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Chapter 9 Molecular Geometries and Bonding Theories Chemistry, The Central Science , 11th edition Theodore L. Brown, H. Eugene LeMay, Jr., and Bruce E. Bursten John D. Bookstaver St. Charles Community College Cottleville, MO
Molecular Shapes ,[object Object],[object Object]
What Determines the Shape of a Molecule? ,[object Object],[object Object]
Electron Domains ,[object Object],[object Object],[object Object]
Valence Shell Electron Pair Repulsion Theory (VSEPR) ,[object Object]
Electron-Domain Geometries ,[object Object]
Electron-Domain Geometries ,[object Object],[object Object]
Molecular Geometries ,[object Object],[object Object]
Molecular Geometries ,[object Object]
Linear Electron Domain ,[object Object],[object Object]
Trigonal Planar Electron Domain ,[object Object],[object Object],[object Object]
Nonbonding Pairs and Bond Angle ,[object Object],[object Object]
Multiple Bonds and Bond Angles ,[object Object],[object Object]
Tetrahedral Electron Domain ,[object Object],[object Object],[object Object],[object Object]
Trigonal Bipyramidal Electron Domain ,[object Object],[object Object],[object Object]
Trigonal Bipyramidal Electron Domain ,[object Object]
Trigonal Bipyramidal Electron Domain ,[object Object],[object Object],[object Object],[object Object],[object Object]
Octahedral Electron Domain ,[object Object],[object Object],[object Object],[object Object],[object Object]
Larger Molecules ,[object Object]
Larger Molecules ,[object Object]
Polarity ,[object Object],[object Object]
Polarity ,[object Object]
Polarity
Overlap and Bonding ,[object Object],[object Object]
Overlap and Bonding ,[object Object],[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object],[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object],[object Object],[object Object]
Hybrid Orbitals ,[object Object],[object Object]
Hybrid Orbitals ,[object Object],[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object],[object Object]
Hybrid Orbitals ,[object Object]
Hybrid Orbitals ,[object Object],[object Object]
Hybrid Orbitals ,[object Object]
Valence Bond Theory ,[object Object],[object Object]
Sigma (  ) Bonds ,[object Object],[object Object],[object Object]
Pi (  ) Bonds ,[object Object],[object Object],[object Object]
Single Bonds ,[object Object]
Multiple Bonds ,[object Object]
Multiple Bonds ,[object Object],[object Object]
Multiple Bonds ,[object Object]
Delocalized Electrons:  Resonance ,[object Object]
Delocalized Electrons:  Resonance ,[object Object],[object Object]
Delocalized Electrons:  Resonance ,[object Object]
Resonance ,[object Object]
Resonance ,[object Object],[object Object]
Molecular Orbital (MO) Theory ,[object Object]
Molecular Orbital (MO) Theory ,[object Object],[object Object]
Molecular Orbital (MO) Theory ,[object Object]
MO Theory ,[object Object],[object Object]
MO Theory ,[object Object],1 2 (2 - 0) = 1
MO Theory ,[object Object],[object Object],1 2 (2 - 2) = 0
MO Theory ,[object Object],[object Object],[object Object]
MO Theory ,[object Object],[object Object]
MO Theory ,[object Object],[object Object]
Second-Row MO Diagrams

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Ch09 outline

  • 1. Chapter 9 Molecular Geometries and Bonding Theories Chemistry, The Central Science , 11th edition Theodore L. Brown, H. Eugene LeMay, Jr., and Bruce E. Bursten John D. Bookstaver St. Charles Community College Cottleville, MO
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