in US) and $18.2 billion in revenues
What is Xerography?
Creation of a visible image using surface charge pattern on a
“photoconductor”.
Visible images consist of fine charged particles called
toners”.
slide #5
Xero-graphy = Dry-Writing (Greek)
Xerographic Prints are composed of
toners
5-10 microns
COLORDigital prints are halftones
Inside a xerographic printer
Photoreceptor
Charging Subsystem (Corotron):
Electrons
Positive Ions
Free ions are attracted
to wire; Free electrons are
repelled. Counter-charges
build up on grounded surfaces.
Rapidly moving electrons
and ions collide with air
molecules, ionizing them
and creating a corona.
Electrons continue to
follow Electric Field lines
to Photoreceptor until
uniform charge builds up
HV Power
Supply (-)
HV Power
Supply (-)
HV Power
Supply (-)
slide #10
Transfer to paper
• Electric field moves particles from
photoreceptor to paper or
transparency
• Detachment field must overcome
toner adhesion to photoreceptor
Apply E
Field
Paper
Paper
Photoreceptor
Photoreceptor
slide #18
Additives control adhesion
Changing type type of additive modifies adhesion
Atomic Force Microscopy results
Electrical Field Detachment of Fine
Particles
E. Eklund, W. Wayman, L. Brillson, D. Hays, 1994 IS&T Proc.,
10th Int. Cong. on Non-Impact Printing, 142-146
slide #19
Measure Many Particle Adhesion
Donor Receiver
V
transparent
conductive
electrodes
VV
Fusing Subsystem
• Permanently affix the image to the final substrate
– paper of various roughness
– transparency (plastic)
• Apply heat and/or pressure
Hot Roll
Fuser:
Pressure Roll
Heat Roll
Paper
slide #21
Cleaning and Erase Subsystems
• Removes unwanted residual toner and charge
from photoreceptor before next imaging cycle
– Physical agitation removes toner (blade or brush)
– Light neutralizes charge by making entire
photoreceptor conductive
slide #22
Physics of the Photo-discharge of
the Corona Charge
Future of Xerography
• Color: Wide gamut, offset quality
• High Image Quality: High resolution,
continuous tone
• High Speed: Full color at 200 pages per
min, and higher
• Higher reliability: No paper jams
• Lower cost: Xerography vs. inkjet
slide #25
Reference
The physics of
XEROGRAPHY:
Howard Mizes
Xerox Corporation
Wilson Center for Research & Technology
Webster, New York
Organic Light-emitting diodes
(OLEDS) and Active Matrix OLEDS
(AMOLEDS) for Display and Lighting
Overview
Inorganic LED’s
Inorganic Vs. Organic
LEDs
Why Organic LED?
 Vibrant colors
 High contrast
 Wide viewing angles from all directions
 Low power consumption
 Low operating voltages
 Wide operating temperature range
 A thin and lightweight form factor
 Cost-effective manufacturability , etc
Organic LED Energy Diagram
A full color, 13-inch diagonal small-molecular-weight OLED display with
2mm thickness.
Flexible internet display screen
S. R. Forrest in Nature428, 911 (2004)
Applications — Full color OLED display
Samsung large OLED displays
KODAK OLED displays
http://www.kodak.com/eknec/PageQuerier.jhtml?pq-path=1473/1481/1491&pq-locale=en_US
Applications — Full color OLED display
OLED Device Physics and
Chemistry
EIL, ETL: n-type materials
Alq3, PBD
HIL, HTL: p-type materials
NPB, TPD
EML:
Fluorescent dye
DCM2
Phosphorescent dye
PtOEP, Ir(ppy)3
Small molecular OLEDs — Materials
Alq3 PBD
NPB TPB
DCM2
Cathode
Organic Layer
Anode
Substrate
Single layer device
Small molecular OLEDs — Structure
Cathode
Hole transport layer
Anode
Substrate
Electron transport layer
P-n junction device
Electron transport layer
Hole transport layer
Anode
Substrate
Emissive layer
Electron Injection layer
Cathode
Hole Injection layer
Multiple layers device
Electron transport layer
Hole transport layer
Anode
Substrate
Emissive layer
Electron Injection layer
Cathode
Hole Injection layer
HOMO — Ev
LUMO — Ec
Transparent
substrate
ITO HIL HTL EML ETL EIL Cathode
h+
e-
h+ h+
e-
e-Light
 Electrons injected from cathode
 Holes injected from anode
 Transport and radiative recombination of
electron hole pairs at emissive layer
Small molecular OLEDs — Device operation principle
Anode:
Indium-tin-oxide (ITO): 4.5-5.1 eV
Au: 5.1 eV
Pt: 5.7 eV
Cathode:
Ca: 2.9 eV
Mg: 3.7 eV
Al: 4.3 eV
Ag: 4.3 eV
Mg : Al alloys
Ca : Al Alloys
Small molecular OLEDs — Electrodes
Substrate
Small
molecules
Vacuum
Heater
Cathode
Hole transport layer
Anode
Substrate
Electron transport layer
Small molecular OLEDs — Device preparation
Growth:
~10-5-10-7 Torr
Room temperature
~20 Å- 2000 Å
Thermal vacuum evaporation
Polymeric OLEDS
Cathode
Emissive polymer
Anode
Substrate
Cathode
Conducting polymer
Anode
Substrate
Emissive polymer
Polymer OLEDs — Structure and Operation
http://www.ewh.ieee.org/soc/cpmt/presentations/cpmt0401a.pd
Conducting polymers:
PANI:PSS
PDOT:PSS
Emissive polymers:
R-PPV
PFO
Polymer OLEDs — Materials
PANI
PDOT
PSS
Polymer OLEDs — Fabrication
Spin coating
Ink jet printing
Screen printing
Web coating
Substrate
Ink jet printing
Substrate
Polymer film
Spin coating
Organic Solar Cells
Example
Self-Organized Discotic Liquid Crystals for High-Efficiency Organic
Photovoltaics
Organic Field Effect transistors
Organic Thin Film Transistors (OTFTs)
Organic material Organic material
An Example of an I-V of OTFTs
Lg = 20 µm
W = 220 µm
400 nm SiO2
50 nm organic
Battery Applications
Li
LiI
PVP-I CT
complex
Li+
Photo-detectors
Luminescence for Mine-Sniffing
Organic Semiconducting Lasers
Organic Switches
E-ink
Lecture 7 oms
Lecture 7 oms
Lecture 7 oms
Lecture 7 oms

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Lecture 7 oms

  • 1. Lecture VII. Applications Electrostatic Imaging and Xerographic materials Organic Light-emitting diodes ) OLEDS and Active Matrix OLEDS (AMOLEDS) for Display and Lighting Solar Cells Field-effect transistors Batteries Photo-detectors Luminescence for Land-mine Sniffing Lasers Switches E-Ink
  • 2.
  • 4. Limitations At Early Stage  Organic materials have often proved to be unstable.  Making reliable electrical contacts to organic thin films is difficult.  When exposed to air, water, or ultraviolet light, their electronic properties can degrade rapidly.  The low carrier mobilities characteristic of organic materials obviates their use in high- frequency (greater than 10 MHz) applications. These shortcomings are compounded by the difficulty of both purifying and doping the materials.
  • 5.
  • 6.
  • 7.
  • 9. Chester Carlson History of Xerography The first xerographic image 10-22-1938, Astoria, NY. slide #2
  • 10. History of Xerography 1906: Haloid Corp. founded 1900 1910 1920 1930 1940 1950 1938: 1st xerographic image 1949: 1st copier - Model A 1950 1960 1970 1980 1990 2000 1959: Xerox 914, 1st plain paper automatic copier - 7 1/2 copies/min 1964: LDX (long distance xerography) - 1st fax 1973: Xerox 6500 - 1st color copier 1977: Xerox 9700 - 1st laser printer 1988: Xerox 5090 - 135 copies/min 1997: Docutech digital printer (180 copies/min) 1997: Docucolor 70 - 70 color prints/min Today Xerox has 91,400 employees (50,200 in US) and $18.2 billion in revenues
  • 11. What is Xerography? Creation of a visible image using surface charge pattern on a “photoconductor”. Visible images consist of fine charged particles called toners”. slide #5 Xero-graphy = Dry-Writing (Greek)
  • 12. Xerographic Prints are composed of toners 5-10 microns COLORDigital prints are halftones
  • 13.
  • 14. Inside a xerographic printer Photoreceptor
  • 15.
  • 16. Charging Subsystem (Corotron): Electrons Positive Ions Free ions are attracted to wire; Free electrons are repelled. Counter-charges build up on grounded surfaces. Rapidly moving electrons and ions collide with air molecules, ionizing them and creating a corona. Electrons continue to follow Electric Field lines to Photoreceptor until uniform charge builds up HV Power Supply (-) HV Power Supply (-) HV Power Supply (-) slide #10
  • 17.
  • 18.
  • 19. Transfer to paper • Electric field moves particles from photoreceptor to paper or transparency • Detachment field must overcome toner adhesion to photoreceptor Apply E Field Paper Paper Photoreceptor Photoreceptor slide #18
  • 20. Additives control adhesion Changing type type of additive modifies adhesion Atomic Force Microscopy results
  • 21. Electrical Field Detachment of Fine Particles E. Eklund, W. Wayman, L. Brillson, D. Hays, 1994 IS&T Proc., 10th Int. Cong. on Non-Impact Printing, 142-146 slide #19 Measure Many Particle Adhesion Donor Receiver V transparent conductive electrodes VV
  • 22. Fusing Subsystem • Permanently affix the image to the final substrate – paper of various roughness – transparency (plastic) • Apply heat and/or pressure Hot Roll Fuser: Pressure Roll Heat Roll Paper slide #21
  • 23. Cleaning and Erase Subsystems • Removes unwanted residual toner and charge from photoreceptor before next imaging cycle – Physical agitation removes toner (blade or brush) – Light neutralizes charge by making entire photoreceptor conductive slide #22
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29.
  • 30.
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 37. Physics of the Photo-discharge of the Corona Charge
  • 38.
  • 39.
  • 40.
  • 41.
  • 42.
  • 43.
  • 44.
  • 45.
  • 46.
  • 47.
  • 48.
  • 49. Future of Xerography • Color: Wide gamut, offset quality • High Image Quality: High resolution, continuous tone • High Speed: Full color at 200 pages per min, and higher • Higher reliability: No paper jams • Lower cost: Xerography vs. inkjet slide #25
  • 50. Reference The physics of XEROGRAPHY: Howard Mizes Xerox Corporation Wilson Center for Research & Technology Webster, New York
  • 51. Organic Light-emitting diodes (OLEDS) and Active Matrix OLEDS (AMOLEDS) for Display and Lighting
  • 53.
  • 55.
  • 57. Why Organic LED?  Vibrant colors  High contrast  Wide viewing angles from all directions  Low power consumption  Low operating voltages  Wide operating temperature range  A thin and lightweight form factor  Cost-effective manufacturability , etc
  • 58.
  • 59.
  • 61.
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  • 63. Samsung large OLED displays KODAK OLED displays http://www.kodak.com/eknec/PageQuerier.jhtml?pq-path=1473/1481/1491&pq-locale=en_US Applications — Full color OLED display
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  • 88. EIL, ETL: n-type materials Alq3, PBD HIL, HTL: p-type materials NPB, TPD EML: Fluorescent dye DCM2 Phosphorescent dye PtOEP, Ir(ppy)3 Small molecular OLEDs — Materials Alq3 PBD NPB TPB DCM2
  • 89.
  • 90.
  • 91. Cathode Organic Layer Anode Substrate Single layer device Small molecular OLEDs — Structure Cathode Hole transport layer Anode Substrate Electron transport layer P-n junction device Electron transport layer Hole transport layer Anode Substrate Emissive layer Electron Injection layer Cathode Hole Injection layer Multiple layers device
  • 92. Electron transport layer Hole transport layer Anode Substrate Emissive layer Electron Injection layer Cathode Hole Injection layer HOMO — Ev LUMO — Ec Transparent substrate ITO HIL HTL EML ETL EIL Cathode h+ e- h+ h+ e- e-Light  Electrons injected from cathode  Holes injected from anode  Transport and radiative recombination of electron hole pairs at emissive layer Small molecular OLEDs — Device operation principle
  • 93.
  • 94. Anode: Indium-tin-oxide (ITO): 4.5-5.1 eV Au: 5.1 eV Pt: 5.7 eV Cathode: Ca: 2.9 eV Mg: 3.7 eV Al: 4.3 eV Ag: 4.3 eV Mg : Al alloys Ca : Al Alloys Small molecular OLEDs — Electrodes
  • 95. Substrate Small molecules Vacuum Heater Cathode Hole transport layer Anode Substrate Electron transport layer Small molecular OLEDs — Device preparation Growth: ~10-5-10-7 Torr Room temperature ~20 Å- 2000 Å Thermal vacuum evaporation
  • 97. Cathode Emissive polymer Anode Substrate Cathode Conducting polymer Anode Substrate Emissive polymer Polymer OLEDs — Structure and Operation http://www.ewh.ieee.org/soc/cpmt/presentations/cpmt0401a.pd
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  • 102. Polymer OLEDs — Fabrication Spin coating Ink jet printing Screen printing Web coating Substrate Ink jet printing Substrate Polymer film Spin coating
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  • 134. Organic Thin Film Transistors (OTFTs) Organic material Organic material
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  • 136. An Example of an I-V of OTFTs Lg = 20 µm W = 220 µm 400 nm SiO2 50 nm organic
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  • 161. E-ink